Chevron U.s.a. Inc.

Chevron Phillips Chemical Company LP

Exxonmobil Chemical Patents Inc.

Chevron Oronite Company LLC

Hye-Kyung Cho Timken

Huping Luo

Bong-Kyu Chang

Saleh Ali Elomari

Michael Sean Driver

Howard Steven Lacheen

Sven Ivar Hommeltoft

Joel E Schmidt

Bi-Zeng Zhan

Shawn Shlomo Winter

Tengfei Liu

Bong Kyu Chang

Thomas Van Harris

Michelle K Young

Michael John Girgis

Toni Zhang Miao

Cameron McCord

Stephen Joseph Miller

John Scott Buchanan

Jose G Santiesteban

David Lawrence Stern

Curtis Bay Campbell

Kandaswamy Jothimurugesan

William Alois Weber

Lei Ji

Ai-Fu Chang

Abdenour Kemoun

Robert A Crane

Robert Fletcher Cleverdon

Ronald Joseph Cimini

Steven Xugi Song

Christine Marie Phillips

Andrew Michael Thomas

David Anthony Stachelczyk

Mark Anthony Fernandez

Madeleine Sessions

Kenneth John Peinado

Wenyih Frank Lai

Cong-Yan Chen

Steven M Bischof

James Nathan Ziemer

Andrew Rainis

Theodorus Maesen

Kenneth D Hope

Robert W Campbell

Jeff Johns

Janine Lichtenberger

Robert C Coffin

Richard L Grove

Frank Lai

Richard Joseph Grove

Eddy Lee

Shawn Stephen Healy

Annie T Pathiparampil

Steve Sarup Mathur

Robert E Montgomery

Thomas Michael Porritt

A continuous process for transporting a waste plastic feedstock to a refinery processing unit, includes forming a solution containing (i) about 1 to about 40 wt. %, based on the total weight of the solution, of one or more waste plastic feedstocks and (ii) a recycled inert carrier fluid received from a refinery processing unit, and processing the solution comprising the one or more waste plastic feedstocks and the recycled inert carrier fluid in the presence of a catalyst under catalytic cracking conditions.

Processes for transporting waste plastics to a refinery processing unit

Provided is a composition comprising a blend of a waste plastic and a bio feedstock. Also provided is a process for preparing a stable blend of a plastic and bio feedstock which can be stored or transported if desired. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend can be passed to a conversion unit for conversion of the waste plastic and bio feedstock. The conversion process produces clean monomers for polymerization and chemical intermediates.

Blend of waste plastic with bio feed and process of preparation

Provided is a blend of a petroleum feedstock and 1-20 wt. % of plastic, based on the weight of the blend, with the plastic comprising polyethylene and/or polypropylene, and the plastic in the blend comprising finely dispersed microcrystalline particles having an average particle size of 10 micron to less than 100 microns and less than 100 ppm chloride. A process for preparing a blend of plastic and petroleum is provided, comprising mixing together a petroleum feed and a plastic comprising polyethylene and/or polypropylene and heating the mixture in the range of from 550° F. to 700° F. The blend mixture is then hot filtered and then optionally treated with a chloride removal guard bed. The resulting blend can then be cooled and stored or sent directly to a refinery conversion unit.

Process for stable blend of waste plastic with petroleum feed for feeding to oil refinery units and process of preparing same

Provided is a blend of a petroleum feedstock and 1-20 wt. % of plastic, based on the weight of the blend, with the plastic comprising polyethylene and/or polypropylene, and the plastic in the blend comprising finely dispersed microcrystalline particles having an average particle size of 10 micron to less than 100 microns, and less than 10 ppm chloride. A process for preparing a blend of plastic and petroleum is provided, comprising mixing together a petroleum feed and a plastic comprising polyethylene and/or polypropylene and heating the mixture above the melting point of the plastic, but less than 500° F. The blend mixture is then hot filtered with the resulting filtered blend mixture being heated to at least 500° F. The heated mixture can then be treated with a chloride removal guard bed. The resulting blend can then be cooled and stored or sent directly to a refinery conversion unit.

