Greatbatch Ltd.

Ho-Chul Yun

Robert S Rubino

Joseph M Lehnes

Marcus J Palazzo

Keith W Seitz

William C Thiebolt

Gary Freitag

Brian P Hohl

Mark J Roy

David Dianetti

Todd C Sutay

Thomas Marzano

David M Spillman

Holly Noelle Moschiano

Xiaohong Tang

Afsar Ali

Biswa P Das

David Wutz

Sourabh Biswas

An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, dibenzyl carbonate (DBC), lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably DBC is present in an amount ranging from about 0.005 moles (M) to about 0.25M, LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFmixture cells, and Li-SVO/CFsandwich cathode primary electrochemical cells.

Lithium electrochemical cell activated with an electrolyte containing DBC, LiBOB and FEC additives

An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFmixture cells, and Li-SVO/CFsandwich cathode primary electrochemical cells.

Lithium electrochemical cell activated with an electrolyte containing LiBOB and FEC additives

A miniature electrochemical cell having a total volume that is less than 0.5 cc is described. The cell casing is formed by joining two ceramic casing halves together. One or both casing halves are machined from ceramic to provide a recess that is sized and shaped to contain the electrode assembly. The opposite polarity terminals are metal feedthroughs, such as of gold, and are formed by brazing gold into openings machined into one or both of ceramic casing halves. A thin film metallization, such as of titanium, contacts an edge periphery of each ceramic casing half. The first ceramic casing half is moved into registry with the second ceramic casing half so that the first and second ring-shaped metallizations contact each other. Then, a laser welds through one of the casing halves being a substantially transparent ceramic, for example sapphire, to braze the first and second ring-shaped metallizations to each other to thereby join the first and second casing halves together to form a casing housing the electrode assembly. A solid electrolyte (LiPON) activates the electrode assembly.

Hermetic weld for a thin film electrochemical cell activated with a solid electrolyte and housed in a ceramic casing

A current collector for an electrochemical cell is described. Unlike conventional current collector designs, the current collector does not have an unperforated perimeter frame completely bordering or surrounding a perforated interior region. Instead, only that portion of the current collector adjacent to the connector tab is unperforated. Otherwise, perforations extend directly to the perimeter edge.

Foil-type current collector having an unperforated strip at the connector tab

A lithium electrochemical cell with increased energy density is described. The electrochemical cell comprises an improved sandwich cathode design with a second cathode active material of a relatively high energy density but of a relatively low rate capability sandwiched between two current collectors and with a first cathode active material having a relatively low energy density but of a relatively high rate capability in contact with the opposite sides of the two current collectors. In addition, a cathode fabrication process is described that increases manufacturing efficiency. The cathode fabrication process comprises a process in which first and second cathode active materials are directly applied to opposite surfaces of a perforated current collector and laminated together. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.

Sandwich cathode lithium battery with high energy density

A miniature electrochemical cell having a total volume that is less than 0.5 cc is described. The cell casing is formed by joining two ceramic casing halves together. One or both casing halves are machined from ceramic to provide a recess that is sized and shaped to contain the electrode assembly. The opposite polarity terminals are metal feedthroughs, such as of gold, and are formed by brazing gold into openings machined into one or both ceramic casing halves. The two ceramic casing halves are separated from each other by a metal interlayer, such as of gold, bonded to a thin film metallization adhesion layer, such as of titanium, that contacts an edge periphery of each ceramic casing half. A solid electrolyte (LiPON) is used to activate the electrode assembly.

Hermetic thin film electrochemical cells housed in a ceramic casing and activated with a solid electrolyte

A miniature electrochemical cell having a total volume that is less than 0.5 cc is described. The casing enclosure consists of a lower plate supporting a cylindrically-shaped can having an open upper end closed with a cover. The can is selectively coated with a dielectric material to provide electrical isolation of the to-be-housed active materials from the can sidewall. A glass-to-metal seal electrically isolates the lower plate from the can. An electrode assembly comprising a sandwich of cathode active material/separator/anode active material is housed in the casing. That way, the lower plate contacting the cathode active material is the positive terminal and the closing cover connected to the can and contacted to the anode active material serves as the negative cell terminal. An electrolyte filled into the casing activates the electrode assembly and the fill opening is sealed with a plug. The cell can be of either a primary or a secondary chemistry.

Miniature electrochemical cells housed in a metallic casing having a glass-to-metal seal isolating the opposite polarity terminals

An electrochemical cell comprising a cathode and an anode residing within a casing, the anode being positioned distal of the cathode. The cathode having a cathode current collector having an angled configuration that encourages the cathode active material to move in an axial distal direction during cell discharge. The cathode current collector may be configured having at least one fold thereby dividing the current collector into at least two portions having an angle therebetween. The cathode current collector may comprise a wire having a helical configuration or the cathode current collector may comprise a post with a thread having a helical orientation about the post exterior. A preferred chemistry is a lithium/CFactivated with a nonaqueous electrolyte.

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East Amherst, NY, United States of America

Ho-Chul Yun