Samsung Electro-mechanics Co., Ltd.

Hyoung Uk Kim

Jae Sung Park

Hyung Soon Kwon

Seung In Baik

Jong Han Kim

Tae Young Ham

Ki Myoung Yun

Ji Hong Jo

Eun Ha Jang

Min Young Choi

Seok Hyun Yoon

Jeong Ryeol Kim

Hee Sun Chun

Chung Eun Lee

Ji Su Hong

Je Hee Lee

Jong Ho Lee

Doo Young Kim

Kyoung Jin Cha

Chang Hoon Kim

Dong Jun Jung

Yun Jung Park

Yun Gwan Kim

Hyung Joon Jeon

Hyeg Soon An

Jeong Yun Park

Kwang Hee Nam

Ku Tak Lee

A dielectric composition and a multilayer capacitor including the same are disclosed. The dielectric composition including: a BaTiO-based main ingredient; a first auxiliary ingredient including rare earth elements; and a second auxiliary ingredient including at least one of Ba and Ca but essentially including Ba, wherein the rare earth elements include Tb and Dy, and the first auxiliary ingredient and the second auxiliary ingredient satisfy a molar content condition of 0.40<(Tb/T_RE)*(Ba+Ca)<0.93, where T_RE is a total molar content of the rare earth elements in the first auxiliary ingredient.

Dielectric composition and multilayer capacitor

A dielectric ceramic composition and a multilayer ceramic capacitor including the same are provided. The dielectric ceramic composition includes a BaTiO-based base material main ingredient and an accessory ingredient, where the accessory ingredient includes dysprosium (Dy) and niobium (Nb) as first accessory ingredients. A total content of the Dy and Nb is greater than 0.2 mol and less than or equal to 1.5 mol based on 100 mol of titanium (Ti) of the base material main ingredient.

Dielectric ceramic composition and multilayer ceramic capacitor comprising the same

A multilayer electronic component includes: a body including a dielectric layer including a plurality of dielectric grains and internal electrodes alternately disposed with the dielectric layer; and an external electrode disposed on the body and connected to the internal electrodes At least one of the plurality of dielectric grains includes Ba, Ti, Sn, and a rare earth element and has a core-dual shell structure, which includes a core, a first shell disposed on at least a portion of the core, and a second shell disposed on at least a portion of the first shell. When an average molar ratio of Sn to Ti included in the first and second shells is S1 and S2, respectively, and an average molar ratio of the rare earth element to Ti included in the first and second shells is R1 and R2, respectively, S1>S2 and R2>R1 are satisfied.

Multilayer electronic component

A multilayer capacitor includes a body including a multilayer structure in which a plurality of dielectric layers are stacked in a first direction and a plurality of internal electrodes stacked with the dielectric layer interposed therebetween and external electrodes formed outside the body and connected to the internal electrodes. The body includes an active portion and a side margin portion covering the active portion and opposing each other in a second direction, and 1<A2/M1≤1.5 and A2<A1 in which A1 is an average grain size of the dielectric layers in a central region of the active portion, A2 is an average grain size of the dielectric layers at an active boundary part of the active portion adjacent to the side margin portion, and M1 is an average grain size of the dielectric layers in a central region of the side margin portion.

Multilayer capacitor having improved reliability by adjusting grain size of dielectric layer

A multilayer electronic component includes a body including a plurality of dielectric layers, side margin portions disposed on the body, and external electrodes disposed on the body. The reliability of the multilayer electronic component is improved by controlling the contents of Si for each position of the dielectric layer and the side margin portion.

Multilayer electronic component including side margin portion having composition gradient across thickness thereof

A dielectric composition and a multilayer capacitor including the same are provided. The dielectric composition includes a BaTiO-base main component, a first subcomponent including an Nb component and a Gd component, a second subcomponent including an Mg component, and a third subcomponent including a Ba component and a Ca component. The first subcomponent is included in an amount of 4 moles or less per 100 moles of the main component. In the first subcomponent, a molar content of Nb and a molar content of Gd satisfy 0.33≤Nb/Gd, and in the third subcomponent, a molar content of Ba and a molar content of Ca satisfy 0.2≤Ca/(Ba+Ca).

