Cellicon B.v.

Igor Babich

Paul O'Connor

Jacobus Johannes Leonardus Heinerman

The invention relates to a method for the preparation of micro- or nano crystalline cellulosic compositions from virgin cellulose containing amorphous and crystalline cellulose phases comprising the following steps: (A) contacting virgin cellulose with a first solvent, characterized in that the first solvent is an aqueous solution comprising 40-65 wt. % ZnClin water, relative to the total weight of the of ZnCland water, (B) dissolving the amorphous cellulosic phase, whereby the amorphous cellulosic phase is preferentially dissolved over the crystalline cellulosic phase, (C) separating the dissolved amorphous cellulose from the crystalline cellulose and preferably step C wherein the obtained micro- or nanocellulose has XRD type I structure, which then can be contacted with a second solvent comprising between 65 and 90 wt. % ZnClin water to produce delaminated cellulose having XRD type II structure. The invention also relates to micro- or nano crystalline cellulose having an XRD type I structure and nano crystalline cellulose having an XRD type II structure or mixtures thereof of high crystallinity and purity and the uses thereof.

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Hagestein, Netherlands

Igor Babich