Toyota Jidosha Kabushiki Kaisha

Ippei Goto

Akira Tsujiko

A main object of the present disclosure is to provide an all solid state battery with excellent cycle characteristics. The present disclosure achieves the object by providing an all solid state battery comprising, in an order of, a cathode CA, a first solid electrolyte layer, an anode AN, a second solid electrolyte layer, and a cathode CA, along a thickness direction, wherein: the first solid electrolyte layer contains a first nonwoven fabric, and a first solid electrolyte arranged inside the first nonwoven fabric; the second solid electrolyte layer contains a second nonwoven fabric, and a second solid electrolyte arranged inside the second nonwoven fabric; and in a plan view along the thickness direction, an angle formed by a first fabric direction in the first nonwoven fabric and a second fabric direction in the second nonwoven fabric is 45° or more and 90° or less.

All solid state battery

To improve durability of an all-solid-state battery, a method of manufacturing an all-solid-state battery includes: obtaining a stack having an anode active material layer, a cathode active material layer, a first solid electrolyte layer, and a second solid electrolyte layer, the first solid electrolyte layer and the second solid electrolyte layer being disposed between the anode active material layer and the cathode active material layer, the second solid electrolyte layer containing a sublimational filler; densifying the stack; and subliming the sublimational filler from the second solid electrolyte layer.

Method of manufacturing all-solid-state battery

A method of producing a secondary battery disclosed here includes forming a positive electrode active material layer containing a lithium- and manganese-containing composite oxide on a positive electrode current collector to produce a positive electrode; measuring a peel strength between the positive electrode active material layer and the positive electrode current collector; producing a secondary battery assembly including the positive electrode, a negative electrode, and a nonaqueous electrolyte using the positive electrode; and initially charging the secondary battery assembly. When the secondary battery assembly is initially charged, a restraining pressure is determined based on the measured peel strength, and in a predetermined peel strength range, a higher restraining pressure is set for a secondary battery assembly including a positive electrode having a low peel strength than for a secondary battery assembly including a positive electrode having a large peel strength.

Method of producing secondary battery

The present invention provides a positive electrode material for lithium secondary batteries, having: a positive electrode active material containing Li; and a cover disposed on the positive electrode active material, and containing Li and F, and further containing one or two or more cover elements from among Al, Ti, Zr, Ta and Nb. With a Point a as an arbitrary point of the cover in contact with the positive electrode active material, a Point c as a point on the surface of the cover at a shortest distance from the Point a, and a Point b as a midpoint between the Point a and the Point c, an analysis of the Point a, the Point b and the Point c by X-ray photoelectron spectroscopy yields a ratio of Li concentration at the Point a with respect to the Li concentration at the Point b is 1.1 or higher and lower than 10.8, and a ratio of F concentration at the Point c with respect to F concentration at the Point b is 1.1 or higher and lower than 51.1.

Positive electrode material and lithium secondary battery using same

A method of producing a secondary battery disclosed here includes forming a positive electrode active material layer containing a lithium- and manganese-containing composite oxide on a positive electrode current collector to produce a positive electrode; measuring a peel strength between the positive electrode active material layer and the positive electrode current collector; producing a secondary battery assembly including the positive electrode, a negative electrode, and a nonaqueous electrolyte using the positive electrode; and initially charging the secondary battery assembly. When the secondary battery assembly is initially charged, a charging rate is determined based on the measured peel strength, and in a predetermined peel strength range, a lower charging rate is set for a secondary battery assembly including a positive electrode having a low peel strength than for a secondary battery assembly including a positive electrode having a large peel strength.

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Toyota, Japan

Ippei Goto