Rohm Gmbh

Roehm Gmbh Chemische Fabrik

Rohm Gmbh Chemische Fabrik

Other

Huls Aktiengesellschaft

Roehm Gmbh & Co Kg

Roehm Gmbh

Rohn Gmbh

Rphm Gmbh

Horst Pennewiss

Heinz Jost

Helmut Knoell

Hermann Plainer

Clemens Auschra

Gerhard Markert

Juergen Masanek

Michael Mueller

Roland Schweder

Reiner Schnee

Juergen Omeis

Claudia Beyer

Herbert Fink

Hans Trabitzsch

Waldemar Schleier

Ruediger Jelitte

Juergen Gebhardt

Juergen Jakob

Helmuth Knoell

Rainer Benda

Hellmuth Knoell

Peter Neudoerfl

Jaroslaw Monkiewicz

Klaus Lehmann

Roland Streck

Peter Quis

Winfried Wunderlich

Dieter Kraemer

Hans Guenther Wey

Michael Muller

Michael Neusius

Wolfgang Tschepat

Ulrich Schoedel

Frank Kraushaar

Uwe Boehmke

Otto Hitzler

Michael Stehr

Dieter Kramer

Josef Frieser

Bernhard Will

Susanne Graner

August Froelich

Egon Grumbach

Gerhard Renner

Dirk Hoppe

J Urgen Omeis

Motor oil with high dispersivity and good wear protection characteristics

Demulsifiers

The invention relates to a method for making oligomers, including homo-oligomers and cooligomers, by the free radical polymerization of at least one monomer component B) having a greater tendency to polymerize and 0-90 wt. %, calculated on the oligomers, of a monomer component A) having a lesser tendency to polymerize, at an elevated temperature and in the presence of a polymerization initiator in a conventional polymerization vessel, by adding monomer component B) to monomer component A), or to a solution of monomer component A), or merely to a solvent, so that the mol ratio of B) to A), if A) is present, passes through values of 0 to about 0.2 during the initial phase of the polymerization and takes the value 0.2 to 20 during the terminal phase of the polymerization, the reaction temperature being in a region in which a homopolymer of the monomer component B) is already significantly depolymerized, and the initiator, which has a half-life time at the reaction temperature from 1 minute to about 5 hours, being added throughout the duration of the polymerization in an amount from 0.1 to 10 percent of the total weight of the monomers.

Method for making oligomers

The invention relates to polymer emulsions of poly(meth)acrylic acid esters and olefin copolymers suitable for improvement of the viscosity index, for use as oil additives. The polymer emulsion is formed of a continuous phase of poly(meth)acrylic acid esters and d-oligomers where the esters and oligomers have a bimodal molecular-weight distribution, a stabilizing agent (a graft or block polymerizate of an olefin copolymerizate and methacrylic acid esters), and a disperse phase of olefin copolymerizates distributed in the continuous phase.

Polymer emulsions with bimodal molecular-weight distribution

A composition comprising a carrier and a comb copolymer made by copolymerizing a polyalkyl (meth)acrylate macromonomer, present in an amount of 10-90 wt %, with the following monomers in a total amount of 90-10 wt %:

Lubricant additives

Co-oligomers and copolymers having dispersant activity and usable as emulsifiers are based on esters of (meth)acrylic acid; where the co-oligomers and copolymers are comprised of the following components: (A) 60-95 wt. % of at least one (meth)acrylic acid ester of formula I ##STR1## where R represents hydrogen or methyl, and

Co-oligomers and copolymers having dispersant activity

Synthetic oils comprising 5-100 percent by weight of an oligomer of

Synthetic oligomeric oils

The present invention relates to comb polymers KP, produced from macromonomers of formula (I) ##STR1## where X represents a group which comes from the initiator system, preferably an alkyl group with 1-50 C atoms; R1 represents an alkyl group with 1-18 C atoms, preferably 1-10 C atoms, particularly preferably 1-4 C atoms; R2 and R3 each represent an alkyl group with 1-8 C atoms; and B represents a terminal alkene group with at least 2 and not more than 12 C atoms; wherewith the compound of formula (I) is converted, by means which are per se known, to a compound of formula (II) which contains an active hydrogen substituent in the terminal position: ##STR2## where X, R1, R2, a, b, and c are as defined above, and a represents the group B modified by introduction of the active hydrogen function; wherewith the compound of formula (II) in turn is acylated to a macromonomer of formula (IV) by a reagent MR which introduces the (meth)acryloyl group: ##STR3## where X, R1, R2, R3, A, a, b, and c are as defined above, and R4 represents hydrogen or methyl; and the macromonomers of formula (IV) thus obtained are converted to the comb polymers KP by radical polymerization with monomers M chosen from the group comprised of: (meth)acrylic acids of C.sub.1 -C.sub.28 -alkanols, functionalized radically polymerizable monomers, vinyl esters of fatty acids and vinylaromatic monomers.

