China Petroleum & Chemical Corporation

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

Huijie Hu

Wenbo Song

Shijun Zhang

Xiaomeng Zhang

Jie Zhang

Jinliang Qiao

Hua Yin

Meifang Guo

Fuyong Bi

Zhenjie Liu

Wenjun Wei

Dezhan Li

Hao Yuan

Qing Shao

Hao Zhang

Tao Liu

Luqiang Yu

Liying Zhang

Honghong Huang

Huan Xu

Liping Hou

Yujing Tang

Peiqian Yu

A microspheric ionomer having a cross-linked structure, a preparation method therefor, applications thereof, and a preparation system thereof. The ionomer comprises structure units A represented by formula (1), structure units B represented by formula (2), and a cross-linking structure provided by a cross-linking agent, M being separately selected from H, a metal cation, and a straight chain, a saturated alkyl of branched or ring-shaped C-C, R being H or a methyl; and metal cations are introduced to part of structure units A in the ionomer. The ionomer shows an outstanding effect on nucleation of PET, serves as a nucleating agent for PET modification, so as to obtain a corresponding PET composition. A system and method for continuously preparing maleic acid ester ionomer microspheres and cross-linked maleic acid ionomer microspheres, so as to achieve continuous preparation, washing and separation of ionomer microspheres, effectively stabilizes the separation effect, and avoids frequent start and stop operations of a centrifuge.

Microspheric ionomer having cross-linked structure, preparation method therefor, applications thereof, and preparation system thereof

The present invention relates to a propylene-butene-1 random copolymer which has a butene-1 content of 1-6 mol % and a relative dispersity of butene-1, as determined according to NMR method, of greater than 98.5%. The propylene-butene-1 random copolymer of the present invention has a high relative dispersity of butene-1, as well as better transparency and heat resistance, so that it is more suitable for packaging food that may be edible after heating. Moreover, the copolymer has a lower xylene solubles content at room temperature. In addition, the present invention further relates to a method for preparing the copolymer and to a composition and an article comprising the copolymer.

Propylene random copolymer, method for its preparation, and compositions and articles containing the same

The present invention provides a process for preparing high melt strength propylene polymer by direct polymerization, comprising that a propylene polymer with wide molecular weight distribution and containing 'very high molecular weight fraction' can be prepared by controlling the species and ratios of the external electron donors in the Ziegler-Natta catalyst system at different reaction stages according to the requirement for different molecular weight fractions in the different propylene polymerization stage of the series operation, and said polymer has excellent mechanical properties, especially with very high melt strength. The present invention also provides a propylene homopolymer with high melt strength, comprising the following features: (1) the MFR is 0.2-10 g/10 min at 230&#xb0; C. with a load of 2.16 kg; (2) the molecular weight distribution M/Mis 6-20; (3) the content of the fraction with a molecular weight higher than 5,000,000 is higher than or equal to 0.8 wt %; (4) M/Mis higher than or equal to 70. Said homopolymer can be used in the preparation of foam products, thermoforming products, biaxial stretching films, blown films and blow-molded products.

Propylene homopolymer having high melt strength and preparation method thereof

Growing community of inventors

Beijing, China

Huijie Hu