Apple Inc.

UChicago Argonne, LLC

Huiming Wu

Hongli Dai

Christopher S Johnson

John David Carter

Dapeng Wang

Xiaoping Wang

Hakim H Iddir

Anh D Vu

Zhenzhen Yang

Yanjie Cui

Arthur Jeremy Kropf

Yan Li

James A Gilbert

Victor A Maroni

Arturo Gutierrez

Chi-Kai Lin

Khalil Amine

Fiona Claire Strobridge

Ali Abouimrane

Michael J Erickson

Martin Bettge

Rui Xu

Jun Lu

Akshaya K Padhi

YoungHo Shin

Fulya Dogan-Key

Ana Kircova

Methods of making such compounds, powders, and cathode active materials are described. The powders are formed of particles with specific properties: a particle size distribution with a D50 ranging from 10 μm to 20 μm, a D10 less than 8 μm, and a D99 of the particles ranges from 25 μm to 35 μm. The final compound is represented by the Formula Li(CoMnMeAl)O, wherein 0.95<α<1.05, x≤1.00, 0<y≤0.04, 0<z≤0.050, and δ≈2.

Mono-grain cathode materials

The disclosure provides a plurality of particles. Each particle may include a material comprising 0.95 to 1.30 mole fraction Li, at least 0.60 and less than 1.00 mole fraction Co, up to 10,000 ppm Al, 1.90 to 2.10 mole fraction O, and up to 0.30 mole fraction M, where M is at least one element selected from B, Na, Mg, P, Ti, Ca, V, Cr, Fe, Mn, Ni, Cu, Zn, Al, Sc, Y, Ga, Zr, Ru, Mo, La, Si, Nb, Ge, In, Sn, Sb, Te, and Ce. Each particle may also include a surface composition comprising a mixture of LiF and a metal fluoride. An amount of fluorine (F) is greater than 0 and less than or equal to 5000 ppm. The metal fluoride comprises a material selected from the group consisting of AlF, CaF, MgF, and LaF. The surface composition may also include a metal oxide comprising a material selected from the group consisting of TiO, MgO, LaO, CaO, and AlO. An amount of the metal oxide is greater than 0 and less than or equal to 20000 ppm.

Lithium fluoride-containing coatings for cathode active materials in Li-ion batteries

A cathode active material includes a plurality of cathode active compound particles and a coating disposed over each of the cathode active compound particles. The coating includes a lithium (Li)-ion conducting oxide containing lanthanum (La) and titanium (Ti).

Coatings for cathode active materials

Compounds, particles, and cathode active materials that can be used in lithium ion batteries are described herein. Methods of making such compounds, powders, and cathode active materials are described. The particles have a particle size distribution with a D50 ranging from 10 μm to 20 μm.

Compounds, particles, and cathode active materials that include lithium, cobalt, manganese, nickel, aluminum, and other elements can be used in lithium ion batteries. The cathode active materials include compounds having the general Formula (I): compound represented by Formula (I): LiCOMeMnNiAlO, as well as Formula (II): LiCOMeMnNiAlO.

Cathode active materials for lithium ion batteries

Compounds, powders, and cathode active materials that can be used in lithium ion batteries are described herein. Methods of making such compounds, powders, and cathode active materials are described.

Cathode active materials for lithium-ion batteries

Compounds, particles, and cathode active materials that can be used in lithium ion batteries are described herein. Methods of making such compounds, powders, and cathode active materials are described.

Aluminum-doped lithium cobalt manganese oxide batteries

Cathode active materials are provided. The cathode active material can include a plurality of cathode active compound particles. A coating is disposed over each of the cathode active compound particles. The coating can include at least one of ZrO, LaO, a mixture of AlOand ZrOor a mixture of AlOand LaO. The battery cells that include the cathode active material are also provided.

Oxide mixture and complex oxide coatings for cathode materials

A compound represented by LiCoMe(M1M2)O, (Formula (I)) wherein Me, is one or more of Li, Mg, Al, Ca, Ti, Zr, V, Cr, Mn, Fe, Ni, Cu, Zn, Ru and Sn, and wherein 0&#x2264;x&#x2264;0.3, 0&#x3c;y&#x2264;0.4, 0.95&#x2264;&#x3b1;&#x2264;1.4, and 1.90&#x2264;&#x3b4;&#x2264;2.10 is disclosed. Further, particles including such compounds are described.

Surface stabilized cathode material for lithium ion batteries and synthesizing method of the same

Mixed-metal oxides and lithiated mixed-metal oxides are disclosed that involve compounds according to, respectively, NiMnCoMeOand LiNiMnCoMeO. In these compounds, Me is selected from B, Na, Mg, Al, Si, K, Ca, Sc, Ti, V, Cr, Fe, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Ag, In, and combinations thereof; 0&#x2264;x&#x2264;1; 0&#x2264;y&#x2264;1; 0&#x2264;z&#x3c;1; x+y+z&#x3e;0; 0&#x2264;&#x3b1;&#x2264;0.5; and x+y+&#x3b1;&#x3e;0. For the mixed-metal oxides, 1&#x2264;&#x3b2;&#x2264;5. For the lithiated mixed-metal oxides, &#x2212;0.1&#x2264;&#x3b3;&#x2264;1.0 and 1.9&#x2264;&#x3b2;&#x2264;3. The mixed-metal oxides and the lithiated mixed-metal oxides include particles having an average density greater than or equal to 90% of an ideal crystalline density.

Cathode active materials having improved particle morphologies

A process of forming a coated cathode active material include preparing a cathode material precursor by co-precipitation; coating the cathode material precursor with an electrochemically inert coating material precursor by precipitation to form a coated cathode material precursor; lithiating the coated cathode material precursor with a lithium source material to form a lithiated coated cathode material precursor; and sintering the lithiated coated cathode material precursor to form a cathode active material coated with an electrochemically inert material.

Cathode materials for lithium ion batteries

The disclosed embodiments provide a battery cell. The battery cell includes an anode containing an anode current collector and an anode active material disposed over the anode current collector. The battery cell also includes a cathode containing a cathode current collector and a cathode active material disposed over the cathode current collector. The cathode active material has a composition represented by xLiMO&#xb7;(1-)LiCoM'O.

Growing community of inventors

San Jose, CA, United States of America

Huiming Wu