Lg Chem, Ltd

Electronics and Telecommunications Research Institute

Other

Ant21 Co., Ltd

Hyun Kyu Kim

Jeong Ju Moon

Joo Ho Kim

Seok Ho Jeong

Mi Yeon Lee

Yun Ki Cho

Woo Hyuk Choi

Sung Kyu Lee

Hyoung Jun

Dong Hyun Ko

Chan Hyu Jin

Da Won Jung

Yeon Uk Choo

Jin Sung Park

Gyu Il Lee

Hyoung Sun Kim

Young Ae Jeon

Ji Yeon Son

Hark Jin Lee

Yong Kwi Lee

Young-Ho Suh

Jae Hun Jeong

Hyun Jong Kim

Chil Eui Hong

Kang-Woo Lee

Jae Hong Kim

Joon Ho Shin

Seung Jin Lee

Sang Woo Kim

Young Il Kim

Joo Chan Sohn

Jun Hee Park

Sung Shik Eom

Nam Gyun Kim

Young Ho Suh

Hyun-Jong Kim

Ha Na Lee

Young Jo Cho

Joo-Haeng Lee

Ji-Yeon Son

Kang Woo Lee

Young Sung Son

Mun Sung Han

Seok Goo Lee

Yong-Kwi Lee

Eun Seo Lee

Hyoungsun Kim

Joo Haeng Lee

Eun Suk Kim

Hark-Jin Lee

Joonmyun Cho

Young-Ae Jeon

Young Giu Jung

Yeon Jun Kim

Byong Cheol Kwon

Jin Young Kwon

Dong Woo Kim

Chi Jae Oh

Hwa Gyoo Park

Kun-Ouk Kim

Joon-Myun Cho

Rock Won Kim

Kyu Cheol Lee

Myung Han Ko

Wook Bae

Joo Shin Park

Jae Kyung Yang

Kyung Han Ko

Gyu Ll Lee

Kyoung Ryeol Baek

Dae Hwan Yoon

Seung Taek Woo

Gyu Ii Lee

The present disclosure is characterized in comprising a terephthalate-based composition and a citrate-based composition, wherein the terephthalate-based composition comprises di(2-ethylhexyl) terephthalate, hexyl(2-ethylhexyl) terephthalate and dihexyl terephthalate, the citrate-based composition comprises trihexyl citrate, and the hexyl group of the terephthalate and the hexyl group of the citrate are derived from an isomer mixture of hexyl alcohols. If the composition is applied to a resin, migration resistance and stress resistance may be improved, and on the other hand, mechanical properties may be improved.

Plasticizer composition and resin composition comprising the same

The present invention relates to a plasticizer composition including a lower alkyl-based citrate and a higher alkyl-based citrate simultaneously as citrates, wherein effects are achieved through controlling the ratio of hybrid and nonhybrid types, and the ratio of lower alkyl and higher alkyl, and if the plasticizer composition is applied in a resin, stress resistance and mechanical properties may be maintained to the equal or better levels, balance between migration and loss properties, and plasticization efficiency may be achieved, and light resistance and heat resistance may be markedly improved.

Citrate-based plasticizer composition and resin composition comprising the same

An esterification reaction apparatus and an esterification reaction method, the esterification reaction apparatus comprising a reaction tank having an accommodation part, in which a raw material containing carboxylic acid and alcohol is accommodated, a heating unit configured to individually heat partition regions that are partitioned into N regions in a vertical direction of the accommodation part, and a controller configured to control the heating unit so that only the partition regions in which a liquid is accommodated among the N partition regions are heated, thereby performing an esterification reaction of the raw material.

Apparatus and method for esterification reaction

The present invention relates to a tetraester-based plasticizer composition characterized in including a product derived from esterification reaction of an isomer mixture of hexanoic acid and a tetraol, wherein the degree of branching of the isomer mixture of hexanoic acid is 2.0 or less. If the plasticizer composition is applied to a resin, plasticization efficiency and absorption rate may be maintained to equal or better levels when compared to a case applying the conventional plasticizer, and mechanical properties, migration resistance, stress migration and loss properties may be markedly improved.

Plasticizer composition and resin composition including the same

Provided are a plasticizer composition and a resin composition, and a preparation method thereof, wherein the present invention may provide a plasticizer, which may improve physical properties, such as plasticizing efficiency, migration, tensile strength, elongation rate, stress resistance, and light resistance, required for a sheet formulation when used as a plasticizer of a resin composition, by improving poor physical properties that have been ascribed to structural limitations, and a resin composition including the plasticizer.

Plasticizer composition and resin composition, and preparation method thereof

The present disclosure relates to a plasticizer composition characterized in including two or more isophthalates of the same carbon number type, in which alkyl groups bonded to two ester groups have the same carbon number; one or more isophthalates of a different carbon number type, in which alkyl groups bonded to two ester groups have different carbon numbers; wherein the different carbon number type includes both a higher alkyl and a lower alkyl, the carbon number of the higher alkyl is 8 to 10, and the carbon number of the lower alkyl is selected from 5 to 7, thereby, when applied to a resin, showing improved viscosity stability, migration resistance and stress resistance, while maintaining and improving plasticization efficiency and mechanical properties to the same or better level.

