Tokai Rubber Industries, Ltd.

Sumitomo Riko Company Limited

Kyushu University

Hitoshi Yoshikawa

Jun Kobayashi

Satoshi Suzuki

Shigeaki Takamatsu

Atsushi Takahara

Yota Kokubo

Hideyuki Otsuka

Kazunobu Hashimoto

Kunio Ito

Akihiko Kaji

Ryosuke Matsuno

Kenichi Ohkuwa

Shoji Arimura

Sumio Oinuma

Yutaro Taguchi

Akitoshi Nozawa

Kazuhiro Takeda

Wataru Takahashi

Shingi Kumagai

Katsuhiko Nakano

Keita Shiraki

Mitsuyoshi Kondo

Naoki Yamaguchi

Hiroki Sugiura

Masaharu Tsuji

Hiroshige Hiramatsu

Yoshihiro Wago

Minobu Iinuma

Shunsuke Taniguchi

Takamasa Ito

Shinji Iio

Takamasa Itou

Ryousuke Matsuno

Hidetsugu Torihara

A dielectric film which has high electrical resistance and excellent durability and a process for producing the dielectric film are provided. Also provided is a transducer which has large displacement and excellent durability. The dielectric film includes a three-dimensional crosslinked body that is synthesized from an organic metal compound, a rubber polymer that is other than a polydimethyl siloxane and has a functional group that is reactive with the organic metal compound, and an inorganic filler that has a functional group that is reactive with the organic metal compound. The transducer is configured by interposing the dielectric film between at least a pair of electrodes. The dielectric film may be produced by preparing a first solution that contains a rubber polymer and an inorganic filler in a solvent that is capable of dissolving the rubber polymer and of chelating an organic metal compound, then preparing a second solution by mixing the organic metal compound into the first solution, and then removing the solvent from the second solution to allow a crosslinking reaction to proceed.

Dielectric film, process for producing same, and transducer using same

A reactive ionic liquid to be used as an ionic component that is contained in an ion-containing layer in a transducer arranged in contact with a high-resistance layer as a dielectric layer of the transducer, and is restrained from migrating from the ion-containing layer to the high-resistance layer on application of a voltage is provided. The reactive ionic liquid comprises an ion pair that consists of an anion and a cation. (a) The cation (a1) is an imidazolium or quaternary ammonium cation, and (a2) comprises a reactive group that consists of an alkoxysilyl or phosphonate group. (b) The anion (b1) is a sulfonate, sulfonylimide, or nitrobenzoate anion.

Reactive ionic liquid, and ion-immobilized metal oxide particle, ion-immobilized elastomer, and transducer using same

A conductive material includes metal nanowires and an extensible copolymer having an N&#x2014;C&#x2550;O structure and combined with the metal nanowires. The conductive material has excellent elongation properties and has an electrical resistance that is unlikely to increase even when the conductive material is extended. A method for producing a conductive material includes: a copolymer production step of polymerizing a plurality of monomers including a growth direction control monomer that has an N&#x2014;C&#x2550;O structure and controls a growth direction of metal nanowires to produce an extensible copolymer; a reaction step of reacting a metal compound in a solvent containing the copolymer to grow metal nanowires in a longitudinal direction; and an extraction step of extracting a product from the solution after the reaction.

Conductive material, method for producing the conductive material, and transducer including the conductive material

An ion-immobilized metal oxide particle includes a metal oxide particle and an anion that itself includes a) a reactive group that consists of an alkoxysilyl group and b) an anionic group consisting of a carboxylate (&#x2014;COO) group or a sulfonate (&#x2014;SO) group, the anion being immobilized to the metal oxide particle via a silanol group derived from the reactive group. An elastomer includes the ion-immobilized metal oxide particle, and a transducer includes the elastomer.

Provided is a conductive film having a high conductivity in which electric resistance is less likely to increase, and a conductive composition for forming the same. The conductive composition includes an elastomer component, a fibrous carbon material having a fiber diameter of less than 30 nm, and a flake-like carbon material having a graphite structure, having an intensity ratio (G/D ratio) of a peak (G band) appearing in the vicinity of 1580 cmto a peak (D band) appearing in the vicinity of 1330 cmof Raman spectrum of not less than 1.8, and having a maximum length of not less than 150 nm and a thickness of not more than 100 nm. The conductive film is formed from the conductive composition.

Conductive composition and conductive film

Provided is a conductive composition that has a high conductivity and from which a coating can be formed easily. Also provided is a conductive film that has a high conductivity and in which electric resistance is less likely to increase even during expansion. A conductive composition is prepared by including an elastomer component, a fibrous carbon material having a graphite structure and a fiber diameter of not less than 30 nm, and a conductive carbon black having a structure. A conductive film formed from the conductive composition. The viscosity of the conductive composition formed into a coating with a solid content concentration of not less than 20% by mass, which is measured with a B-type viscometer with an H7 rotor under the conditions of a temperature of 25&#xb0; C. and a rotation speed of 20 rpm, is not more than 200 Pa&#xb7;s.

