Hoechst Aktiengesellschaft

Horst Lorke

Werner Ritschel

Rainer Helwerth

Helmut Diery

Horst Frohlich

Francesco Cargnino

Giuseppe Natoli

Bernhard Mees

Helmold Von Plessen

Wolfram Fritsche-Lang

Gernot Kremer

Alkenylsuccinic acid half-amides of the formulae ##STR1## are used in water-containing and/or oil-containing formulations or metalworking liquids as anticorrosive agents and emulsifiers. In said formulae: A=C.sub.6 -C.sub.30 alkenyl, R=H or R.sup.1, R.sup.1 =--R.sub.2 --O--(CH.sub.2 CHR.sup.3 --O).sub.n H, R.sup.2 =C.sub.1 -C.sub.1 -C.sub.10 alkylene, R.sup.3 =--H or --CH.sub.3, n=0 to 50 and Me.sup..sym. is an alkali metal ion, a proton or an ammonium ion of the formula HN.sup..sym. R.sup.4 R.sup.5 R.sup.6, R.sup.4, R.sup.5 and R.sup.6, which are identical or different, being hydrogen, C.sub.1 -C.sub.6 alkyl or hydroxyalkyl or Me.sup..sym. is a mixture of an alkali metal ion and an ammonium ion of the above-mentioned formula.

Use of alkenylsuccinic acid half-amides

Process for conditioning waste sulfuric acid

The use of 2-benzthiazolylthiocarboxylic acid ammonium salts of the formula ##STR1## wherein n denotes a number from 1 to 6 and M denotes an organic ammonium ion as a corrosion-inhibiting agent in aqueous functional fluids, in particular in aqueous cooling lubricants.

Aqueous anti-corrosion agent containing an ammonium salt of

The use, as anticorrosion agents, of alkenylsuccinic acid half-amides of the formulae ##STR1## in which R denotes C.sub.6 -C.sub.12 -alkenyl and M denotes a proton or an ammonium ion of the formula NHR.sub.1 R.sub.2 R.sub.3 and R.sub.1, R.sub.2 and R.sub.3 are identical or different and denote hydrogen, C.sub.1 -C.sub.12 -alkyl, 2-hydroxyethyl or 2-hydroxypropyl.

Alkenylsuccinic acid half-amides as anticorrosion agents

The use, as anti-corrosion agents, of alkenylsuccinic acid half-amides of the formulae ##STR1## in which R denotes C.sub.6 -C.sub.18 -alkenyl, R.sup.1 denotes C.sub.12 -C.sub.18 -alkyl and K denotes a proton, an alkali metal ion or an ammonium ion of the formula NHR.sup.2 R.sup.3 R.sup.4, and R.sup.2, R.sup.3 and R.sup.4 are identical or different and denote hydrogen, C.sub.1 -C.sub.12 -alkyl, 2-hydroxyethyl or 2-hydroxypropyl.

Use of alkenylsuccinic acid half-amides as anti-corrosion agents

The use, as anticorrosion agents, of alkenylsuccinic acid half-amides of the formulae ##STR1## in which R denotes C.sub.6 -C.sub.12 -alkenyl and K denotes a proton or an ammonium ion of the formula NHR.sub.1 R.sub.2 R.sub.3 and R.sub.1, R.sub.2 and R.sub.3 are identical or different and denote hydrogen, C.sub.1 -C.sub.12 -alkyl, 2-hydroxyethyl or 2-hydroxypropyl.

Use of alkenylsuccinic acid half-amides as anticorrosion agents

The invention relates to novel compounds which are particularly suitable as corrosion inhibitors for aqueous liquids for the cleaning of metals, and especially as corrosion inhibitors for oil-free aqueous liquids used for the working of metals, in particular those exposed to corrosion. The compounds according to the invention correspond to the formula ##STR1## The invention also relates to a process for their preparation.

Corrosion inhibitors for aqueous liquids for the working of metals, and

Oils for metal processing (e.g. oils for cutting operations) are typically aqueous emulsions, and the emulsifiers for these processing oils should have lubricating bacteriostatic/bactericidal, and corrosion-inhibiting properties. Suitable emulsifiers should comprise the following components:

Emulsifiers for metal processing oils

Anticorrosive agent for aluminium and the alloys thereof consisting of

Anticorrosive agent for aluminium and aluminium alloys

Water-miscible corrosion inhibitors, substantially consisting of

Water miscible corrosion inhibitors

Aqueous metal working liquids containing a bis-sulfonamidocarboxylic acid of the formula ##SPC1## In the form of its water soluble or water dispersible salt with an alkali or an organic base, as corrosion protection and metal-working agent wherein R.sub.1 denotes hydrogen, halogen, alkyl and/or alkoxy of 1 to 3 carbon atoms, R.sub.2 denotes an alkylene radical having a total of 1 to 5 carbon atoms, and x denotes an integer of from 2 to 6.

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Liederbach, Germany

Horst Lorke