Emory University

Iourii V Gueletii

Craig L Hill

Djamaladdin G Musaev

Jie Song

Zhen Luo

Hongjin Lv

This disclosure relates to photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. In certain embodiments, the disclosure relates to compositions comprising water, a complex of a tetra-metal oxide cluster and VWOligands, and a photosensitizer. Typically, the metal oxide cluster is Co. In certain embodiments, the disclosure relates to electrodes and other devices comprising water oxidation catalysts disclosed herein and uses in generating fuels and electrical power from solar energy.

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Decatur, GA, United States of America

Iourii V Gueletii