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend is passed to a refinery hydrocracking unit. A liquid petroleum gas Colefin/paraffin mixture is recovered from the hydrocracking unit. The Cparaffins and Colefins are separated into different fractions with the Colefin fraction passed to a propylene polymerization reactor, and the Cparaffin fraction passed optionally to a dehydrogenation unit to produce additional propylene. A heavy fraction can also be recovered from the hydrocracking unit and passed to an isomerization dewaxing unit to prepare base oil.

Circular economy for plastic waste to polypropylene and base oil via refinery hydrocracking unit

A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas Colefin/paraffin mixture. The Cparaffins and Colefins are separated into different fractions with a propane/propylene splitter. The Colefin fraction is passed to a propylene polymerization reactor. The Cparaffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting Colefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil.

Circular economy for plastic waste to polypropylene and lubricating oil via refinery FCC and isomerization dewaxing units

A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.

Process for the production of renewable distillate-range hydrocarbons

A process for producing high octane alkylate is provided. The process involves reacting isobutane and ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.

Ionic liquid alkylation of isobutane with ethylene to produce alkylate

A process of making a silica-alumina composition having improved properties is provided. The process includes (a) mixing an aqueous solution of a silicon compound and an aqueous solution of an aluminum compound and an acid, while maintaining a pH of the mixed solution in a range of 1 to 3, and obtaining an acidified silica-alumina sol; (b) adding an aqueous solution of a base precipitating agent to the acidified silica-alumina sol to a final pH in a range of 5 to 8, and co-precipitating a silica-alumina slurry, wherein the base precipitating agent is selected from ammonium carbonate, ammonium bicarbonate, and any combination thereof; (c) optionally, hydrothermally aging the silica-alumina slurry to form a hydrothermally aged silica-alumina slurry; and (d) recovering a precipitate solid from the silica-alumina slurry or the hydrothermally aged silica-alumina slurry, wherein the precipitate solid comprises the silica-alumina composition.

Amorphous silica-alumina composition and method for making the same

Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally pyrolysis wax comprising a naphtha/diesel fraction and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC feed pretreater unit. A heavy fraction is recovered and sent to a refinery FCC unit, from which a Colefin/paraffin mixture fraction is recovered, which is passed to a steam cracker for ethylene production. In another embodiment, a propane fraction (C) is recovered from a propane/propylene splitter and passed to the steam cracker.

Circular economy for plastic waste to polyethylene via refinery FCC feed pretreater and FCC units

Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC unit from which a liquid petroleum gas C-Colefin/paraffin mixture fraction is recovered. The liquid petroleum gas C-Colefin/paraffin mixture fraction is passed to a refinery alkylation unit, with a propane and butane fraction recovered from the alkylation unit. The propane and butane fraction is then passed to a steam cracker for ethylene production. In another embodiment, a naphtha fraction (C-C) is recovered from the alkylation unit and passed to the steam cracker. In another embodiment, a propane/propylene fraction (C-C) is recovered from the FCC and passed to the steam cracker.

Circular economy for plastic waste to polyethylene via refinery FCC and alkylation units

A process is provided for producing a liquid hydrocarbon material suitable for use as a fuel or as a blending component in a fuel. The process includes co-processing a pyrolysis oil derived from a waste plastic raw material and a biorenewable feedstock comprising triglycerides in a catalytic cracking process in a presence of a solid catalyst at catalytic cracking conditions to provide a cracking product. The cracking product may be fractionated to provide at least one of a gasoline fraction and a middle distillate fraction.

Co-processing of waste plastic pyrolysis oils and biorenewable feedstocks

Growing community of inventors

Albany, CA, United States of America

Hye-Kyung Cho Timken