Huntsman Petrochemical Corporation

Howard M Stridde

Curtis M Elsik

R Scott Tann

Alan J Stern

Samir S Ashrawi

Joe C Arzola

John M Larkin

Terry L Renken

James R Machac, Jr

David C Lewis

Andrew Francis Kirby

Christopher J Whewell

David Ferguson

Jeffrey J Vipond

In agricultural practice it is known to use emulsifiable oils (commonly referred to a Crop Oil Concentrates, COC) as bioefficacy enhancers for pesticides, especially herbicides. Cationic surfactants are widely known to be particularly effective bio-active enhancers for herbicides, especially for glyphosate-type herbicides. The present invention includes two novel aspects: 1) While the vast majority of COCs are petroleum-based paraffinic oils or esterified seed oils, this invention embodies a new oil phase, a hydrocarbon oil such exemplified by EXXON-MOBIL'S D-130, which when combined with the surfactants described herein, exhibits surprising enhancement of herbicidal activity in field tests; and 2) COC's are designed to form stable emulsions in water. The combination of cationic surfactants and phosphate esters in this invention not only form very stable emulsions in water, but, surprisingly, also form extremely stable emulsions in concentrated liquid fertilizers, including 32-0-0 fertilizer.

Crop oil concentrate adjuvants containing amine surfactants

A pesticide composition exhibiting streaming birefringence and methods for making the pesticide composition are disclosed. In one embodiment, the pesticide composition comprises an active ingredient and a surfactant adjuvant.

Pesticide formulation with streaming birefringence

Embodiments of the present invention disclose an agricultural composition that is a field ready spray or a tank mix that includes at least one isethionic acid salt neutralized with sodium, at least one agriculturally active ingredient, and at least one surfactant.

Isethionic acid salts in field ready spray and tank mixes

Embodiments of the present invention disclose an agricultural composition that is a registerable, stable agricultural formulation that includes at least one nitrogen containing isethionic acid salt, at least one plant protection product, at least one surfactant and optionally at least one inert ingredient.

Nitrogen containing isethionic acid salt in registerable, stable agricultural formulations

Embodiments of the present invention disclose an agricultural composition that is a field ready spray or a tank mix that includes at least one nitrogen containing isethionic acid salt, at least one agriculturally active ingredient, and at least one surfactant.

Nitrogen containing isethionic acid salts in field ready spray and tank mixes

A composition includes an agricultural component in an amount of at least about 27% by weight and a solvent composition in an amount not greater than about 55% by weight. The solvent composition includes an amide having a structure of Formula I: wherein Rcomprises a Cto Chydrocarbon group, and wherein Rand Rcomprise a Cor higher hydrocarbon group.

Low odor, low volatility solvent for agricultural chemicals

An agrochemical composition includes a homogeneous single-phase liquid crystal in thermodynamic equilibrium. The agrochemical composition can be a surfactant composition or a pesticide composition. The surfactant composition is a blend of surfactants, whereas a pesticide composition has an active ingredient and one or more surfactant adjuvants. A pesticide composition, or a surfactant composition in combination with an active ingredient, may be used to control pests.

Liquid crystal agrochemical formulations

Provided herein are compositions of matter which contain an agriculturally-active material in combination with an agricultural adjuvant and at least one alkylene carbonate. The presence of an alkylene carbonate in such formulations increases the efficacy of herbicides and pesticides used in controlling unwanted foliage and insects in commercial agriculture.

Alkylene carbonate adjuvants

Surfactant adjuvants that improve the bioefficacy of herbicides by combining known surfactancy, or wetting characteristics, of sulfosuccinate or sulfosuccinamate-based surfactants, with the proven bioefficiacy characteristics of alkoxylated amine-based surfactants. The surfactant adjuvants contain an amine-based surfactant, and a sulfosuccinate or sulfosuccinamate-based surfactant. The surfactant adjuvants are combined with herbicidal active ingredients, and optionally, one or more formulation aids to form herbicide compositions that have a reduced tendency to cause eye and skin irritation and can be used to control unwanted weeds or vegetation.

Surfactant adjuvants useful in herbicide compositions

Surfactants that are expected to further improve the bioefficacy of herbicides. The surfactants comprise esterified alkoxylated polyether diamines, alkoxylated polyether diamines, and mixtures thereof. The present invention also provides for herbicide compositions that contain the surfactants of the present invention. The herbicide compositions comprise a herbicidal active ingredient, a surfactant of the present invention, and optionally, one or more formulation aids. The present invention additionally provides for a method of controlling unwanted weeds or vegetation using the herbicide compositions of the present invention.

Polyether diamine&mdash;based surfactant adjuvants and compositions thereof

Etheramine alkoxylates are described which have the formula: ##STR1## where R.sup.1 is a straight or branched alkyl, aryl or alkylaryl group of 6 to 22 carbon atoms; R.sup.3 are independently hydrogen or C.sub.1 to C.sub.3 alkyl; m averages from about 1 to about 20; and x and y each independently average from about 0 to 30, where x+y averages from about 2 to about 60. These etheramine alkoxylates have surfactant properties. Further, they may be quaternized to make other compounds which will have useful surfactant properties.

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George West, TX, United States of America

Howard M Stridde