Lg Chem, Ltd

Toray Battery Separator Film Co., Ltd.

Hyun-Min Jang

Sang-Young Lee

Seok-Koo Kim

Jang-Hyuk Hong

Dae-Jong Seo

Joon-Yong Sohn

Dong-Myung Kim

Jong-Hwan Kim

Jong-Hun Kim

Yoon-Jung Bae

Pil-Kyu Park

Han-Ho Lee

Byoung-Jin Shin

Jong-Hyeok Park

Young-Soo Kim

Ji-Sang Yu

Dong-Hun Han

Jang-Hyup Hong

Disclosed is an electrode whose surface includes an organic/inorganic composite porous coating layer comprising heat-absorbing inorganic particles and a binder polymer, wherein the heat-absorbing inorganic particle is at least one particle selected from the group consisting of antimony-containing compounds, metal hydroxides, guanidine-based compounds, born-containing compounds and zinc tartrate compounds. A separator using the heat-absorbing inorganic particles as a component for forming or coating the separator, and an electrochemical device including the electrode and/or the separator are also disclosed. The separator using the heat-absorbing inorganic particles as a component for forming or coating the separator can ensure excellent thermal safety and minimizes degradation of the quality of a battery.

Lithium secondary battery with enhanced heat-resistance

Disclosed is an electrode whose surface includes an organic/inorganic composite porous coating layer comprising heat-absorbing inorganic particles and a binder polymer, wherein the heat-absorbing inorganic particle is at least one particle selected from the group consisting of antimony-containing compounds, metal hydroxides, guanidine-based compounds, boron-containing compounds and zinc tartrate compounds. A separator using the heat-absorbing inorganic particles as a component for forming or coating the separator, and an electrochemical device including the electrode and/or the separator are also disclosed. The separator using the heat-absorbing inorganic particles as a component for forming or coating the separator can ensure excellent thermal safety and minimizes degradation of the quality of a battery.

Disclosed is an electrode comprising an organic/inorganic composite introduced onto either surface or both surfaces thereof, the organic/inorganic composite comprising inorganic particle or aggregates thereof having a unique spectrum or color pattern according to a predetermined rule, and a polymer capable of interconnecting and fixing the inorganic particles. Also, disclosed are an electrochemical device comprising the above electrode, and a method for identifying the origin or kind of an electrode itself or an electrochemical device comprising the same by using the above electrode.

Electrode with organic/inorganic composite and electrochemical device comprising the same

An electrochemical device includes a plurality of unit cells, each having a first separator and a cathode and an anode positioned at both sides of the first separator, and a continuous single second separator interposed between adjacent unit cells in correspondence with each other in a laminated pattern and arranged to surround each unit cell. The first separator includes a heat-resisting porous substrate having a melt point of 200&#xb0; C. or above and a first porous coating layer formed on at least one surface of the heat-resisting porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer. The second separator includes a polyolefin porous substrate and a second porous coating layer formed on at least one surface of the polyolefin porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer.

Electrochemical device having different kinds of separators

A separator includes a porous substrate having a plurality of pores; and a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer, wherein the binder polymer includes a first polyvinylidene fluoride based copolymer having solubility of 25 weight % or more with respect to acetone at 35&#xb0; C.; a second polyvinylidene fluoride-based copolymer having solubility of 10 weight % or less with respect to acetone at 35&#xb0; C.; and a polymer having a cyano group. This separator decelerates deterioration of life span of an electrochemical device, and prevents disintercalation of inorganic particles in the porous coating layer, thereby improving safety of the electrochemical device.

Separator having porous coating layer and electrochemical device containing the same

Disclosed is a separator comprising inorganic particle or aggregates thereof having a unique spectrum or color pattern according to a predetermined rule. Also, disclosed are an electrochemical device comprising the above separator and a method for identifying the origin or kind of the separator itself or the electrochemical device comprising the same by using the above separator. Further, disclosed is a method for manufacturing the aforementioned separator, the method comprising a step of forming a specific pattern by coating inorganic particles having a unique spectrum or color pattern on at least one area selected from the group consisting of a surface of a porous substrate and a porous part of the substrate.

Separator and electrochemical device comprising the same

An organic/inorganic composite separator includes (a) a polyolefin porous substrate having pores; and (b) a porous active layer containing a mixture of inorganic particles and a binder polymer, with which at least one surface of the polyolefin porous substrate is coated, wherein the porous active layer has a peeling force of 5 gf/cm or above, and a thermal shrinkage of the separator after being left alone at 150&#xb0; C. for 1 hour is 50% or below in a machine direction (MD) or in a transverse direction (TD). This organic/inorganic composite separator solves the problem that inorganic particles in the porous active layer formed on the porous substrate are extracted during an assembly process of an electrochemical device, and also it may prevent an electric short circuit between cathode and anode even when the electrochemical device is overheated.

Organic/inorganic composite separator having porous active coating layer and electrochemical device containing the same

Disclosed is an organic/inorganic composite separator including: a porous substrate having pores; and a porous active layer containing a mixture of inorganic particles and a binder polymer with which at least one surface of the porous substrate is coated. The organic/inorganic composite separator of the present invention may be useful to enhance peeling and scratch resistances and improve a lamination characteristic by introducing a porous active layer onto a porous substrate having pores, the porous active layer having heterogeneity of morphology toward a thickness direction in which a content ratio of the binder polymer/inorganic particles present in a surface layer is higher than that of the binder polymer/inorganic particles present inside the surface layer. Accordingly, the stability and performances of a battery can be improved together since the detachment of inorganic particles from the porous active layer may be reduced during the assembly process of the electrochemical device.

Growing community of inventors

Daejeon, South Korea

Hyun-Min Jang