Comb polymers

The invention relates to comb polymers based on olefin copolymer macromonomers. Preferred comb polymers are copolymers of optionally hydrogenated olefin copolymer macromonomers of formula I ##STR1## wherein R' is hydrogen or methyl

Comb polymers based on olefin copolymer macromonomers

The invention relates to the use of polymethylalkanes having terminal methyl groups and methylene and ethylidene groups of the formula I ##STR1## in which the total number of C atoms n+2 m+2 is 20 to 100 and the ratio of the methyl and methylene groups to the ethylidene groups is 3 to 20:1 and the ethylidene groups are always separated by at least one methylene group, as biodegradable base oils for lubricants and functional fluids. Suitable polymethylalkanes are obtained by oligomerization of .alpha.,.omega.-diolefins, for example in particular according to P 41 19 332.6, or by pyrolysis of ethene/propane copolymers and subsequent hydrogenation in each case. The polymethylalkanes can be combined with conventional additives and other degradable or non-degradable base oils.

Use of polymethylalkanes as biodegradable base oils in lubricants and

The present invention provides a polymer-modified bitumeniferous composition containing polymer components in the amount of 0.5-50 wt. %, wherein 20-100 wt. % of the polymeric additive is a copolymer comprises of units of: C.sub.6 -C.sub.28 -alkyl (meth)acrylates in the amount of 80-99.9 wt. %, maleic anhydride in the amount of 0.1-20 wt. %, and other polymerizable compounds in the amount of 0-19.9 wt %. The polymer-modified bitumens exhibit excellent and persistent homogeneity, high elastic resilience, and a good range of plasticity.

Alkyl (meth)acrylate-maleic anhydride copolymer-modified bitumen

Polyalkyl acrylates and methacrylates, suitable for improvement of the viscosity index, are used as oil additives imparting improved dispersant and detergent effects in diesel and gasoline engines, said polyalkyl acrylates or methacrylates being copolymers comprising from 80 to 99.5 parts by weight of alkyl acrylates of methacrylates of the formula ##STR1## wherein R is hydrogen or methyl and R.sub.1 is alkyl having from 6 to 24, and preferably from 8 to 20, carbon atoms, together with from 0.5 to 20 parts by weight of at least one functionalized alkyl methacrylate of the formula ##STR2## wherein R.sup.1 is hydrogen or methyl and R.sub.2 is alkyl having from 2 to 6 carbon atoms and substituted with at least one OH group, or is a polyalkoxylated group of the formula ##STR3## wherein R.sub.3 and R.sub.4 are hydrogen or methyl, R.sub.5 is hydrogen or alkyl having from 1 to 40 carbon atoms, and n in an integer from 1 to 60, the sum of the monomers of formulas (I) and (II) being 100 parts by weight, and optionally further comprising from 0 to 20 parts by weight of one or more monomers of the formula ##STR4## wherein R' is hydrogen or methyl and R.sub.6 is alkyl having from 1 to 5 carbon atoms. Such copolymers are conveniently prepared by copolymerization, advantageously in an oil-compatible vehicle in the presence of an olefin copolymer to form a concentrated emulsion additive.

Viscosity index improver having detergent properties

A method for the solvent dewaxing of wax-containing petroleum products with at least one solvent suitable for dewaxing and a polymeric dewaxing aid comprising polyacrylates, by mixing the products to be dewaxed with the solvent and the polymeric dewaxing aid, chilling the mixture so obtained, and separating the precipitated wax, the dewaxing aid used being a mixture of

Method for dewaxing waxy petroleum products

A polymer-modified bitumen (PmB) having improved elastic restoration prepared by blending from 0.5-20 wt. % of a polymer material in bitumen, said polymer additive, which may be comprised of various polymers, being comprised of from 20-100 wt. % of a polyalkyl (meth)acrylate comprising monomer units as follows:

Polymer-modified bitumen (PMB)

Multifunctional additives for lubricating oils containing n-paraffins, said additives comprising a solvent and a blend of polymers containing

Addives for paraffinic lubricants

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Darmstadt, Germany

Horst Pennewiss