Shiseido Company, Limited

Isamu Kaneda

Toshio Yanaki

Kazuyuki Miyazawa

Katsunori Yoshida

Atsushi Sogabe

Toshihito Yabu

Tadashi Nakamura

Yoshikazu Soyama

Katsuyuki Kaneko

Fumiaki Matsuzaki

Tomoyuki Kawasoe

Tomo Osawa

Shuji Nishihama

Takahiro Akutsu

Katsuo Hashimoto

Masatoshi Ochiai

Shin-ichi Yusa

Ryota Yamasaki

To provide surface-treating agents that can provide excellent hydrophobicity to powder and can improve its rinsability, to provide surface-treated powders that are treated with the surface-treating agent, and to provide cosmetics that comprise the surface-treated powder. A surface-treating agent consisting of a polymer which comprises a monomer (A) represented by the general formula (1) described below as a constituent monomer. (wherein Rrepresents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, Rrepresents an alkylene group having 4 to 22 carbon atoms, Xrepresents an &#x2014;NH&#x2014; group or an oxygen atom, and Mrepresents a hydrogen atom or a monovalent inorganic or organic cation.)

Surface-treating agents, surface-treated powders, and cosmetics comprising the same

The present invention provides a microgel having a mean particle size of 0.1-1,000 &#x3bc;m, the microgel being produced from a gel which is formed by use of a hydrophilic compound capable of forming a gel. An external composition containing the microgel provides an excellent sensation during use; i.e., the composition provides neither sticky sensation during use nor frictional sensation. Furthermore, even when a large amount of a pharmaceutical ingredient, such as a whitening ingredient, or a salt is incorporated into the composition, the viscosity of the composition is not lowered, and the composition exhibits excellent viscosity increasing property. In addition, the composition exhibits long-term stability, without inviting separation of water.

Microgel and external compositions containing the same

The present invention is a thickener consisting of a microgel obtained by radical polymerization of water soluble ethylene-type unsaturated monomers dissolved in the dispersion phase in a composition having an organic solvent or an oil component as the dispersion medium and water as the dispersion phase, as well as a cosmetic containing said thickener. Also, the present invention is a method of manufacturing a water-swelling polymer in a radical polymerization system consisting of a composition having an organic solvent or oil component as the dispersion medium and an aqueous solution of a water soluble ethylene type unsaturated monomer as the dispersion phase wherein said system contains a surfactant chosen in such a way that the aforementioned composition forms a single phase W/O microemulsion or fine W/O emulsion at a thermal radical polymerization temperature and said thermal radical polymerization is carried out at a temperature equal to or higher than the phase transition temperature of the radical polymerization system, yet not higher than the phase transition temperature by 20&#xb0; C. or more.

Thickener, cosmetic preparation containing the same, and process for producing the same

The invention is an alternating copolymer, and a method of producing the same, obtained by alternately copolymerizing a vinylbenzyl-terminated polyethylene oxide (or polydimethylsiloxane) and a (meth)acryloyl-terminated polydimethylsiloxane (or polyethylene oxide). The alternating copolymer is a novel amphiphilic brush-shaped alternating copolymer having a structure that is well-suited as an emulsifier or a dispersant for oil and silicone solvents commonly used in cosmetics and pharmaceuticals.

Brush-form alternative copolymer and process for producing the same

A hair treatment agent composition characteristically comprising a specific hydrophobically modified polyether urethane and cationic surfactant. The hair treatment agent composition of the present invention provides has good temperature stability in terms of the viscosity, exhibits superior fluid flow characteristics, achieves smoothness and ease of arranging the hair after drying, and gives a superior sensation during use. A cleaning agent composition characteristically comprising a specific hydrophobically modified polyether urethane and anionic surfactant and/or ampholytic surfactant. The cleaning agent composition of the present invention has superior viscosity and is superior in terms of foam formation as well as foam durability and feels refreshing without a slimy sensation after rinsing-off.

Hair grooming preparation

The object of the present invention is to provide a film composition which is solidified in water of which a painted film is rapidly solidified and also has proper usabilities for use as a manicure. To accomplish the object a film composition of the present invention comprises water insoluble film materials, and a solvent which dissolves the water insoluble film materials and soluble with water, wherein the solvent contains specified alkylene glycol ethers and ketones, and characterized by that the film materials are precipitated from the mixture of the remaining solvent and penetrating water in a painted film of the composition when the painted film is dipped in water.

Compositions forming film solidifying in water and nail-care products and nail-care method with the use of the same

The present invention is an emulsion-type pack cosmetic containing polyvinyl alcohol, oil, and water which characteristically contains the oil in the amount of 20-80 wt % or 15-50 wt % of the total emulsion-type pack cosmetic. A fast-drying peel-off type pack cosmetic with a short drying time and superior usability can be provided.

Emulsified cosmetic face pack

Cosmetic composition

A microcapsule of the present invention is characterized in that it encapsulate oil droplets having average particle size of 0.01 to 3 &mgr;m and its capsulating agent is a hydrophilic polymer gelling agent. The main component of the capsulating agent is preferably a hydrophilic polymer gelling agent which hardens by heating and cooling, and, in particular, agar or carrageenan. In the making method of the present invention, a microcapsule can be made efficiently due to no loss in the inner oil phase, and its particle size can easily be controlled. The microcapsule is excellent in shearing-resistance, store stability. Also, if the fracture strength of the microcapsule is within a specific range, a microcapsule which releasing characteristic of encapsulated oil droplets when applied is immediately-, gradually- or non-releasing can be obtained. Further, when such a hydrophilic microcapsule is coated, the contraction in air, dispersibility to various medium, and elusion of encapsulated components in medium can be also improved.

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Yokohama, Japan

Isamu Kaneda