Lg Chem, Ltd

Hyun Jee Kwon

Ki Soo Lee

Heon Yong Kwon

Dae Sik Hong

Eun Young Shin

Sung Min Lee

Jin Young Lee

Sung Ho Park

Se Young Kim

Seungmi Lee

Sol Cho

Oh Joo Kwon

Poeun Kim

Yongwoo Kwon

Yu Taek Sung

Jung Won Lee

Seung Mi Lee

Dong Hoon Jeong

Myung Han Lee

Sung Hyun Park

Young Suk You

Yong Ho Lee

Dae Hwan Kim

Eun Ji Shin

Yi Young Choi

Seul Ki Im

Eun Kyoung Song

Jong Hyun Kim

Min Seok Cho

Cheolhwan Jeong

Jae Hoon Choi

Po Eun Kim

Yong Woo Kwon

A supported metallocene catalyst can include a silica-based carrier and an aluminum alkyl halide, a cocatalyst compound, and a metallocene compound supported in the silica-based carrier. The aluminum alkyl halide is supported at higher rate on the surface of the silica-based carrier than inside the pores, and the cocatalyst compound is supported at higher rate inside the pores of the silica-based carrier than on the surface of the silica-based carrier. Such a supported metallocene catalyst can be prepared by: (i) supporting an aluminum alkyl halide in a silica-based carrier; (ii) supporting a cocatalyst compound in the silica-based carrier in which the aluminum alkyl halide is supported; and (iii) supporting a metallocene compound in the carrier in which the aluminum alkyl halide and the cocatalyst compound are supported. Such a supported metallocene catalyst can be used to polymerize polyolefins with excellent activity and polyolefin with a uniform powder morphology.

Method for preparing supported metallocene catalyst, supported metallocene catalyst, and method for preparing polyolefin using the same

The present disclosure provides a hybrid supported metallocene catalyst useful for preparing a polyethylene copolymer exhibiting excellent process stability and high polymerization activity in ethylene polymerization, and excellent mechanical properties by high comonomer incorporation. The hybrid supported metallocene catalyst comprises at least one first metallocene compound selected from compounds represented by the following Chemical Formula 1; and at least one second metallocene compound selected from compounds represented by the following Chemical Formula 2:(CpR)(CpR)MQ  [Chemical Formula 1]

Hybrid supported metallocene catalyst and process for preparing polyethylene copolymer using the same

The present invention relates to: a method for producing a metallocene-supported catalyst, the method including (1) a step of producing a reaction solution 1 by reacting one or more metallocene compounds with one or more co-catalyst compounds, (2) a step of performing supporting by mixing a support with the reaction solution 1, (3) a step of producing a reaction solution 2 by reacting one or more metallocene compounds with one or more co-catalyst compounds, and (4) a step of mixing the reaction solution 2 with the supporting material of the step (2); and a metallocene-supported catalyst produced by the same.

Method for producing metallocene-supported catalyst and metallocene-supported catalyst

The present disclosure provides a hybrid supported metallocene catalyst useful for preparing a polyethylene copolymer capable of producing an mLLDPE shrink film having excellent shrinkage and processability with excellent mechanical properties, and a process for preparing a polyethylene copolymer using the same. The hybrid supported metallocene catalyst comprises at least one first metallocene compound selected from compounds represented by the following Chemical Formula 1 and at least one second metallocene compound selected from compounds represented by the following Chemical Formula 2:

A catalyst composition, a method of preparing a polyolefin including the same, and a polyolefin prepared from the same are disclosed herein. In some embodiments, a catalyst composition comprises a first transition metal compound represented by Chemical Formula 1, and a second transition metal compound represented by Chemical Formula 2, wherein a molar ratio of the first transition compound to the second transition metal compound ranges from 1:0.3 to 1:3.5. The catalyst composition is capable of preparing a polyolefin having excellent mechanical stability, while exhibiting excellent process stability and high polymerization activity during the preparation of a polyolefin in a slurry process.

Catalyst composition and method for preparing polyolefin using the same

Provided are a novel metallocene-supported catalyst and a method of preparing a polyolefin using the same. The metallocene-supported catalyst according to the present disclosure may be used in the preparation of polyolefins, it may have excellent activity and excellent reactivity with comonomers, and it may prepare olefinic polymers having a high molecular weight and a low molecular weight.

Metallocene-supported catalyst and method of preparing polyolefin using the same

The present invention provides a hybrid supported catalyst capable of easily preparing an olefin polymer capable of having improved melt strength even while having appropriate molecular weight distribution, and thus having improved bubble stability and exhibiting excellent blown film processability, and a method for preparing an olefin polymer using the same.

Hybrid supported catalyst

The present disclosure relates to a method for preparing a supported hybrid metallocene catalyst, and the catalyst is prepared by supporting a first metallocene compound, supporting a cocatalyst by a separate-input method in which primarily adding a part at 100&#xb0; C. to 150&#xb0; C. and secondarily adding the rest at &#x2212;5&#xb0; C. to 40&#xb0; C., and then supporting a second metallocene compound, thereby improving a supporting rate of the cocatalyst in the supported catalyst and maintaining high catalytic activity. Therefore, the present disclosure can effectively prepare a polyolefin with improved processability which exhibits increased molecular weight distribution while having high morphology (reduced fine powder), high bulk density and improved settling efficiency.

Method for preparing supported hybrid metallocene catalyst

The present disclosure provides a supported hybrid catalyst which facilitates the preparation of polyolefins having improved bubble stability and exhibiting excellent processability for a blown film while maintaining high transparent haze and improved melt strength, and a method for preparing the same.

Supported hybrid catalyst

The present invention relates to an olefin polymer and a preparation method thereof. The olefin polymer exhibits excellent mechanical strength and high processability, and thus is expected to be utilized as a material for various products. Particularly, the olefin polymer can be stably produced into films by a melt-blowing process and thus is expected to be usefully used as a material for products prepared by a melt-blowing process.

Olefin polymer and preparation method thereof

The present invention provides an olefin polymer in which LCB (long chain branch) is introduced into mLLDPE (metallocene linear low-density polyethylene) to control the storage modulus, whereby the olefin polymer has excellent bubble stability and processing load characteristics and exhibits excellent processability during preparation of a film, and further has excellent mechanical properties and transparency.

Olefin polymer and method for preparing same

The present invention relates to a supported hybrid catalyst and a method for preparing olefin polymer using the same. Using the supported hybrid catalyst, olefin polymer that maintains excellent mechanical strength of olefin polymer polymerized with the existing metallocene catalyst, but exhibits remarkably improved processibility compared to the existing olefin polymer, can be provided.

Supported hybrid catalyst and method for preparing olefin polymer using the same

The present invention provides a metallocene supported catalyst that can prepare a polyolefin having excellent transparency even when processed into a film, as well as excellent processibility and mechanical properties, with high catalytic activity, and a method for preparing a polyolefin using the same.

Metallocene supported catalyst and method for preparing polyolefin using the same

The present disclosure provides a method for preparing a supported hybrid metallocene catalyst which can be used to prepare a polyolefin, a supported hybrid metallocene catalyst prepared by using the method, and a method for preparing a polyolefin using the supported hybrid metallocene catalyst.

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Daejeon, South Korea

Hyun Jee Kwon