Ut-battelle, Inc.

General Graphene Corporation

Other

Nm Devices LLC

University of California

New Mexico State University

Pavan Chaturvedi

Ivan Vlassiouk

Sergei Smirnov

Panagiotis George Datskos

Sheng Dai

Ilia N Ivanov

Shannon Mark Mahurin

Dhanraj Shinde

Sumedh Pradeep Surwade

Adrian Stefan Sabau

Jaswinder Kumar Sharma

Frederick Alyious List, Iii

Xiqing Wang

William H Peter

Raymond Robert Unocic

Georgios Polyzos

Nickolay V Lavrik

Timothy J LaClair

Zuzanna S Siwy

Jaehyeung Park

Pasquale Fernando Fulvio

Yijing Y Stehle

Pavel Yu Apel

Sergey N Dmitriev

Daniel A Schaffer

Michael Stanford

A method for delaminating a graphene layer from a metal catalyst substrate. The method includes depositing the graphene layer on the metal catalyst substrate to form a layered structure and soaking the layered structure in a water-based solution comprising water and a water-miscible organic solvent such that the water-based solution intercalates between the graphene layer and the metal catalyst substrate and oxidizes the metal catalyst substrate for delamination of the graphene layer from the metal catalyst substrate.

Water based solution for decoupling graphene from copper substrates by oxidation

Proton conductive membrane includes a proton selective layer of 80-100% carbon with sp2 hybridization having a thickness of 0.3-100 nm, with 0-20% of hydrogen, oxygen, nitrogen and sp3 carbon; wherein the sp2 carbon is in a form of graphene-like material; the proton selective layer having a plurality of pores formed by any of 7, 8, 9 or 10 sp2 carbon cycles or a combination thereof, with the pores having an effective diameter of up to 0.6 nm; an ionomeric polymer layer on the proton selective layer. Total thickness of the proton conductive membrane is less than 50 microns. The ionomeric polymer is PFSA (perfluorinated sulfonic acid), PVP (polyvinylpyrrolidone) or PVA (poly vinyl alcohol) with iodide or bromide counterion dissolved inside. The graphene-like material is CVD graphene or reduced graphene oxide (rGO). A D to G Raman band ratio of the membrane is more than 0.1.

Method of manufacturing proton selective membranes based on two dimensional materials

Proton selective membranes based on two dimensional materials

Graphene reinforced materials and related methods of manufacture are provided. The graphene reinforced materials include graphene sheet or scroll, graphene-polymer sheet or scroll, and graphene-carbon sheet or scroll, each having material properties that are attractive across a broad range of applications and industries. The graphene reinforced materials generally include monolayer or multilayer graphene that is synthesized by annealing a catalyst substrate within a CVD chamber, introducing a hydrocarbon gas as a carbon source with the CVD chamber to form a layer of graphene on the catalyst substrate, detaching the catalyst substrate from the layer of graphene, and rolling the layer of graphene onto itself to form a scroll, optionally with the addition of a polymer layer or carbonized layer on the graphene layer.

Graphene reinforced materials and related methods of manufacture

A method for producing a composite polymeric article, an additive for a polymeric article, and a composite polymeric article are provided. The method generally includes providing a plurality of graphene nanoplatelets, providing a plurality of silica nanofibers, providing a polymeric material, and distributing the plurality of silica nanofibers and the plurality of graphene nanoplatelets within the polymeric material to achieve a composite article. The additive for a polymeric article includes a plurality of graphene nanoplatelets and a plurality of silica nanofibers. The composite polymeric article includes a plurality of graphene nanoplatelets, a plurality of silica nanofibers, and a polymeric matrix. The plurality of graphene nanoplatelets and the plurality of silica nanofibers are distributed within the polymeric matrix. The silica nanofibers have a mean cross sectional diameter of not more than 100 nm.

Nanocomposite additives based on graphene sheets and silica nanofibers

A method for regulating ion transport between first and second regions of a liquid solution containing ionic species in at least one of said first and second regions, the method comprising applying a voltage on an electrically conductive mesoporous carbon membrane situated between said first and second regions of the liquid solution, wherein liquid flow between first and second regions is permitted only through said mesoporous carbon membrane, and the applied voltage is selected to modulate the degree of ion transport between said first and second regions, wherein an increase in applied voltage results in a reduction in the degree of ion transport between said first and second regions, optionally up to a critical voltage at which ion transport ceases.

Modulation of ion transport in a liquid by application of an electric potential on a mesoporous carbon membrane

Systems and methods for synthesizing continuous single crystal graphene are provided. A catalytic substrate is drawn through a chemical vapor deposition chamber in a first lengthwise direction while flowing a hydrogen gas through the chemical vapor deposition chamber in the same lengthwise direction. A hydrocarbon precursor gas is supplied directly above a surface of the catalytic substrate. A high concentration gradient of the hydrocarbon precursor at the crystal growth front is generated to promote the growth of a continuous single crystal graphene film while suppressing the growth of seed domains ahead of the crystal growth front.

Continuous single crystal growth of graphene

A method for the desalination of water, the method comprising flowing salt water through a free-standing single-layer membrane of nanoporous graphene having a first planar side that makes contact with the salt water and an opposing second planar side from which desalinated water exits, wherein said membrane contains nanopores having a size of up to 1 nm, along with a substantial absence of pores above 1 nm in size, wherein said nanopores up to 1 nm in size have pore edges passivated with silicon, wherein salt ions in said salt water are blocked from passing through said membrane while water in said salt water passes through said membrane to result in desalinated water exiting said membrane.

Nanoporous graphene membrane for desalination of salt water

Systems and methods for synthesizing continuous graphene sheets are provided. The systems and methods include passing a catalyst substrate through a heated chemical vapor deposition chamber and exposing the substrate to a reaction gas mixture of hydrogen and hydrocarbon at a preselected location within the chamber. The reaction gas mixture can include hydrogen having a partial pressure of between about 0 Torr and 20 Torr, hydrocarbon having a partial pressure of between about 20 mTorr and about 10 Torr, and one or more buffer gases. The buffer gases can include argon or other noble gases to maintain atmospheric pressure within the chemical deposition chamber. The resulting graphene can be made with continuous mono and multilayers (up to six layers) and have single crystalline hexagonal grains with a preselected nucleation density and domain size for a range of applications.

High quality large scale single and multilayer graphene production by chemical vapor deposition

A method for fabricating isolated pores in an inorganic membrane includes the steps of patterning the inorganic membrane to selectively expose a portion of the membrane, forming a plurality of tracks of material damage in the exposed portion of the inorganic membrane by irradiation with energetic ions, and chemically etching the track damaged material to define the pores through the inorganic membrane with a predetermined geometrically defined cross sectional shape and with a controlled diameter range from less than 1 nanometer and up to micrometer scale.

Apparatus and method for nanoporous inorganic membranes and films, methods of making and usage thereof

Growing community of inventors

Oak Ridge, TN, United States of America

Ivan Vlassiouk