Lg Chem, Ltd

Electronics and Telecommunications Research Institute

Kyungpook National University Industry-Academic Cooperation Foundation

Hyung Sub Lee

Min Cheol Ju

In Soo Kim

Sung Won Hong

Min Seung Shin

Dae Woo Lee

Won Seok Lee

Ho Hoon Kim

Keun Hoon Yoo

Jeong Su Choi

Roo Da Lee

Sang Hoo Park

Seok Goo Jang

Eun Chang Choi

Jung Tae Park

Dae Sik Kim

Chang Sull Kim

Kyu Hyung Kim

Tae Wuk Bae

Hoi In Jeong

Jung Wook Suh

Sungwon Hong

Jung Chul Kim

Yong Chul Jung

Moon Kyu Kim

Suk Jo Choi

Seong Jae Shin

Chang Hyuk Hong

Hyun Jun Ryu

Woo Ri Kim

Insoo Kim

Minseung Shin

Mincheol Ju

Provided is a method of preparing a maleimide-based copolymer, which comprises adding a monomer mixture including an aromatic vinyl-based monomer and a maleimide-based monomer to an aqueous solution consisting of an aqueous solvent and a first vinyl cyanide-based monomer and performing polymerization.

Method of preparing maleimide-based copolymer

The present invention relates to a method of preparing a polymer, which includes: adding a first reaction solution including an aqueous solvent and a monomer mixture including an alkyl-substituted aromatic vinyl-based monomer, an alkyl-unsubstituted aromatic vinyl-based monomer, and a vinyl cyanide-based monomer to a reactor and initiating polymerization; and performing polymerization by continuously adding an alkyl-substituted aromatic vinyl-based monomer to the reactor, wherein the first reaction solution satisfies Expression 1 (see the description of the invention).

Method of preparing polymer

Provided is a polymer production method including: batch-adding a reaction solution including a monomer mixture including a maleimide-based monomer, a vinyl aromatic monomer, and a vinyl cyanide-based monomer and an aqueous solvent to a reactor and initiating polymerization; and carrying out the polymerization while continuously adding the maleimide-based monomer and the aqueous solvent to the reactor, wherein the reaction solution satisfies the above Formula 1.

Polymer production method

The present invention relates to a method for producing a copolymer, the method for producing a copolymer including: step (S) for adding aromatic vinyl-based monomers substituted with alkyl groups and vinyl cyan-based monomers to perform polymerization in the presence of a polymerization initiator, wherein the vinyl cyan-based monomers are collectively added before initiation of the polymerization in step (S), monomer droplets are continuously divisionally added during the polymerization in step (S), and the monomer droplets contain part or all of the aromatic vinyl-based monomers substituted with alkyl groups, and relates to a copolymer produced therefrom, and a thermoplastic resin composition including the same.

Method for producing copolymer, copolymer produced therefrom, and thermoplastic resin composition including the same

The present invention relates to a method for preparing a thermoplastic copolymer using monomer droplets, a thermoplastic copolymer prepared therefrom and a thermoplastic resin composition including the same. In the preparation method, monomer droplets including an aromatic vinyl-based monomer are injected after reaching a polymerization conversion ratio of 10% to participate in the reaction after initiating polymerization, and a thermoplastic copolymer having an increased average particle diameter may be prepared in high yield.

Method for preparing thermoplastic copolymer, thermoplastic copolymer prepared therefrom, and thermoplastic resin composition including the same

Provided is a method of preparing a copolymer which includes 1) initiating polymerization by batch-adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor; and 2) performing polymerization by continuously adding an aromatic vinyl-based monomer to the reactor at a predetermined rate after the initiation of polymerization, wherein the continuous addition of the aromatic vinyl-based monomer is initiated when a polymerization conversion rate is 10% or less and terminated when a polymerization conversion rate is between 80 and 90%, and step 2) includes a first temperature phase and a second temperature phase, each of which maintains a constant temperature, wherein a temperature of the second temperature phase is higher than that of the first temperature phase, and thereby a copolymer with a small standard deviation for a vinyl cyan-based unit composition and excellent transparency may be prepared.