A reactive ionic liquid to be used as an ionic component that is contained in an ion-containing layer in a transducer arranged in contact with a high-resistance layer as a dielectric layer of the transducer, and is restrained from migrating from the ion-containing layer to the high-resistance layer on application of a voltage is provided. The reactive ionic liquid comprises an ion pair that consists of an anion and a cation. In the reactive ionic liquid, (a) the anion comprises (a1) a reactive group that consists of an alkoxysilyl group and (a2) an anionic group consisting of a carboxylate (&#x2014;COO) group or a sulfonate (&#x2014;SO) group. (b) The cation (b1) consists of an imidazolium, ammonium, pyrrolidinium, morpholinium, or phosphonium cation, and (b2) does not comprise an N&#x2014;H group or a P&#x2014;H group.

A flexible conductive material includes an elastomer, a conductive agent filled in the elastomer, and an adsorbent fixed inside the elastomer and able to adsorb ionic material. With the flexible conductive material, ionized impurities are unlikely to transfer to an adherend such as a dielectric film. Thus, leakage current during application of voltage decreases. Accordingly, by forming an electrode and a wiring with the flexible conductive material, leakage current can be reduced, and a transducer and a flexible wiring board having excellent durability can be produced. In addition, using the flexible conductive material, an electromagnetic shield can be produced having a small leakage current.

Flexible conductive material and transducer, flexible wiring board, and electromagnetic shield using the same

The present invention provides a flexible conductive crosslinked body excellent in durability having a small influence of a reaction residue after the crosslinking on an object to which the conductive crosslinked body adheres, and a production process of the flexible conductive crosslinked body. The conductive crosslinked body is synthesized from a conductive composition containing a rubber polymer, an organic metal compound, and a conducting agent and has a crosslinked structure. The production process of the conductive crosslinked body includes: a mixed solution preparing step for preparing a mixed solution in which the rubber polymer, the conducting agent, and the organic metal compound are mixed in a solvent capable of dissolving the rubber polymer and capable of chelating the organic metal compound; and a crosslinking step for removing the solvent from the mixed solution to allow a crosslinking reaction to proceed. The conductive crosslinked body is suitable as an electrode or a wire for a transducer, a wire for a flexible wiring board, and an electromagnetic wave shield.

Conductive crosslinked body and production process thereof, and transducer, flexible wiring board and electromagnetic wave shield using the conductive crosslinked body

A polymer speaker is configured to include an electrostrictive element having an elastomer or resin dielectric layer and a plurality of electrode layers arranged on the front and back surfaces of the dielectric layer. The electrode layers are formed from a conductive material including a polymer binder and a conductor and having a modulus of elasticity of 100 MPa or less. The spring constant of the electrode layers in the surface direction is smaller than the spring constant of the dielectric layer in the surface direction. The volume resistivity of the electrode layers is 200 &#x3a9;&#xb7;cm or less. The polymer speaker provides a practical sound pressure in a wide frequency region from low frequencies to high frequencies.

Polymer speaker

To provide a conductive film that is flexible, extendable and contractible, and for which the electrical resistance hardly increases even when the conductive film is extended. The conductive film contains an elastomer and metallic filler particles, and satisfies a condition (A) [an average value of reference numbers is 0.8 (1/&#x3bc;m) or more, or the metallic filler particles include flake-like metallic filler particles having a thickness of 1 &#x3bc;m or less and an aspect ratio of 26 or more and the average value of the reference numbers is 0.4 (1/&#x3bc;m) or more] and a condition (B) [a number of unit areas for which an area percentage of the elastomer is 60% or more is 20 or more], the condition (A) being a conductivity indicator and the condition (B) being a flexibility indicator.

Conductive film, and transducer and flexible wiring board using the same

An electrically conductive polymer available at low-cost and superior both in electrical conductivity and solubility. The electrically conductive polymer is solvent soluble and is obtained by imparting electrical conductivity to a pi-electron conjugated polymer by means of a dopant; the dopant comprises an alkylbenzenesulfonic acid or its salt having 2 or more alkyl substituent groups, wherein a total carbon number of the alkyl substituent groups is 10 to 37.

Electrically conductive polymer, semiconductive composition using the same and semiconductive member for electrophotographic equipment

An elastic member of a semiconductive polymer comprising a conductive composition containing a conductive polymer and binder polymer, wherein the elastic member satisfies both characteristics of (A) a variation of 1.5 digit or less between the electrical resistance at an applied voltage of 1V and the electrical resistance at an applied voltage of 133V under an environment of 25&#xb0; C. and 50% RH, and (B) a variation of one digit or less between the electrical resistance at an applied voltage of 10V under an environment of 15&#xb0; C. and 10% RH and the electrical resistance at an applied voltage of 10V under an environment of 35&#xb0; C. and 85% RH.

Elastic member of semiconductive polymer and OA equipment using the same

Electrically conductive foam component

A urethane composition for making a sheet transport roll, the composition comprising: (A) a polyether polyol blend containing polytetramethyleneether glycol (PTMG) and polypropylene glycol (PPG) in a weight ratio of PTMG/PPG&equals;99/1 to 50/50; (B) a polyisocyanate; and (C) a chain lengthening agent; the urethane composition in a cured state having a hardness of not smaller than 40, and a crosslinking density of 0.15 to 0.8 mmol/cm or an allophanate bond concentration of 0.03 to 0.07 mmol/g.

Growing community of inventors

Aichi-ken, Japan

Hitoshi Yoshikawa