Akzo Nobel Chemicals International B.v.

Schlumberger Technology Corporation

Saudi Arabian Oil Company

Nouryon Chemicals International B.v.

Ascend Performance Materials Operations LLC

Hisham Nasr-El-Din

Cornelia Adriana De Wolf

Mohamed Ahmed Nasr-El-Din Mahmoud

James N LePage

Edwin Rudolf Antony Bang

Johanna Hendrika Bemelaar

Estevao De Oliveira Barra

Murtaza Ziauddin

Jefferson Thomas Ebert

Boen Ho O

Abdullah Mohammed Al Moajil

Benjamin Haseltine

Zheng Chai

Conrardus Hubertus Joseph Theeuwen

Theodor Johannes Stanitzek

Salar Afra

Hamidreza Samouei

Noble Thekkemelathethil George

Marcel Cornelis Paulus Van Eijk

Ahmed S Zakaria

Josef Johannes Maria Baltussen

Guanqun Wang

Mohammed Ali Ibrahim Sayed

Marcel Cornelis Van Eijk

Conrardus Hubertus Theeuwen

Jozef Johannes Baltussen

Edwin Rudolf Bang

Albertus Jacobus Bouwman

Mohammed Ali Sayed

Mohamed Ahmed Nasr El Din Mahmoud

James N Lepage

Corrosion inhibitor compositions for reducing the corrosive effect of acidic environments on metallic substrates are provided herein. In particular, the present disclosure describes corrosion inhibitor compositions comprising a condensation product of a trifunctional amine and a fatty acid. The present disclosure also describes methods of preparing and of using such corrosion inhibitor compositions.

Trifunctional amine based corrosion inhibitor compositions

A two-step process to produce oil or gas from a subterranean formation wherein in a first step the subterranean formation is treated with an aqueous composition containing a chelating agent selected from the group of glutamic acid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), and N-hydroxyethyl ethylenediamine N,N',N&#x2032;-triacetic acid or a salt thereof (HEDTA) and wherein, in a next step, in the outlet streams from the subterranean formation the aqueous phase is separated from the non-aqueous phase.

Process to produce oil or gas from a subterranean formation using a chelating agent

In one aspect, methods may include quantifying a pore-scale heterogeneity of a porous medium; determining an adjusted pore volume to breakthrough based on the pore scale heterogeneity determined; and designing a stimulating fluid treatment for the porous medium. Other aspects may include the development of a wellbore stimulation methodology that allows stimulation fluid breakthrough curves of differing formation samples to be plotted as a single curve that accounts for the varied pore structure of the respective samples.

Well treatment

The present invention relates to a process for treating a sandstone formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) and having a pH of between 1 and 14 into the formation. The invention in addition relates to a fluid suitable for use in the above process containing 5-30 wt % of glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA), a corrosion inhibitor, a surfactant, and a mutual solvent.

Treatment of illitic formations using a chelating agent

The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.

Environmentally friendly stimulation fluids, processes to create wormholes in carbonate reservoirs, and processes to remove wellbore damage in carbonate reservoirs

Disclosed is a filter cake removal composition, and method of use thereof, for use in a wellbore for controlled removal of a filter cake present in a target production zone. The filter cake removal composition includes hydrochloric acid and an organic acid. The filter cake removal composition, when a mixture of the hydrochloric acid and the organic acid is applied to the filter cake in the target production zone, is operable to dissolve the filter cake in the target production zone over an extended reaction time. The mixture includes the hydrochloric acid present in an amount of between about 0.1% and 5% by weight and the organic acid present in an amount of between about 0.1% and 10% by weight.

Filter cake removal composition for drilling fluids and method of use thereof

The present invention relates to a process to treat a subterranean formation by introducing a composition containing between 1 and 40 wt % on total weight of the composition of a chelating agent selected from the group of glutamic acid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), and methylglycine N,N-diacetic acid or a salt thereof (MGDA) into the formation, wherein the process comprises a soaking step.

Process to treat subterranean formations using a chelating agent

The present invention relates to a foam containing water, between 5 and 30 wt % on total weight of the foam of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N',N&#x2032;-triacetic acid or a salt thereof (HEDTA), a foaming agent, and at least 25 vol % on total volume of the foam of a gas, and having a pH of between 2 and 5, to a viscosified composition containing water, between 5 and 30 wt % on total volume of the composition of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N&#x2032;,N&#x2032;-triacetic acid or a salt thereof (HEDTA), and at least 0.01 wt % on total weight of the composition of a viscosifying agent, and having a pH of between 2 and 5, and to a process for treating a subterranean formation comprising introducing the above foam or viscosified composition into the formation.

Foam or viscosified composition containing a chelating agent

The present invention relates to a process for treating a subterranean formation wherein a fluid containing an ammonium salt of glutamic acid N,N-diacetic acid (GLDA) or methylglycine N,N-diacetic acid (MGDA) is introduced into the formation. The invention also covers a fluid containing an ammonium salt of GLDA and/or MGDA and at least one component from the group of seawater, mutual solvents, anti-sludge agents, (water-wetting or emulsifying) surfactants, foaming agents, corrosion inhibitors corrosion inhibitor intensifiers, viscosifiers, wetting agents, diverting agents, oxygen scavengers, carrier fluids, fluid loss additives, friction reducers, stabilizers, rheology modifiers, gelling agents, scale inhibitors, breakers, salts, brines, pH control additives, bactericides/biocides, particulates, crosslinkers, salt substitutes (such as tetramethyl ammonium chloride), relative permeability modifiers, sulfide scavengers, fibres, nanoparticles, and consolidating agents, and covers an ammonium salt of the formula M(NH)H-GLDA or the formula M(NH)H-MGDA, wherein M is an alkalimetal cation, x is at least 0.1, y is at least 0.1 and x+y+z=4 for GLDA and x+y+z=3 for MGDA.

Ammonium salts of chelating agents and their use in oil and gas field applications

Growing community of inventors

College Station, TX, United States of America

Hisham Nasr-El-Din