A multilayer ceramic electronic component includes: a ceramic body including a dielectric layer having a main component represented by (BaCa)(Ti(Zr, Sn, Hf))O(where, 0≤x≤1, 0≤y≤0.5), and having a plurality of grains and grain boundaries disposed between the plurality of grains, and including first and second internal electrodes alternately stacked with the dielectric layer interposed therebetween; a first external electrode; and a second external electrode, wherein the dielectric layer includes a triple point in contact with three grain boundaries and a secondary phase of Si disposed inside the triple point, wherein a dispersion of an Si content at an interface between the dielectric layer and the internal electrode may be 1% by weight or less.

Multilayer ceramic electronic component

A dielectric composition includes one of BaTiO, (Ba,Ca)(Ti,Ca)O, (Ba,Ca)(Ti,Zr)O, Ba(Ti,Zr)Oand (Ba,Ca)(Ti,Sn)O, as a main component, a first subcomponent including a rare earth element, and a second subcomponent including at least one of a variable valence acceptor element and a fixed valence acceptor element. When a sum of contents of the rare earth element is defined as DT and a sum of contents of the variable valence acceptor element and the fixed valence acceptor element is defined as AT, (DT/AT)/(Ba+Ca) satisfies more than 0.5 and less than 6.0. In addition, a multilayer electronic component including the dielectric composition is provided.

Dielectric composition and multilayer electronic component including the same

A multilayer electronic component includes: a body including dielectric layers; side margin portions disposed on side surfaces of the body, respectively; and external electrodes disposed on end surfaces of the body, respectively. The body includes a capacitance forming portion including internal electrodes disposed alternately with the dielectric layers and cover portions disposed on upper and lower surfaces of the capacitance forming portion, respectively. Ga2/Ga1 is 0.8 or more and less than 1.0 and Ga2/Gc1 is 0.8 or more and less than 1.0. a1 is a central portion of the capacitance forming portion, a2 is a boundary portion between the capacitance forming portion and the cover portion in the capacitance forming portion, and c1 is a boundary portion between the capacitance forming portion and the cover portion in the cover portion. Ga1, Ga2, and Gc1 are average sizes of dielectric grains at a1, a2, and c1, respectively.

A dielectric composition includes one of BaTiO, (Ba,Ca) (Ti,Ca)O, (Ba,Ca) (Ti,Zr)O, Ba(Ti,Zr)Oand (Ba,Ca) (Ti,Sn)O, as a main component, a first subcomponent including a rare earth element, and a second subcomponent including at least one of a variable valence acceptor element and a fixed valence acceptor element. When a sum of contents of the rare earth element is defined as DT and a sum of contents of the variable valence acceptor element and the fixed valence acceptor element is defined as AT, (DT/AT)/(Ba+Ca) satisfies more than 0.5 and less than 6.0. In addition, a multilayer electronic component including the dielectric composition is provided.

A dielectric ceramic composition and a multilayer ceramic capacitor comprising the same includes a barium titanate (BaTiO)-based base material main ingredient and an accessory ingredient, and the accessory ingredient includes a third trivalent lanthanide rare earth element A and terbium (Tb) as rare earth elements, and a molar ratio (Tb/A) of a content of terbium (Tb) to the content of the trivalent lanthanide rare earth element A satisfies 0.15&#x2264;Tb/A&#x3c;0.50.

A dielectric ceramic composition includes a barium titanate-based base material main ingredient and an accessory ingredient, and the accessory ingredient includes dysprosium (Dy) and gadolinium (Gd) as first accessory ingredient elements, and a content ratio of gadolinium (Gd), based on a total content of the first accessory ingredient elements, is 25% or higher.

A multilayer capacitor includes: a body including dielectric layers and first and second internal electrodes alternately disposed with respective dielectric layers interposed therebetween; and first and second external electrodes disposed on the body to be connected to the first and second internal electrodes, respectively. The dielectric layer contains BaTiOas a main ingredient, and includes a plurality of grains and grain boundaries formed between adjacent grains, the grain boundary containing Si in an amount of 8.0 to 18.0 wt % and Al and Mg in a total content of 2.0 to 6.0 wt %.

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Suwon-si, South Korea

Hyoung Uk Kim