Fuelcell Energy, Inc.

Exxonmobil Technology and Engineering Company

Hossein Ghezel-Ayagh

Fred C Jahnke

Carla S Pereira

Rodrigo F Blanco Gutierrez

Stephen Jolly

Carl A Willman

Mohammad Farooque

Everett J O'Neal

Lu Han

Keith E Davis

Eric B Shen

Timothy M Healy

Frank J Dobek, Jr

Gabor Kiss

Chao-yi Yuh

Timothy Andrew Barckholtz

Abdelkader Hilmi

Heather A Elsen

Timothy C Geary

George P Berntsen

Jonathan Rosen

Jonathan Malwitz

Anthony John Leo

Robert Sanderson

James B Walzak

Zhao-Hui Wang

Frank J Chimbole, Jr

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced COutilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

Reforming catalyst pattern for fuel cell operated with enhanced COutilization

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-COgas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-COflue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of COreaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

Steam methane reforming unit for carbon capture

A fuel cell system includes: a first fuel cell including a first anode and a first cathode, wherein the first anode is configured to output a first anode exhaust gas; a first oxidizer configured to receive the first anode exhaust gas and air from a first air supply, to react the first anode exhaust gas and the air in a preferential oxidation reaction, and to output an oxidized gas; a second fuel cell configured to act as an electrochemical hydrogen separator, the second fuel cell including: a second anode configured to receive the oxidized gas from the first oxidizer and to output a second anode exhaust gas, and a second cathode configured to output a hydrogen stream; and a condenser configured to receive the second anode exhaust gas and to separate water and CO.

Molten carbonate fuel cell anode exhaust post-processing for carbon dioxide capture

Molten carbonate fuel cells (MCFCs) are operated to provide enhanced COutilization. This can increase the effective amount of carbonate ion transport that is achieved. The enhanced COutilization is enabled in part by operating an MCFC under conditions that cause transport of alternative ions across the electrolyte. The amount of alternative ion transport that occurs during enhanced COutilization can be mitigated by using a more acidic electrolyte.

Operation of molten carbonate fuel cells with enhanced COutilization

Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated COutilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated COutilization.

Fuel cell staging for molten carbonate fuel cells

An anode of a fuel cell has an anode current collector defining an inlet configured to receive fuel gas and an outlet configured to output the fuel gas, a barrier that divides an active area of the anode current collector into a first area and a second area, and a flow passage configured to allow a flow of fuel gas from the inlet through the first area and the second area to the outlet. An obstacle is located in the flow passage in an inactive area of the anode current collector and is configured to change a flow direction of the fuel gas in the flow passage from the first area to the second area to achieve intra-cell mixing of the fuel gas.

Fuel cell anode flow field design configurations for achieving increased fuel utilization

A power production system includes a fuel cell separation system configured to receive a flue gas and to produce electrical power therefrom; a flue gas polishing system positioned upstream of the fuel cell separation system and configured to remove contaminants in the flue gas; a flue gas analyzer configured to measure in real-time an amount of the contaminants in the flue gas; and a plant control system operatively coupled to the flue gas polishing system, the flue gas analyzer, and the fuel cell separation system and configured to adjust operational parameters of the flue gas polishing system.

In-situ monitoring of flue gas contaminants for fuel cell systems

A fuel cell system includes a first fuel cell having a first anode and a first cathode, wherein the first anode is configured to output a first anode exhaust gas. The system further includes a first oxidizer configured to receive the first anode exhaust gas and air from a first air supply, to react the first anode exhaust gas and the air in a preferential oxidation reaction, and to output an oxidized gas. The system further includes a second fuel cell configured to act as an electrochemical hydrogen separator. The second fuel cell includes a second anode configured to receive the oxidized gas from the first oxidizer and to output a second anode exhaust gas, and a second cathode configured to output a hydrogen stream. The system further includes a condenser configured to receive the second anode exhaust gas and to separate water and CO.

Molten carbonate fuel cell anode exhaust post-processing for carbon dioxide

A fuel cell system includes an anode configured to output an anode exhaust stream comprising hydrogen, carbon dioxide, and water; and a membrane dryer configured to receive the anode exhaust stream, remove water from the anode exhaust stream, and output a membrane dryer outlet stream. The membrane dryer includes a first chamber configured to receive the anode exhaust stream; a second chamber configured to receive a purge gas; and a semi-permeable membrane separating the first chamber and the second chamber. The semi-permeable membrane is configured to allow water to diffuse therethrough, thereby removing water from the anode exhaust stream. The membrane dryer may further be configured to remove hydrogen from the anode exhaust stream.

System and method for removing water and hydrogen from anode exhaust

A fuel cell system includes a fuel cell having an anode configured to receive anode feed gas and output anode exhaust, and a cathode configured to receive cathode feed gas and output cathode exhaust. The system further includes a pressurizing assembly downstream from the anode and an oxidizer downstream from the anode. The cathode feed gas is the anode exhaust that has been compressed in the pressurizing assembly and reacted with air in the oxidizer.

Pressure balancing of anode and cathode in a fuel cell system

A power producing system adapted to be integrated with a flue gas generating assembly, the flue gas generating assembly including one or more of a fossil fueled installation, a fossil fueled facility, a fossil fueled device, a fossil fueled power plant, a boiler, a combustor, a furnace and a kiln in a cement factory, and the power producing system utilizing flue gas containing carbon dioxide and oxygen output by the flue gas generating assembly and comprising: a fuel cell comprising an anode section and a cathode section, wherein inlet oxidant gas to the cathode section of the fuel cell contains the flue gas output from the flue gas generating assembly; and a gas separation assembly receiving anode exhaust output from the anode section of the fuel cell and including a chiller assembly for cooling the anode exhaust to a predetermined temperature so as to liquefy carbon dioxide in the anode exhaust, wherein waste heat produced by the fuel cell is utilized to drive the chiller assembly.

Power producing gas separation system and method

A hybrid fuel cell system comprising a high temperature fuel cell having an anode section and a cathode section, a gas turbine comprising a compressor cycle for compressing a supply gas and an expansion cycle for expanding one of heated compressed supply gas and a second gas derived from the compressed supply gas to provide mechanical energy to an induction machine, and an induction machine for converting mechanical energy to electrical energy and adapted to output an electrical output.

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New Milford, CT, United States of America

Hossein Ghezel-Ayagh