The Goodyear & Tire Rubber Company

Howard K Foley

David A Hutchings

Paul Harry Sandstrom

Terry C Neubert

The invention relates to a method of preparing a composite suitable as an oxidizing component in a redox aqueous emulsion polymerization initiator starting with the relatively harsh oxidation of p-diisopropylbenzene with oxygen and involving a manipulative separation procedure for obtaining the effective oxidizing component. The invention also relates to the oxidizing component, the redox polymerization initiator and to the aqueous emulsion polymerization of selected unsaturated monomers.

Redox catalyst oxidant, catalyst and polymerization therewith

Redox catalyst oxidant, preparation, catalyst and polymerization

A method of producing a polymeric material comprised of polymerizing at least one unsaturated organic compound in an aqueous emulsion in the presence of a free radical generating redox catalyst comprised of a reducing component and an oxidizing component. Said oxidizing component is a composite prepared by (A) obtaining the oxidation product of reacting p-diisopropylbenzene with oxygen and (B) removing a major portion of resulting p-diisopropylbenzene hydroperoxide and unreacted monomers therefrom to effect a concentration of the remainder of the byproducts therein.

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Cuyahoga Falls, OH, United States of America

Howard K Foley