Degussa Aktiengesellschaft

Degussa - Huls Ag

Hubert Angert

J&uuml;rgen Glenneberg

Eugen Staab

Gustaf Goor

Holger Sauerstein

A method for producing 2-(4-methyl-3-pentenyl)anthraquinone (IHEAQ) that includes a Diels-Alder addition of naphtho-1,4-quinone and myrcene and an oxidation of the resulting adduct. The oxidation step is carried out in the presence of a solvent mixture that contains a polar and a nonpolar solvent. The oxidation takes place with air or an O -containing gas in the presence of a combination of a strong inorganic base and an organic, especially a nitrogen-containing base. The method leads to a higher space-time yield and higher product purity.

Method for producing 2-(4-methyl-3-pentenyl) anthraquinone

A cyclic anthraquinone process for producing hydrogen peroxide using at least two differently substituted 2-alkylanthraquinones and/or their tetrahydro derivatives. The working solution to be used contains (i) at least one reaction carrier from the series 2-(4-methyl-3-pentenyl) anthraquinone (IHEAQ), 2-(4-methylpentyl) anthraquinone (IHAQ) and their di- and tetrahydro derivatives such as, in particular 2-(4-methylpentyl)-&bgr;-tetrahydroanthraquinone (THIHAQ), and (ii) at least one reaction carrier from the series of the 2-(C - to C )-alkylanthraquinones, especially 2-ethylanthraquinone (EAQ), and their tetrahydro derivatives. The reaction carriers according to (i) make up 5 to 95 molar %, especially 20 to 50 molar % of all reaction carrier. The method is distinguished by greater H O capacity, improved hydrogenation kinetics and lesser susceptibility to disturbances. A method for making THIHAQ is also disclosed.

Method of producing hydrogen peroxide and reaction promoters therefor

A cyclic anthraquinone process for producing hydrogen peroxide using at least two differently substituted 2-alkylanthraquinones and/or their tetrahydro derivatives. The working solution to be used contains (i) at least one reaction carrier from the series 2-(4-methyl-3-pentenyl) anthraquinone (IHEAQ), 2-(4-methylpentyl) anthraquinone (IHAQ) and their di- and tetrahydro derivatives such as, in particular 2-(4-methylpentyl)-.beta.-tetrahydroanthraquinone (THIHAQ), and (ii) at least one reaction carrier from the series of the 2-(C.sub.1 - to C.sub.5)-alkylanthraquinones, especially 2-ethylanthraquinone (EAQ), and their tetrahydro derivatives. The reaction carriers according to (i) make up 5 to 95 molar %, especially 20 to 50 molar % of all reaction carriers. The method is distinguished by greater H.sub.2 O.sub.2 capacity, improved hydrogenation kinetics and lesser susceptibility to disturbances. A method for making THIHAQ is also disclosed.

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Coqueiral-Arancruz, Brazil

Hubert Angert