Basf Aktiengesellschaft

Basf Aktiengellschaft

Basf Se Corporation

Ingo Klopp

Helmut Reichelt

Hansulrich Reisacher

Dirk Franke

Gunter-Rudolf Schroeder

Thomas Bogenstätter

Andreas Stohr

Juan Antonio Gonzalez Gomez

Gero Nordmann

Juergen Decker

Karl-Heinz Etzbach

Hartwig Voss

Stephan Hueffer

Stephan Hüffer

Armin Diefenbacher

Uwe Mauthe

Holger Schöpke

Manfred Munzinger

Matthias Klüglein

Matthias Klueglein

Gunter-Rudolf Schröder

Josef Hetzenegger

Christoph Bomba

Andrea Birgit Schutze

Frank Scherhag

Peter B Ottcher

Hans Kraus

Anette Hartmann

Otto Schiller

Ulrich Frick

Peter B&ouml;ttcher

Heidrun Knoben

Disclosed are solid pigment preparations containing (A) 60 to 95 per weight of at least one pigment, (B) 5 to 40 percent by weight of at least one water-soluble anionic surface-active additive from the group of the homopolymers and copolymers of ethylenically unsaturated monocarboxylic acids and/or ethylenically unsaturated dicarboxylic acids which can additionally contain monopolymerized vinyl monomers having no acid function, the alkoxylation products of said homopolymers and copolymers, and the salts of said homopolymers and copolymers and the alkoxylation products thereof, and (C) 0 to 20 percent by weight of at least one nonionic surface-active polyether-based additive as essential components. Also disclosed are a method for the production thereof and methods for dyeing macromolecular organic and inorganic materials.

Solid pigment preparations containing water-soluble anionic surface-active additives that comprise carboxylate groups

A process for producing a liquid formulation of salts of sulfonated azo dyes by coupling an at least equimolar amount of diazotized aminoarylsulfonic acids IHN&#x2014;Ar&#x2014;SOH&#x2003;&#x2003;(I),where Ar is phenylene (which may be monosubstituted by sulfo) or naphthylene (which may be mono- or disubstituted by sulfo and/or monosubstituted by hydroxyl) onto the coupling product of an unsubstituted or methyl-substituted phenylenediamine with itself comprises dissolving the azo dye in a basic medium and then subjecting the solution to a nanofiltration.

Method for producing a liquid formulation of salts of sulphonic-acid azo dyes

The present invention relates to aqueous liquid formulations comprising

Liquid direct dye formulations

A process for carrying out a liquid/solid reaction comprises The process has the advantage that the insoluble reaction product is obtained in a readily filterable form.

Process for liquid/solid reaction

Solid pigment preparations comprising as essential constituents

Solid pigment preparations containing anionic and non-ionic surface-active additives

Liquid formulations of direct dyes

Solid pigment preparations containing the following ingredients as substantial components: (A) 60&#x2013;85 wt. % of at least one organic pigment, (B) 0.1&#x2013;15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T, Tindependently represent a chemical bond, &#x2014;CONR&#x2014; or &#x2014;SONR&#x2014;; B, Bindependently represent a chemical bond, C1&#x2013;C8-alkylene or phenylene; X, Y independently represent similar or different groups &#x2014;SO&#x2014; Kaor &#x2014;COO&#x2014; Ka; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; KaH, Li, Na, K, NRRRRor a mixture of said cations; Rrepresents hydrogen; C&#x2013;C-alkyl; phenyl or naphthyl which can be respectively substituted by C&#x2013;C-alkyl; R, R, R, Rindependently represent hydrogen; C&#x2013;C-alkyl; C&#x2013;C-alkenyl; C&#x2013;C-cycloalkyl which can be substituted by C&#x2013;C-alkyl; phenyl or naphthyl which can be respectively substituted by C&#x2013;C-alkyl or C&#x2013;C-alkenyl; a radical of formula &#x2014;[CHR&#x2014;CHR&#x2014;O]x&#x2014;R, wherein the repeating units &#x2014;[CHR&#x2014;CHR&#x2014;O] for x &#x3e;1 can vary; R, R, Rindependently represent hydrogen or C&#x2013;C-alkyl; x is a whole number =1, and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters, phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde. 

Solid pigment preparations containing pigment derivatives and surface-active additives

The present invention relates to an aqueous liquid formulation comprising based on the total weight of the aqueous liquid formulation.

A process is described for preparing ammonium salts of aromatic carboxylic acids by reacting an aromatic carboxylic acid with ammonia in an aprotic solvent, which comprises carrying out the reaction in a closed vessel by continuously introducing a solution of the aromatic carboxylic acid in the aprotic solvent and passing in gaseous ammonia so that an ammonia partial pressure in the range from 0.1 to 3 bar is maintained in the gas space of the vessel, and discharging a suspension of the ammonium salt in the aprotic solvent. The process allows the preparation of ammonium salts of defined crystal size having a narrow size distribution.

Production of ammonium salts of aromatic carboxylic acids

Ethers, esters or acid anhydrides are advantageously obtained when a cake of a first reactant selected from salts of organic or oxygen-containing inorganic acids or alkoxides disposed on a filter element is flowed through by a solution of a second reactant selected from inorganic or organic acid halides and alkyl halides, so that the insoluble halide salt formed remains on the filter element. The halide salt can thus be removed substantially quantitatively in a simple manner.

Method for producing ethers, esters or acid anhydrides

Incipiently chlorinated copper phthalocyanine pigments having a chlorine content of from 10 to 40% by weight and a dispersion harshness &lE;10 in LDPE are useful for coloring plastics.

Chlorinated copper phthalocyanine pigments

A process for preparing metal-free phthalocyanine by reductive cyclization of phthalonitrile in the presence of an aliphatic alcohol, of a redox catalyst and of an inorganic base comprises effecting the cyclization in the presence of one or more phthalocyanine derivatives selected from the group consisting of phthalocyanine-sulfonic acids and -carboxylic acids and their alkali metal, ammonium and alkylarnozium salts, the amino-substituted and aminomethylated phthalocyanines and their reaction products with alkylating agents, sulfonic acids, sulfonyl chlorides and carbonyl chlorides, the imidomethylene- and amidomethylene-substituted phthalocyanines, the alkyl-, aryl- and cyano-substituted phthalocyanines, the hydroxyl- and alkoxy-substituted phthalocyanines and their reaction products with tetraalkyl- and tetraalkoxy-silanes and the halogenated phthalocyanines.

Phase-directed preparation of metal-free phthalocyanine

A process for preparing metal-free phthalocyanines which can carry up to 16 halogen atoms, cyano groups, carboxyl groups, sulfo groups, C.sub.1 -C.sub.18 -alkyl groups and/or aryl radicals as substituents by reductive cyclization of ortho-phthalodinitrile substituted ortho-phthalodinitriles or mixtures thereof comprises effecting the cyclization in C.sub.2 -C.sub.4 -alkylene monoglycols, oligoglycols or polyglycols, their mono-C.sub.1 -C.sub.4 -alkyl or -aryl ethers or their mixtures in the presence of an aromatic compound of the formula I ##STR1## where the substituents X can be identical or different and each denotes hydroxyl, mercapto, amino or C.sub.1 -C.sub.6 -alkylamino, the substituents Y can likewise be identical or different and each denotes halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkoxycarbonyl, m is from 1 to 4 and n is from 0 to 5, subject to the proviso that m+n .ltoreq.6, and the benzene ring A can be fused to a further benzene ring, and of an inorganic base.

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Weisenheim, Germany

Ingo Klopp