Cosmo Oil Co., Ltd.

Cosmo Research Institute

Other

Hitoshi Kumagai

Sotaro Miyano

Takashi Hori

Sanae Ueda

Setsuko Miyanari

Yoshihiro Kojima

Yoshihiro Sugawa

Mitsuharu Hasegawa

Nobuhiko Iki

Hiroshi Munakata

Shingo Kato

Masahiro Ishizuka

Fumio Hamada

Masato Goto

Yoko Sato

Yoshiyuki Hiraishi

Naoya Morohashi

Fumitaka Narumi

Toyohisa Fujimoto

SULFONATED DERIVATIVES OF CYCLIC PHENOL SULFIDES, PROCESS FOR THE PREPARATION THEREOF, SEPARATING AND RECOVERING AGENTS CONTAINING CYCLIC PHENOL SULFIDES, METHODS FOR SEPARATION AND RECOVERY THEREWITH, AND DRUG COMPOSITIONS CONTAINING THE SULFIDES

Cyclic phenol sulfide having at least one sulfinyl or sulfonyl group and

A composition for extracting a transition metal which comprises as an active ingredient a cyclic phenol sulfide represented by the following formula (1): ##STR1## wherein X represents a hydrogen atom, a hydrocarbon group, an acyl group, a carboxyalkyl group, or a carbamoylalkyl group; Y represents a hydrocarbon group; Z represents a sulfide group, a sulfinyl group, or a sulfonyl group; and n is an integer of 4 to 8; and a method for extracting a transition metal using the composition

Composition for extracting transition metal and method for extracting

A cyclic phenol sulfide represented by the following formula (1) is described: ##STR1## wherein X represents a hydrogen atom, a hydrocarbon group, or an acyl group; Y.sub.1 represents a hydrogen atom, a hydrocarbon group, a halogenated hydrocarbon group, --COR.sup.1, --OR.sup.2, --COOR.sup.3, --CN, --CONH.sub.2, --NO.sub.2, --NR.sup.4 R.sup.5, a halogen atom, --SO.sub.4 R.sup.6, or --SO.sub.3 R.sup.7, in which R.sup.11, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 each represents a hydrogen atom or a hydrocarbon group; n is an integer of 3 or more; and m is an integer of 1 to 7, provided that the plural m's of the S.sub.m 's are the same or different; the plural X's are the same or different; and the plural Y.sub.1 's are the same or different. A process for producing the cyclic phenol sulfide is also described.

Cyclic phenol sulfide and process for producing the same

A process for producing an over-based sulfurized alkaline earth metal phenate type detergent, which comprises reacting a phenol and a dihydric alcohol with an alkaline earth metal reagent to carry out a metal addition reaction, and reacting sulfur therewith to carry out a sulfurization reaction, and then reacting carbon dioxide therewith to carry out a carbon dioxide treatment, characterized in that the metal addition reaction and the sulfurization reaction are carried out under pressure and closed conditions. The sulfurization reaction may be carried out simultaneously with the metal addition reaction, or, alternatively, with the carbon dioxide treatment after the metal addition reaction. Furthermore, the sulfurization reaction may be carried out between the metal addition reaction and the carbon dioxide treatment.

Process for producing over-based sulfurized alkaline earth metal phenate

A process for producing a mixture of sulfides of alkaline earth metal salts of an alkylhydroxybenzoic acid and an alkylphenol comprising the steps of: reacting a mixture of a phenol, a dihydric alcohol and an alkaline earth metal oxide and/or hydroxide (hereinafter referred to as an alkaline earth metal reagent) in an amount of no more than 0.99 gram equivalents per gram equivalent of said phenol; distilling off water and the dihydric alcohol until the amount of the dihydric alcohol becomes no more than 0.6 moles per mole of the alkaline earth metal reagent; reacting the resulting distillation residue with carbon dioxide; and reacting the resulting product with elemental sulfur in an amount of 0.1-4.0 moles per mole of the alkaline earth metal reagent.

Process for producing a mixture of sulfides of alkaline earth metal

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Saitama, Japan

Hitoshi Kumagai