Saft

Alcatel

Isabelle Coco

Jean-Michel Cocciantelli

Jean-Jacques Villenave

Patrick Bernard

Jos&eacute; Alcorta

Corinne Dennig

A non-sintered nickel electrode contains a conductive support and a paste comprising an electrochemically active material containing nickel hydroxide and a binder which is a mixture of an elastomer and a crystalline polymer. The proportion of the elastomer is in the range 25% to 60% by weight of the binder and the proportion of the crystalline polymer is in the range 40% to 75% by weight of the binder.

Non-sintered nickel electrode

In a method of characterizing a polymer binder for cell electrodes in contact with an electrolyte and including a current collector and a paste containing an electrochemically active material and said binder, a spreading coefficient of the binder on the active material is calculated from the measured angle of contact between standard liquids and the active material and the binder, respectively. An interaction energy of the binder with the electrolyte is calculated from the measured angle of contact between the electrolyte and the binder. The binder is selected such that the spreading coefficient is less than zero and the interaction energy is at least 60 mJ/m.sup.2.

Method of characterizing an electrode binder

The present invention concerns a negative electrode for an alkaline cell, comprising a current collector supporting a paste containing an electrochemically active material and a binder, characterized in that said binder is a polymer containing hydrophilic and hydrophobic groups, said polymer being selected from an acrylic homopolymer, copolymer and terpolymer, an unsaturated organic acid copolymer and an unsaturated acid anhydride copolymer.

Negative electrode for an alkaline cell

The present invention concerns an electrode for an alkaline electrolyte secondary cell, comprising a current collector supporting a paste containing an electrochemically active material and a binder, characterized in that said binder is a copolymer selected from copolymers of maleic anhydride and a vinyl monomer, said binder being cross-linked after said electrode has been formed.

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Talence, France

Isabelle Coco