Toppan Printing Co., Ltd.

Sony Corporation

Murata Manufacturing Co., Ltd.

Nec Corporation

Alps Electric Co., Ltd.

Toppan Inc.

Hirosaki University

Hiroyuki Morioka

Saori Okada

Tatsuya Furuya

Katsunori Takahara

Yuichi Sabi

Yuri Nakayama

Hideki Kawasaki

Haruna Kurata

Kenichiro Oota

Momoe Adachi

Koichiro Hinokuma

Yui Senda

Yasuhiro Haba

Keiichi Iio

Reina Ichikawa

Hiroshi Ishida

Kazumasa Takeshi

Hisanobu Okawa

Hideki Kamimura

Madoka Ozawa

Masaya Yamatani

Chiaki Kera

Koutarou Tsubota

Hiroyuki Kanesada

Mitsuharu Chisaka

Tosiaki Iwaisako

Kazuhide Nakayama

A fuel cell membrane electrode assembly includes a polymer electrolyte membrane and a pair of electrocatalyst layers arranged to have the polymer electrolyte membrane therebetween, at least one of the pair of electrocatalyst layers includes particles supporting a catalyst which is composed of a noble metal component, a polymer electrolyte, and a fibrous oxide-based catalytic material, and the fibrous oxide-based catalytic material includes at least one transition metal element selected from a group consisting of Ta, Nb, Ti, and Zr.

Fuel cell membrane electrode assembly and polymer electrolyte fuel cell

A membrane electrode assembly and a polymer electrolyte fuel cell that are capable of improving water release in a high current region, where a large amount of water is generated, without impairing water retention under low humidity conditions, and also capable of exhibiting high power generation performance and durability under high humidity conditions, and also reducing the production cost of the electrode catalyst layer. A membrane electrode assembly of the present embodiment includes a polymer electrolyte membrane, and a pair of electrode catalyst layers sandwiching the polymer electrolyte membrane. At least one of the pair of electrode catalyst layers contains catalyst-supporting particles having a hydrophobic coating, hydrophobic polymer fibers, and a polymer electrolyte.

Membrane electrode assembly and polymer electrolyte fuel cell

A fuel cell membrane electrode assembly and a polymer electrolyte fuel cell, which improve drainage in a high current range where a large amount of water is produced, without hindering water retention under low humidification conditions, and exhibit high power generation performance and durability even under high humidification conditions. A fuel cell membrane electrode assembly according to a first embodiment of the present invention includes a polyelectrolyte film, and two electrocatalyst layers sandwiching the polyelectrolyte film. At least one of the two electrocatalyst layers includes catalyst support particles with a hydrophobic coating, a polyelectrolyte, and a fibrous material having an average fiber diameter that is 10 nm or more and 300 nm or less. The fibrous material has a mass that is 0.2 times or more and 1.0 times or less the mass of the carrier in the catalyst support particles.

Provided is a catalyst for fuel cells including an oxygen atom, a nitrogen atom, a pentavalent phosphorus atom, and a transition metal atom, in which when the transition metal atom is represented by M, the catalyst for fuel cells is represented by a chemical formula MONP, and the transition metal atom is at least one selected from the group consisting of a titanium atom, a tantalum atom, a niobium atom, and a zirconium atom.

Catalyst for fuel cells, membrane electrode assembly, and polymer electrolyte fuel cell

In one embodiment, a thin film solid state lithium ion secondary battery is able to be charged and discharged in the air and is able to be manufactured stably at a favorable yield. The thin film solid state lithium ion secondary battery has an electric insulating substrate formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film, a cathode active material film, a solid electrolyte film, an anode potential formation layer, and an anode-side current collector film. The cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode potential formation layer is a layer formed from the same material as that of the cathode active material film or a material different from that of the cathode active material film and is a layer provided for forming anode potential at the time of discharge.

Thin film solid state lithium ion secondary battery and method of manufacturing the same

An aluminum secondary battery includes a positive electrode, a negative electrode, and an electrolyte, wherein the positive electrodeincludes an anion receptor such as polyaniline, the negative electrodeincludes aluminum or an aluminum alloy, the electrolyte includes an aluminum salt, a sulfone, and a solvent with a dielectric constant of 20 or less, wherein the aluminum salt is typically AlClor the like, the sulfone is typically ethyl n-propyl sulfone or the like, and the solvent with a dielectric constant of 20 or less is typically toluene or the like.

