Fuji Photo Film Company, Limited

Hisashi Yamazaki

Kikuo Yamazaki

Akio Ishizuka

Satoshi Arakawa

Katsuhiro Kohda

Terumi Matsuda

Akira Kitada

Yuichi Hosoi

Kenji Takahashi

Hideki Suzuki

Junji Miyahara

Norio Miura

Noboru Kotera

Masanori Teraoka

Takeji Ochiai

Shusaku Eguchi

Atsunori Takasu

Yoshiteru Ito

A radiation image storage panel has a phosphor layer which comprises a stimulable phosphor, and a protective film. The protective film is a coated layer containing at least 30% by weight of a fluorine-containing resin which is soluble in an organic solvent, such as a copolymer derived from a fluoroolefin and other copolymerizable monomer, polytetrafluoroethylene or a modified polytetrafluoroethylene.

Radiation image storage panel

A radiation image storage panel having a stimulable phosphor layer and an improved protective film is disclosed. The improved protective film is produced from a mixture of a film-forming resin and an oligomer having a polysiloxane skeleton or a perfluoroalkyl group. The improved protective film can be a coated layer containing a fluorocarbon resin which is soluble in an organic solvent. Otherwise, the improved protective film can be produced by coating on the phosphor layer a mixture of a film-forming resin composition containing a fluorocarbon resin which is soluble in an organic solvent, and a powdery resin of perfluoroolefin or silicone.

A process for the preparation of a radiation image storage panel which comprises a support, a light-reflecting layer and a stimulable phosphor layer, superposed in this order, characterized in that applying a binder solution-I containing a light-reflecting material and a binder solution-II containing a stimulable phosphor onto a surface of a support or a sheet in such a manner that both the binder solutions are superposed, to form a light-reflecting layer and a stimulable phosphor layer simultaneously.

Process for the preparation of radiation image storage panel

A radiation image storage panel comprising a support and a phosphor layer provided on the support which comprises a binder and a stimulable phosphor dispersed therein, characterized in that the side surfaces of said panel are covered with a polymer material composed of a linear polyester or a mixture of a linear polyester and a vinyl chloride-vinyl acetate copolymer.

A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, characterized in that said phosphor layer consists essentially of one part on the support side which contains the stimulable phosphor and the other part on the panel surface side which does not substantially contain the stimulable phosphor. Processes for the preparation of said radiation image storage panel are also disclosed.

Radiation image storage panel and process for the preparation of the same

A radiographic intensifying screen comprising a support and a phosphor layer provided thereon which comprises a binder and a phosphor dispersed therein, characterized in that said binder contains a (meth)acrylic copolymer in the amount of 5-100% by weight, having repeating units represented by the formulas (I), (II) and (III): ##STR1## in which each of R.sub.1, R.sub.3 and R.sub.5 is independently a hydrogen atom or an alkyl group; R.sub.2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R.sub.4 is a hydrogen atom or an alkyl group, provided that R.sub.4 is not identical to R.sub.2 ; and x, y and z which represent molar percents are numbers satisfying the conditions of 5.ltoreq.x.ltoreq.99, 1.ltoreq.y+z.ltoreq.95 and x+y+z.gtoreq.90. The (meth)acrylic copolymer is preferably employed in combination with a linear polyester having a hydroxyl value in the range of 20-70.

Radiographic intensifying screen

In a radiation image storage panel comprising a support and a phosphor layer which comprises a binder and a stimulable phosphor dispersed therein and is colored with a colorant, the improvement which comprises said colorant is a pigment capable of absorbing a portion of stimulating rays for the stimulable phosphor and said phosphor layer contains a dispersing agent of at least one fatty acid ester selected from the group consisting of sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters and polyoxyethylene fatty acid esters.

Radiation image storage panel with dispersing agent

A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, characterized in that said binder contains a (meth)acrylic copolymer in the amount of 5-100% by weight, which has repeating units represented by the formulas (I), (II) and (III): ##STR1## in which each of R.sub.1, R.sub.3 and R.sub.5 is independently a hydrogen atom or an alkyl group; R.sub.2 is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R.sub.4 is a hydrogen atom or an alkyl group and R.sub.2 .noteq.R.sub.4 ; and x, y and z representing molar percents are numbers satisfying the conditions of 5.ltoreq.x.ltoreq.99, 1.ltoreq.y+z.ltoreq.95 and x+y+z.gtoreq.90. The (meth)acrylic copolymer is preferably employed in combination with a linear polyester having a hydroxyl value in the range of 20-70%.

A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, characterized in that a friction-reducing layer having a surface of a friction coefficient of not more than 0.6 is provided on the support-side surface and/or the phosphor layer-side surface thereof.

A radiation image storage panel comprising a support and phosphor layers provided thereon which comprise a binder and a stimulable phosphor dispersed therein, characterized in that said phosphor layers comprise the first phosphor layer on the support side and the second phosphor layer provided on the first phosphor layer, and that the mean particle size of the stimulable phosphor contained in said first phosphor layer is smaller than the mean particle size of the stimulable phosphor contained in said second phosphor layer.

A radiation image storage panel comprising a support, a subbing layer and a phosphor layer which comprises a binder and a stimulable phosphor dispersed therein, superposed in this order, characterized in that said subbing layer contains fine particles having a size of 1-30 .mu.m in an amount of 1-200% by weight of a resin constituting the subbing layer.

A radiation image storage panel comprising a support, a subbing layer and a phosphor layer which comprises a binder and a stimulable phosphor dispersed therein, superposed in this order, characterized in that said subbing layer comprises a synthetic resin crosslinked with a crosslinking agent.

A radiation image storage panel comprising a substrate, a fluorescent layer provided on the substrate and composed of a binder and a stimulable phosphor dispersed therein, and a protective layer provided on the fluorescent layer. The panel is edge-reinforced by coating the edge faces thereof with a polymer material comprising polyurethane or acrylic resin.

A radiation image storage panel having a fluorescent layer which comprises a binder and a stimulable phosphor dispersed therein. Further, the panel is colored with a colorant so that the mean reflectance of the panel in the wavelength region of the stimulating rays of the stimulable phosphor is lower than the mean reflectance of the panel in the wavelength region of the light emitted by the stimulable phosphor upon stimulation thereof. The panel provides an image of high sharpness.

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Kaisei, Japan

Hisashi Yamazaki