Ciba-Geigy Corporation

Basf Aktiengesellschaft

Ciba-Geigy Ag

Hubert Meindl

Dieter Strasilla

Laszlo Moldovanyi

Charles Fearnley

Peter Rohringer

Michael Bernheim

Roland Darms

Hans Wegmuller

Dieter Werthemann

Rosemarie Topfl

Walter Hungerbuhler

Peter Hindermann

Sizing agents of which some are novel and which have at least one anionic or acidic group which is optionally in the form of a salt and at least two hydrophobic substituents which each have at least 5 carbon atoms, at least two of the most adjacent hydrophobic substituents being bonded to each other with a linking member which has at least 2 hetero atoms, are particularly suitable for use, together with commercially available polymeric, cationic retention aids, in a process for sizing paper or cardboard.

Process for sizing paper with anionic hydrophobic sizing agents and

A hair-setting preparation which contains

Hair-setting preparation

Sizing agents devoid of anhydride groups, some of which are known and others are novel compounds, and which carry a single N,N-C.sub.6 -C.sub.22 alkyl(or alkenyl)amide group as hydrophobic substituent and at least one anionic group, in particular N,N-C.sub.6 -C.sub.22 dialkyl or N,N-C.sub.6 -C.sub.22 dialkenyl partial amides of a dicarboxylic acid, tricarboxylic acid or sulfocarboxylic acid, or the salts thereof, are particularly suitable, together with commercially available retention aids, for use in a process for pulp-sizing paper or cardboard at a pH of at least 6.5 of the fibre suspension, in the absence of e.g. aluminium sulfate, or in a process for surface-sizing paper.

Process for the manufacture of paper or cardboard which is sized under

Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.

Process for sizing paper or cardboard with anionic hydrophobic sizing

Sizing agents which are novel compounds and have at least one anionic or acidic group which is optionally in salt form and at least two hydrophobic substituents of which at least two of the most adjacent ones are bonded to each other with a bridging member which has at least 1 carbon atom and 2 hetero atoms, at least one sulfur atom being present as hetero atom, in particular sulfimides or bisulfimides of fatty acid derivatives, are highly suitable for use, together with commercially available retention aids, in a process for sizing paper or cardboard.

Sizing agents, which are novel compounds and contain at least one anionic or acidic sulfonylcarbonylimide group which may be in salt form and at least two hydrophobic substituents of which at least two are linked to each other through a bridge member of the formula --CO--NH--A.sub.1 --(SO.sub.2 --NH--CO).sub.t, where A.sub.1 is a divalent or trivalent aliphatic, cycloaliphatic or aromatic radical of up to 10 carbon atoms, and t is 1 or 2, are particularly suitable, together with commercially available retention aids, for use in a process for sizing paper or cardboard.

Novel copolymeric ammonium salts which are soluble or form microemulsions in aqueous surfactant systems and which can be obtained by water-in-oil emulsion polymerization or solution polymerization of a quaternary ammonium salt of the acrylic acid series and at least one other acrylic comonomer and reaction with an anionic optionally zwitterionic surfactand, ion exchange taking place, and has a molecular weight distribution of 10.sup.4 to 10.sup.9, the molecular weight of at least 5 percent by weight of the copolymer being 10.sup.7 to 10.sup.9, can be used as cosmetics, in particular as hair cosmetics, hair treated according to the invention having excellent ease of dry combing and, in particular, ease of wet combing.

Quaternary, copolymeric, high molecular weight ammonium salts based on

Novel copolymeric ammonium salts which are soluble or form microemulsions in aqueous surfactant systems and which can be obtained by water-in-oil emulsion polymerization or solution polymerization of a quaternary ammonium salt of the acrylic acid series and at least one other acrylic comonomer and reaction with an anionic optionally zwitterionic surfactant, ion exchange taking place, and has a molecular weight distribution of 10.sup.4 to 10.sup.9, the molecular weight of at least 5 percent by weight of the copolymer being 10.sup.7 to 10.sup.9, can be used as cosmetics, in particular as hair cosmetics, hair treated according to the invention having excellent ease of dry combing and, in particular, ease of wet combing.

Novel copolymeric ammonium salts which are soluble or form microemulsions in aqueous surfactant systems and which can be obtained by water-in-oil emulsion polymerization or solution polymerization of a quaternary ammonium salt of the acrylic acid series and at least one other acrylic comonomer and reaction with an anionic optionally zwitterionic surfactand, ion exchange taking place, and has a molecular weight distribution of 10.sup.4 to 10.sup.9, the molecular weight of at least 5 percent by weight of the copolymer being 10.sup.7 and 10.sup.9, can be used as cosmetics, in particular as hair cosmetics, hair treated according to the invention having excellent ease of dry combing and, in particular, ease of web combing.

Mixtures of quaternary, polymeric, high molecular weight ammonium salts,

Novel phthalimides substituted by alkenylamino groups, processes for their preparation and hot-curable mixtures which are stable on storage and contain at least one phthalimide according to the invention and a polyimide which has at least two groupings containing a C.dbd.C double bond are described. These hot-curable mixtures which are stable on storage are distinguished by improved processing characteristics, in particular a prolonged pot life, and are suitable for the production of various mouldings and especially also for the production of complicated castings.

Growing community of inventors

Riehen, Switzerland

Hubert Meindl