Sabic Global Technologies B.v.

Ilya Borisov

Nicolaas Hendrika Friederichs

Vincenzo Busico

Roberta Cipullo

Bogdan A Guzeev

Dmitry Uborsky

Dmitry Y Mladentsev

Anton Ginzburg

Abbas-Alli Ghudubhai Shaikh

Antonio Vittoria

Alexander Voskoboynikov

Hendriksen Coen

Mikhail I Sharikov

Shaneesh Vadake Kulangara

Vyatcheslav Izmer

Dmitry Kononovich

Oleg Samsonov

Luca Rongo

Ninad Ghavale

Nitin Nandurkar

Anamitra Chatterjee

The invention relates to a metallocene complex according to formula (A): wherein R1 is selected from C1-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, and C1-C10 alkoxy groups, wherein R2 is selected from H, C1-C10 alkyl; wherein R3-R6, R10 are independently selected from H, C1-C10 alkyl, C6-C10 aryl, and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ringstructure; wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2, and wherein each R7 independently is selected from C1-C6 alkyl or aryl groups. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers. 

Dihydrocarbyl-silyl-bridged-1,3 disubstituted-2-indenyl metallocene complexes for olefin polymerization

The invention relates to a metallocene complex according to formula (I), wherein R1 is selected from C2-C10 alkyl, preferably C3-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, wherein R2 is selected from H, C1-C10 alkyl, and wherein R3, R4, R5 and R6 are independently selected from H, C1-C10 alkyl, C6-C20 aryl, or C7-C20 aralkyl groups and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ring structure wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers. 

Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization

The invention relates to a metallocene complex according to formula A, wherein R1-R10 are independently selected from H, C1-C10 alkyl, C7-C20 Aralkyl groups, and C1-C10 alkoxy groups; wherein R11 is selected from methyl, ethyl, propyl, isopropyl, butyl, phenyl; wherein R1 and R2, R3 and R4, R4 and R5, R5 and R6, R7 and R8, R8 and R9, and/or R9 and R10 can be connected to form a ringstructure; wherein R0 is selected from a C1-C10 alkyl group or an aryl group wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2. The invention further relates to a catalyst for preparing polyolefins, a process for polymerizing olefins and to polymers prepared by said catalyst system. 

Dimethyl-silyl-bridged-1-substituted-2-indenyl metallocene complexes for olefin polymerization

The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R, R, Rand R4 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; and R, R, Rand Rare each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; or two adjacent radicals Rand R, Rand R, and Rand Rare connected with each other in a hydrocarbon ring system. The invention also relates to a catalyst comprising the metallocene complex, to a process for making polyolefins and to the use of the polyolefins for making articles. 

Catalyst comprising a metallocene complex and co-catalyst

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Geleen, Netherlands

Ilya Borisov