Method of preparing copolymer

The present invention relates to a method of preparing a thermoplastic resin, a thermoplastic resin prepared by the same, and a thermoplastic resin composition including the same. More specifically, the method of the present invention includes a step of performing acid coagulation of emulsion polymerization latex, a step of treating coagulated slurry with a base and performing dehydration, and a step of adding a metal salt and water to dehydrated wet powder to adjust pH to 9 or more. According to the present invention, the method may increase the productivity of a thermoplastic resin, and the thermoplastic resin prepared by the method has excellent mechanical strength, thermal stability, and appearance properties. In addition, when the thermoplastic resin of the present invention is used in coating, the thermoplastic resin has an effect of improving the adhesive strength and appearance quality of a coating film.

Method of preparing thermoplastic resin, thermoplastic resin prepared therfrom and thermoplastic resin composition comprising the same

The present invention relates to a method of preparing a thermoplastic resin. More particularly, the present invention relates to a method of preparing a thermoplastic resin, the method including A) a step of coagulating an emulsion-polymerized latex with an acid; B) a step of treating the coagulated aggregate (slurry) with a base, followed by dehydration; and C) a step of treating the dehydrated wet powder with an acid, followed by dehydration. A method of preparing a thermoplastic resin which exhibits reduced gas generation, color improvement, and superior thermal stability is provided.

Method of preparing thermoplastic resin

Disclosed are a method of preparing a resin powder and an integrated reactor for the same. When a coagulation process is performed using an acidic coagulant in the integrated coagulator for latex coagulation and aging according to the present invention, a remaining acidic coagulant is also removed from a reactor through neutralization, and thus, a resin powder having enhanced moist-heat resistance and thermal stability may be prepared.

Method of preparing resin powder and integrated coagulator for the same

The present invention relates to a method of preparing a thermoplastic resin. More particularly, the present invention relates to a method of preparing a thermoplastic resin, the method including a coagulation step of adding a water-soluble silicate compound and a metal salt coagulant to an &#x3b1;-methylstyrene-vinyl cyan compound copolymer latex, followed by coagulation. In accordance with the present invention, a method of preparing a thermoplastic resin having superior heat resistance by adding an additive during coagulation and aging of &#x3b1;-methylstyrene-vinyl cyan compound copolymer latex while controlling an addition time point of the additive is provided.

The present invention relates to a thermoplastic resin. In accordance with the present invention, a thermoplastic resin exhibiting superior heat resistance, gloss, and whiteness while having mechanical properties identical to or higher than those of a conventional thermoplastic resin and a thermoplastic resin composition including the same are provided.

Thermoplastic resin and thermoplastic resin composition including the same

Provided is a manual follicle-transplanting hair transplanter for increasing a graft survival rate. The manual follicle-transplanting hair transplanter includes a needle member having a lower end containing a follicle to be transplanted and having a head having a larger diameter than a portion below the head at an upper end thereof, a rod member inserted into the needle member and having a push portion having a larger diameter than a portion below the push portion at an upper end thereof, an inner body configured to contain the needle member and limit downward movement of the needle member, and an outer body configured to contain the inner body and limit upward movement of the needle member. The needle member is automatically withdrawn when a compressed spring disposed in the inner body expands and pushes up a lower surface of the head.

Manual follicle-transplanting hair transplanter for increasing graft survival rate

Disclosed are a thermoplastic resin composition and a method of preparing the same. More particularly, the present invention relates to a thermoplastic resin composition including 10 to 90% by weight of a graft copolymer resin coagulated by an organic acid or an organic acid salt; and 90 to 10% by weight of a non-graft copolymer resin and having a moist-heat characteristic of 20 or less, wherein a refractive index difference between the graft copolymer resin and the non-graft copolymer resin is less than 0.01, a method of preparing the same, and a molded product comprising the same. According to the present disclosure, provided are a thermoplastic resin composition having superior overall property balance, color, and transparency, and being applicable to products that are exposed to high-temperature water or should be sterilized, due to excellent moist-heat resistance thereof, a method of preparing the same, and a molded product comprising the same.

Thermoplastic resin composition, method of preparing the same and molded product using the same

Disclosed are an apparatus for preparing a polymer latex resin powder in which an efficiency of mixing of steam, a latex, and a coagulant is increased by introducing a non-continuous screw into a reactor that performs coagulation and aging and thus a moisture content of a slurry is decreased and, accordingly, drying efficiency may be enhanced, and a polymer latex resin powder with excellent color and powder characteristics may be prepared using a decreased amount of coagulant and a method of preparing a polymer latex resin powder by using the same.

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Daejeon, South Korea

Hyung Sub Lee