Petrochina Company Limited

Tsinghua University

Huimin Yuan

Guizhi Wang

Jianzhong Li

Ning Zhang

Jingyuan Zhang

Qian Chen

Zhixiang Zhang

Sihan Wang

Xianming Xu

Yongjun Zhang

Yong Jin

Hongxia Chen

Baojun Zhang

Deshun Zhang

Shukun Sun

Yunguang Han

Yulong Li

Fengrong Wang

Yongcheng Sun

Fangwei Li

Dawei Zhang

Dongting Kuang

Yingnan Ning

Lihua Xing

Lijun Liu

Jina Zhao

Jing Wei

Fengbo Ma

Shubao Wan

Xuli Zhai

Zhongtao Zhang

A method for preparing catalyst coating on a metal base plate comprising: thermal-spraying a layer of &#x3b1;-aluminum oxide nano-particles on a metal base plate using a high temperature flame powder spray gun, at a temperature of 2500-3500&#xb0; C. and a pressure of 0.2-1.2 MPa; coating an aluminum sol, the weight concentration of the aluminum sol aqueous solution being 2-30%, at a pH of 0.5-4, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours; immersing in an active component, the immersing temperature being 20-120&#xb0; C., the duration being 0.5-24 hours, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours. The method is suitable for the preparation of various catalyst coatings with active components.

Method for preparing catalyst coating on metal base plate

The present invention relates to a catalyst composition for ethylene oligomerization and the use thereof. Such catalyst composition includes chromium compound, ligand containing P and N, activator and accelerator; wherein the chromium compound is selected from the group consisting of acetyl acetone chromium, THF-chromium chloride and Cr(2-ethylhecanoate); general formula of the ligand containing P and N is shown as: in which R, R, Rand Rare phenyl, benzyl, or naphthyl. Ris isopropyl, butyl, cyclopropyl, cyclopentyl, cyclohexyl or fluorenyl; the activatior is methyl aluminoxane, ethyl aluminoxane, propyl aluminoxane and/or butyl aluminoxane; the accelerator is selected from the group consisting of 1,1,2,2,-tetrachloroethane, 1,1,2,2-tetrabromoethane, 1,1,2,2-tetrafluoroethane, and compounds having a formula of XRX, in which Xand Xare F, Cl, Br, I or alkoxyl, Ris alkylene or arylene group; the molar ratio of chromium compound, ligand containing P and N, activator and accelerator is 1:0.5&#x2dc;10:50&#x2dc;3000:0.5&#x2dc;10. After mixing the four components mentioned previously under nitrogen atmosphere for 10 minutes, they are incorporated to the reactor, or these four components are incorporated directly into the reactor. Then ethylene is introduced for oligomerization. Such catalyst can be used in producing 1-octene through ethylene oligomerization. It is advantageous in high catalysing activity, high 1-octene selectivity, etc. The catalytic activity is more than 1.0&#xd7;10g product&#xb7;maCr&#xb7;h, the fraction of Clinear &#x3b1;-olefin is more than 70% by mass.

Catalyst composition for ethylene oligomerization and the use thereof

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Dongcheng, China

Huimin Yuan