Metallgesellschaft Aktiengesellschaft

Horst Seidel

Hans J Weiss

Norbert Magedanz

Wolfgang Fennemann

Hermann Schmidt

Erich Minzl

Horst Dahlmann

Rolf Bothe

A process is disclosed for the regeneration of pickling solutions which contain ZrF.sub.4 by addition of a Na compound in which a charge of the pickling solution to be regenerated is analyzed and heated. The amount of Na required for the regeneration is determined in each case and is admixed with intense stirring. Then the mixture is cooled, the precipitated NaZrF compounds are separated and a regenerated pickling solution is recovered.

Method of regenerating ZrF.sub.4 pickling solutions

In a process of recovering oil from oil-containing minerals on a traveling grate, hot gases are passed through the bed in a retorting zone, oil is separated from the retort gases in a separating stage, solid carbon in the retorted bed is burnt in a succeeding combustion zone by means of oxygen-containing gases passed through, gases from which the oil has been removed in the separating zone are passed through the bed in a succeeding cooling zone and the heated gases are recycled to the retorting zone. To recover maximum quantities of oil and energy with a low expenditure, the solid carbon in the top layer of the bed is ignited by means of an ignition furnace at the beginning of the combustion zone, oxygen-containing gases are sucked through the bed thereafter to cause the burning zone to move through the bed, preferably the rate at which said oxygen-containing gases (19) are sucked through the bed (3) is so controlled that the bed is heated to the highest possible temperature by the combustion of carbon, a partial stream of the gases leaving the separating stage is heated by an indirect heat exchange with the exhaust gases from the combustion zone and is passed through the bed in the cooling zone and is further heated there and is then recycled to the retorting zone, and a partial stream of the gases leaving the separating zone is discharged.

Process of recovering oil from oil-containing materials

Oil-containing materials and part of the hot burnt material which is available after the combustion of solid carbon are charged into a retorting shaft reactor and the oil-containing mineral in the mixture is heated to the retorting temperature. For a processing even of minerals consisting of coarse lumps at high throughput rates and with a high oil yield, part of the retorting is effected in the retorting shaft reactor, the mineral from the retorting reactor is charged onto a traveling grate, the remaining retorting is effected in an after-retorting zone, in which inert or reducing gases are passed through the material, the gases from the retorting reactor and from the after-retorting zone are supplied to the separating stage and oil is removed from said gases in the separating stage, the retorted material is moved on the traveling grate to a combustion zone, the solid carbon in the surface of the bed is ignited at the beginning of the combustion zone, oxygen-containing gases are then sucked through the bed to cause the burning zone to move through the bed, the rate at which said oxygen-containing gases are sucked through the bed is preferably so controlled that the bed is heated to the highest possible temperature by the combustion of solid carbon, the burnt mineral is discharged from the traveling grate and part of the burnt material is recycled to the retorting reactor.

Process of recovering oil from oil-containing minerals

A process is disclosed for cleaning waste gases generated in an at least partially covered movable grate-type sintering line, said sintering line comprising an ignition zone, a sintering zone and a burning zone, wherein waste gases generated in the burning zone are returned to the sintering zone, passed through the sinter charge and at least those waste gases emerging from the last third of the sintering zone are scrubbed after passage through the charge.

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Frankfurt am Main, Germany

Horst Seidel