Aluminum secondary battery and electronic device

In one embodiment, a thin film solid state lithium ion secondary battery is able to be charged and discharged in the air and manufactured stably at a favorable yield. The thin film solid state lithium ion secondary battery has an electric insulating substrate formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film, a cathode active material film, a solid electrolyte film, an anode potential formation layer, and an anode-side current collector film. The cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode potential formation layer is a layer formed from the same material as that of the cathode active material film or a material different from that of the cathode active material film and is a layer provided for forming anode potential at the time of discharge.

A method for producing a thin-film battery includes a film-formation step of forming a film of a positive-electrode material to form a positive-electrode active material film and an annealing step of annealing the positive-electrode active material film. After the annealing step, a lithium-ion introduction step of introducing lithium ions into the positive-electrode active material film. After the introduction of the lithium ions, a reverse-sputtering step of edging the positive-electrode active material film by reverse sputtering.

Method for producing positive electrode of thin-film battery and method for producing thin-film battery

There is provided an electrolyte solution including a solvent formed from a sulfone, and a magnesium salt dissolved in the solvent.

Electrolyte solution, method for producing electrolyte solution, and electrochemical device

The present invention provides a manufacturing method of an electrode catalyst layer which contains a catalyst, carbon particles and a polymer electrolyte, wherein an oxide type of non-platinum catalyst is used as the catalyst and a fuel cell employing the electrode catalyst layer achieves a high level of power generation performance. The manufacturing method of the electrode catalyst layer of the present invention includes at least: preparing a first catalyst ink, in which a catalyst, first carbon particles and a first polymer electrolyte are dispersed in a first solvent, drying the first catalyst ink to form complex particles, preparing a second catalyst ink, in which the complex particles, second carbon particles and a second polymer electrolyte are dispersed in a second solvent, and coating the second catalyst ink on a substrate to form the electrode catalyst layer.

Manufacturing method of electrode catalyst layer, membrane electrode assembly using the same, fuel cell using the same and complex particles

According to the present invention, it is possible to improve the use ratio of active sites in a catalyst having oxygen reduction activity so as to provide a cathode catalyst layer and MEA for a fuel cell with high a level of power generation performance. The present invention includes a process of introducing a functional group into a surface of the catalystwhich has oxygen reduction activity and a process of blending the catalystwith the functional group on the surface together with an electron conductive material and a proton conductive polymer electrolyte to prepare a catalyst ink for forming the cathode catalyst layer for the fuel cell.

Cathode catalyst layer, manufacturing method thereof and membrane electrode assembly

An IC card having a secondary battery, which causes no increase in thickness and also has excellent safety, is provided. The IC card includes an antenna coil for inducing electric power by electromagnetic induction, a thin-film battery for storing electric power induced by the antenna coil, and a control portion for controlling the storage of the electric power from the antenna coil in the thin-film battery. The thin-film battery includes a positive electrode, a negative electrode, and a solid electrolyte layer between the positive electrode and the negative electrode.

IC card

The present invention provides an MEA which improves water retention properties of an electrode catalyst layer without inhibiting diffusion of a reaction gas and drainage of water produced by an electrode reaction etc. One aspect of the present invention is a manufacturing method of an MEA which includes coating and drying a catalyst ink to form a first electrode catalyst sub-layer, coating and drying a catalyst ink to form a second electrode catalyst sub-layer, and forming the first and the second electrode catalyst sub-layers on a polymer electrolyte membrane in this order, and has a specific feature that a solvent removal rate in drying to form the first electrode catalyst sub-layer is higher than that in drying to form the second electrode catalyst sub-layer.

Method of manufacturing a membrane electrode assembly, membrane electrode assembly and fuel cell

[Problem] To provide a membrane and electrode assembly comprising a catalyst layer that improves water holding properties and exhibits high power generation characteristics even in low humidified conditions without inhibiting removal of the water generated by the electrode reaction, etc. and its manufacturing method. [Solution] The membrane and electrode assembly produced by sandwiching a polymer electrolyte membrane between a pair of catalyst layers is provided, in which the catalyst layer comprises a polymer electrolyte and particles carrying a catalyst material, and in which the proportion of the polymer electrolyte expressed by {(mass of polymer electrolyte)/(mass of particles in particles carrying catalyst material)} in the catalyst layer is decreased toward the polymer electrolyte membrane (the inside) from the surface of the catalyst layer (the outside).

Growing community of inventors

Tokyo, Japan

Hiroyuki Morioka