Honeywell International Inc.

Alliedsignal Inc.

Allied Corporation

The Chemours Company Fc, LLC

Hsueh Sung Tung

Daniel C Merkel

Haiyou Wang

Konstantin A Pokrovski

Rajiv R Singh

Hang Thanh Pham

Robert C Johnson

Michael Van Der Puy

Stephen A Cottrell

Ian R Shankland

Yuon Chiu

Haluk Kopkalli

Sudip Mukhopadhyay

Ryan J Hulse

Selma Bektesevic

Terris Yang

Gustavo Cerri

Addison Miles Smith

Haridasan K Nair

Jing Ji Ma

Kevin D Uhrich

Rajesh K Dubey

Alagappan Thenappan

Joshua Close

Clayton Herbert Carson

Mario Joseph Nappa

David John Williams

Mary Charlotte Bogdan

Leslie Bruce Bement

Cheryl L Bortz

Barbara A Light

Paul Gene Clemmer

Xuehui Sun

Peter B Logsdon

Steven D Phillips

Ronald Riegal

Richard E Eibeck

Shuwu Yang

Jason T Stuck

Franklin S Wong

John Stephen Bass

Rajesh Dubey

John Joseph Senetar

Bernard F Sukornick

George R Cook

Robert L Bell

Peter Scheidle

Kim M Fleming

G V Madhavan

Tadeusz Piotr Rygas

Robert Scott Wedinger

Orlando George Rodrigues

Gus Cerri

Milton Cook

Sudip Mukhopahyay

Ryan Hulse

Stephen Frederic Yates

Andrew Joseph Poss

Kane David Cook

Barry Asher Mahler

Matthew H Luly

Timothy R Demmin

Yian Zhai

Michael G Gatter

Jeffrey Warren McKown

Willie Perez

Charles Francis Swain

Robert A Smith

David J Friedland

Lynn E McCurry

John L Welch

Jingji Ma

Ron Joseph Roof

Michael Vanderpuy

Lois Anne Ellis

Ralph John Borowski

Lucas Peter Labuda

Jeffrey Ball

B V Bindu Madhavan

Philip L Da Prato

Lois Anne Short Ellis

Jeffrey A Ball

Susan A Ferguson

G V Bindu Madhavan

Nemesio Rogelio Viso

Stanley Michael Jaskot

Jay Philip Friedenson

Zenart Joseph Dziadyk

Daniel Chistopher Merkel

Peter H Sheidle

David Goldschmidt

Richard Udy

George D Lockyer

Chad L Marks

Kevin D Ulrich

Fang Huang Tu

Haiyoul Wang

Robert Johnson

The present invention relates, in part, to an alpha-alumina support for a hydrogenation catalyst useful in hydrogenating fluoroolefins. In certain aspects, it relates to a method for hydrogenating a compound by contacting an olefin reactant having at least one carbon-fluorine bond, with a supported hydrogenation catalyst. The reaction results in a product that includes a hydrogenated derivative of the olefin. In certain embodiments, the supported hydrogenation catalyst includes a zero-valent metal disposed on an alpha-alumina support.

Hydrogenation catalyst

The invention relates to a process for reducing the concentration of a fluorinated alkyne impurity, such as 3,3,3-trifluoropropyne (TFPY), in 2,3,3,3-tetrafluoropropene (HFO-1234yf) which comprises contacting such a mixture with a caustic material, such as sodium hydroxide (NaOH), under conditions effective to reduce the concentration of the fluorinated alkyne impurity, including in some practices reducing the concentration by at least about 50%.

Process for reducing 3,3,3-trifluoropropyne in 2,3,3,3-tetrafluoropropene

The invention provides a reactor comprising a reaction chamber having a catalytic surface in contact with reactants in said chamber, and a source for passing electrical current through said catalytic surface. The reactor can be used for dehydrohalogentation reactions, such as dehydrochlorination of HCFC-244bb to HFO-1234yf and for reactions where zero valent metals are employed for catalysis. The invention further provides a process to prepare HFO-1234yf from HCFC-244bb using an electrically heated reaction chamber.

Dehydrohalogenation reactor and process

A process for making a fluorinated olefin having the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms, preferably carried out in the presence of a catalyst selected from the group consisting of (i) one or more metal halides, (ii) one or more halogenated metal oxides, (iii) one or more zero-valent metals/metal alloys, (iv) a combination of two or more of the foregoing.

Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons

A process for the simultaneous removal of iron and phosphate ions from a chlorinated hydrocarbon waste stream, such as a waste stream derived from a process for manufacturing 1,1,1,3,3-pentachloropropane (HCC-240fa) and/or 1,1,1,3-tetrachloropropane (HCC-250fb). The waste stream contains at least one of chlorinated hydrocarbons, tributyl phosphate (TBP) and/or triethyl phosphate (TEP), iron, FeCland/or FeCl, a TBP-FeClcomplex and/or a TBP-FeClcomplex, and a TEP-FeClcomplex and/or a TEP-FeClcomplex, and is subjected to thermal oxidation to generate a second, aqueous waste stream containing at least one of hydrogen chloride (HCl), FeCland/or FeCl, and HPO. The second waste stream is exposed to a base to generate a precipitate including at least one insoluble compound selected from the group consisting of FePO, Fe(OH), and Ca(PO), and the precipitate is separated from the second waste stream to produce a liquid phase including only trace amounts of iron and phosphate ions.

Process for the removal of iron and phosphate ions from a chlorinated hydrocarbon waste stream

Disclosed is a composition comprised of at least one compound selected from 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoro-1-propene and 1-chloro-3,3,3-trifluoropropene and halogenated impurity selected from the group consisting of HFO-1141 (CH&#x2550;CHF), HCFO-1140 (CH&#x2550;CHCl), and HCFO-1131 (CH&#x2550;CFCl and/or trans/cis-CHF&#x2550;CHCl) and combination thereof, said halogenated impurity being present in said composition in an amount of 50 ppm or less.

Methods for removing halogenated ethylene impurities in 2, 3, 3, 3-tetrafluoropropene product

A process for the manufacture of haloalkanes, or more particularly to a process for the manufacture of 1,1,1,3,3-pentachloropropane (HCC-240fa) and/or 1,1,1,3-tetrachloropropane (HCC-250fb). The process includes (a) mixing a catalyst, co-catalyst and a haloalkane starting material under conditions suitable to produce a homogeneous mixture; (b) reacting the homogeneous mixture with a haloalkene and/or alkene starting material under conditions suitable to produce a haloalkane product stream; and (c) recovering a haloalkane product from said product stream.

Process for the manufacture of 1,1,1,3,3-pentachloropropane

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

Process for producing chlorotrifluoroethylene

Disclosed are processes for producing halogenated olefins, and preferably tetrafluorinated propene(s), from one or more alkanes having both fluorine substituents and non-fluorine substituents, preferably with a high degree of conversion and selectivity. Preferably the process comprises the use of a catalyzed reaction in which the catalyst is selected from the group consisting of activated carbons halogenated mono- and di-valent metal oxides, mono- and di-valent Lewis acid metal halides, zero-valent metals, and combinations of these.

Processes for selective dehydrohalogenation of halogenated alkanes

The present invention discloses a manufacturing process to produce high purity 1234yf from 245eb, which preferably includes the removal of impurities present in 245eb raw material, the dehydrofluorination of 245eb, and the removal of impurities present in final crude product. The disclosed manufacturing process allows the production of a 1234yf product with lower the levels of 1225ye and/or trifluoropropene, preferably in amounts of less than about 500, and 50 ppm, respectively.

Process for producing 2,3,3,3-tetrafluoropropene

In certain aspects, the present invention relates to methods for increasing the cost efficiency and safety of the hydrogenation of a fluorinated olefin by controlling the reaction conditions and parameters. In further aspects, the hydrogenation reaction is provided in a two stage reaction wherein the reactant amounts, temperature and other parameters are controlled such that the conversion percentage, selectivity, and reaction parameters are all within commercially acceptable levels.

Process for the manufacture of fluorinated olefins

The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefin starting reagents, particularly, 1,1,2,3-tetrachloropropene (1230xa), oligomerization/polymerization of such starting reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that providing one or more organic co-feed to the fluooolefin starting stream reduces such oligomerization/polymerization and improves catalystic stability.

Provided are azeotropic and azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).

Azeotrope-like composition of 2-chlor0-3,3,3-trifluoropropene (HCFC-1233xf) and hydrogen fluoride (HF)

Provided are azeotropic or azeotrope-like mixtures of 1,3,3,3-tetrachloroprop-1-ene (HCO-1230zd) and hydrogen fluoride. Such compositions are useful as a feed stock in the production of HFC245fa and HCFO1233zd.

Azeotropic compositions of 1,3,3,3-tetrachloroprop-1-ene and hydrogen fluoride

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Getzville, NY, United States of America

Hsueh Sung Tung