Tongji University

Tianjin Polytechnic University

Tianjin University of Technology

Hongwei Zhang

Zhiwei Wang

Liang Wang

Ruobin Dai

Jie Wang

Xueye Wang

Zhichao Wu

Lei Zhang

Sheng Lin

Mei Chen

Tianlin Wang

Qiaoying Wang

Jinsong Wang

Hongyi Han

Jiayi Li

Zening Zhao

Yue Wen

Yingqing Chen

A device for decomplexation and enhanced removal of copper based on self-induced Fenton-like reaction constructed by electrochemistry coupled with membrane separation is disclosed. The device includes a reactor, two electrocatalytic anodes capable of generating hydroxyl radicals, an electrocatalytic cathode membrane assembly, a direct current power supply, an aeration system, an inlet pipe and an outlet pipe. The device of the present invention has a simple construction. Using this device to treat industrial wastewater containing copper complexes under specific conditions allows the decomplexation and the removal of the industrial wastewater containing the copper complexes to be simultaneously realized at a low consumption and a high efficiency. The coupling of electrochemistry with membrane separation can be achieved to protect the cathode from being contaminated by pollutants in the sewage and prolong the service life of the electrode.

Device for decomplexation and enhanced removal of copper based on self-induced fenton-like reaction constructed by electrochemistry coupled with membrane separation, and use thereof

A nanofiltration membrane with a high flux for selectively removing hydrophobic endocrine disrupting chemicals and a preparation method thereof are provided. The method includes the following steps: immersing a porous support layer into a first solution, removing excess droplets from a surface of the support layer after taking the support layer out of the first solution, and then immersing the support layer attached with the first solution into a second solution for an interfacial polymerization reaction, followed by washing after completion of the reaction to obtain the subject nanofiltration membrane. The first solution is an aqueous solution containing a polyamine monomer and an acid binding agent, and the second solution is an organic solution containing an acid chloride monomer and a metal-organic framework.

Nanofiltration membrane with high flux for selectively removing hydrophobic endocrine disrupting chemicals and preparation method thereof

A high-performance thin-film composite polyamide membrane upcycled from a substrate fouled with a biopolymer and a preparation method thereof are provided. The method includes fouling the substrate preferably with the biopolymer to obtain a composite of the substrate and a biopolymer foulant layer; then immersing the composite into a first solution formed by dissolving a polyamine monomer in water, followed by taking the composite out of the first solution and removing excess droplets from a surface of the composite; then immersing the composite treated in the previous step into a second solution formed by dissolving an acyl chloride monomer in n-hexane for interfacial polymerization to form a rejection layer on the surface of the composite; and after completion of the reaction, taking the composite out of the second solution, followed by drying and heat treatment, to obtain the target polyamide membrane.

High-performance thin-film composite polyamide membrane upcylcled from biopolymer-fouled substrates and preparation method thereof

A flexible electrocatalytic membrane for removing nitrate from water, a preparation method and use thereof are provided. The method of the present invention includes dropwise adding an aramid fiber solution into deionized water to prepare an aramid nanofiber sol, then reacting an ethanol solution containing 3,4-ethylenedioxythiophene and ferric nitrate with the aramid nanofiber sol to prepare a conductive aramid nanofiber sol, and finally dropwise adding MXene nanosheets ultrasonically pretreated by a tetramethylammonium hydroxide solution into the conductive aramid nanofiber sol to prepare the flexible electrocatalytic membrane. The prepared flexible electrocatalytic membrane possesses good mechanical strength and flexibility, and can not only effectively remove nitrate but also avoid failure of electrocatalytic materials due to surface fouling in the process of electrocatalytic reduction of nitrate, and thus has a long service life.

Flexible electrocatalytic membrane for removing nitrate from water, preparation method and use thereof

A thin-film composite polyamide reverse osmosis membrane with anti-bacterial and anti-biofouling effects and a preparation method thereof are disclosed. The preparation method includes: dissolving a highly water-stable metal organic framework CuBTTri in an n-hexane solution containing trimesoyl chloride by ultrasonic wave, immersing a polyethersulfone ultrafiltration membrane in an aqueous solution of m-phenylene diamine and taking out, and then immersing the ultrafiltration membrane in the trimesoyl chloride-n-hexane solution containing the aforementioned metal organic framework for reaction and modification, so as to obtain the thin-film composite polyamide reverse osmosis membrane. The resulting composite reverse osmosis membrane integrated with the anti-bacterial metal organic framework CuBTTri has a high reverse osmosis membrane permeability and possesses greatly improved and persistent anti-bacterial and anti-biofouling properties. The preparation method is simple and conducive to promotion, and has mild conditions.

Thin-film composite polyamide reverse osmosis membrane with anti-bacterial and anti-biofouling effects and preparation method thereof

The invention relates to the field of software management and is intended to invent a blockchain-based software version data management system and an establishing method thereof. The system mainly comprises a data acquisition module, a data transmission module and a data consensus module, wherein the data acquisition module involves data generation, data splicing, and data encapsulation, and provides functions such as acquisition of software version data and structural processing function; the data transmission module involves data communication, data parsing and data forwarding and provides a transmission function for the software version data; the data consensus module involves block synchronization, data verification and consensus mechanism and provides reliability test for the software version data, system new block generation and node data synchronization. Through the decentralized characteristic of the blockchain, the invention avoids the system paralysis problem caused by the single-point fault of the centralized system, solves the problem that the compatibility of the multi-version software systems is not consistent, and reduces the maintenance cost of the software version data.

Blockchain-based software version data management system and establishing method thereof

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Tianjin, China

Hongwei Zhang