Alberta Research Council Incorporated

Alberta Innovates-technology Futures

Hongqi Yuan

Theodore Meyer Garver

Ross Chow

John Harry Woolley

Deborah Jean Henry

Allan Chambers

Ross S Chow

John Woolley

The present invention provides a system and method for continuous measurement of acid gas concentration or amine loading in a basic solution using Raman spectroscopy.

Continuous measurement of amine loading in gas processing plants using raman spectroscopy

Disclosed is a method and apparatus for determining stone cells within a sample of wood pulp or paper. According to the instant invention a portion of the sample is irradiated with light at a predetermined wavelength or within a predetermined range of wavelengths. The incident light causes those areas of the sample that are occupied by stone cells to fluoresce strongly relative to the background matrix of wood pulp or paper. The strongly fluorescing stone cells are registered digitally using a detector, or are observed visually by an operator viewing the sample through an ocular device. The absolute number of stone cells per unit area or a stone cell size-distribution-plot is obtained using one of automated or manual image analysis.

Method and apparatus for determining stone cells in paper or pulp

The invention relates to the use of ratios, products and non-linear functions of adsorption, emission or scattering of light as variables in standard regression and chemometric techniques to predict a characteristic or property of a solid or liquid. The use of one or more non-linear functions within a relationship between measured spectral properties and characteristic properties of solutions and solids provides an improved means to determine a property when the intensities represent or relate to components that are colinear or interelated due to restraints associated with composition, chemical processes, or molecular structure. The invention relates to the use of ratios of Raman peak intensities to predict the properties of a solution or a solid such as pulp that is processed with the solution. The intensity of the Raman shifted light is used to create Raman peak intensity ratios. These Raman intensities are related to the concentration of species dissolved in the liquid. The Raman spectra are baseline corrected and the scattering from a water reference is subtracted before extraction of intensities for Raman peak intensity ratios. The Raman scattering intensities provide a good measure of the concentration of small, oxygenated molecules. The potential of an oxidative reductive process is conveniently determined using Raman peak intensity ratios. Relevant small molecules and complex ions in the pulp and paper industry include SO , SO , H O , ClO2, HClO , silicates, acetic acid, HClO , Chlorate ClO ; Chlorous Acid HClO , Chlorite ClO , Hypochlorous Acid HClO. Hypochlorite ClO , phosphate, nitrate, nitrites. The method may also be used to determine a property related to the relative size, degree of polymerization, branching or network formation, of complexing or polymerized species. The method may also be used to measure large molecules such as hemicellulose, extractives and pectic substances.

Determination of the property of a solution or solid using raman ratios

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Edmonton, Canada

Hongqi Yuan