A neutralization/water separation tank for an esterified product including: a neutralization part in which a crude product mixture containing alcohol and an ester compound, a neutralizing agent, and water are put to produce a neutralized mixture; a water separation part which divides the neutralized mixture into a floating layer and an aqueous layer; a first partition wall which extends upward from a bottom surface to provide an upper passage and by which the neutralization part and the water separation part are partitioned; and a second partition wall which extends downward from a ceiling to provide a lower passage, wherein the water separation part includes: a first water separation part into which the neutralized mixture is introduced from the neutralization part through the upper passage; and a second water separation part into which the neutralized mixture is introduced from the first water separation part through the lower passage, wherein the first water separation part and the second water separation part are partitioned by the second partition wall.

Neutralization/water separation tank for esterified product and neutralization/water separation method for esterified product

The present disclosure relates to a plasticizer composition including a cyclohexane 1,4-diester-based material and a cyclohexane 1,2,4-triester-based material, and may provide a plasticizer maintaining an excellent level of plasticization efficiency when compared with a common phthalate-based plasticizer product and improving mechanical properties, and may also provide a plasticizer having excellent stress resistance as an advantage.

The present disclosure relates to a diester-based material production unit including a reaction device in which an esterification reaction of dicarboxylic acid and a primary alcohol is performed, a column in which the gas-liquid separation of the primary alcohol and the water introduced is performed, a heat exchanger installed on a gas phase line of the column to remove heat of the gas phase line, a flash drum in which separation of a liquid phase and a gas phase is performed in the mixture stream including the primary alcohol and the water, a condenser installed on the flash drum upper line, and a layer separator in which the layer separation of a mixture of a liquefied primary alcohol and water into an organic layer and an aqueous layer is performed, wherein one or more lines through which recirculated primary alcohol from the flash drum and the layer separator flows are connected to an upper portion of the column. According to the present invention, a coolant usage amount can be reduced and a rheological problem can be eliminated since a liquid phase and a gas phase coexist in a pipe.

Diester-based material production unit and diester-based material production system including the same

Provided is a plasticizer composition, comprising: two or more kinds of terephthalates of the same carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is the same; and one or more kinds of terephthalates of a different carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is different, the different carbon number type comprises a higher alkyl and a lower alkyl, the higher alkyl is selected from alkyl groups having a carbon number of 8 or less, and the lower alkyl is selected from alkyl groups having a carbon number of 5 or more.

The present disclosure relates to a continuous production method of a diester-based material in a continuous production process comprising a reaction part in which a total of N reaction units from a first reaction unit to an N-th reaction unit are connected in series. The method comprising the step of feeding dicarboxylic acid and a primary alcohol, wherein the feed of the primary alcohol is divided into front-end feed of being fed into a first reaction unit and rear-end feed of being fed into one or more reaction units selected among from a second reaction unit to an N-th reaction unit, wherein the amount of the rear-end feed is 5 to 80 wt % based on the total feed amount of the primary alcohol into a reaction part, and the N is an integer of 3 to 6. According to the present invention, it is possible to ensure the ease of process operation through reducing the amount of reflux compared to a typical batch process and reducing the volume of steam for heating a reactor, and to ensure the economic feasibility of a product through saving energy.

Continuous production method of diester-based material

The present disclosure relates to a plasticizer composition characterized in having alkyl groups derived from an isomer mixture of hexyl alcohol with the degree of branching of less than 2.0 as a cyclohexane triester. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties may be maintained to equal or better levels, migration and loss properties and plasticization efficiency may keep balance, and light resistance and heat resistance may be markedly improved.

Cyclohexane triester-based plasticizer composition and resin composition including the same

A neutralization/water separation device for an esterified product including: a neutralization tank in which a crude product mixture containing alcohol and an ester compound, a neutralizing agent, and water are put to produce a neutralized mixture; a water separation tank disposed below the neutralization tank to divide the neutralization mixture into a floating layer and an aqueous layer; a partition wall extending downward from a ceiling of the water separation tank to provide a lower passage in the water separation tank; and a transfer line that transfers the neutralized mixture from the neutralization tank to the water separation tank, where the water separation tank includes: a first water separation part into which the neutralized mixture is introduced from the neutralization tank through the transfer line; and a second water separation part into which the neutralized mixture is introduced from the first water separation part through the lower passage, where the first water separation part and the second water separation part are partitioned by the partition wall.

Neutralization/water separation device for esterified product and neutralization/water separation method for esterified product

A plasticizer composition including a citrate-based material and an epoxidized oil, and the plasticizer composition capable of maintaining an excellent plasticization efficiency and providing an improved mechanical properties and stress resistance when compared with conventional phthalate-based plasticizer products.

Growing community of inventors

Daejeon, South Korea

Hyun Kyu Kim