Teijin Limited

National Institute of Advanced Industrial Science and Technology

Hiroyuki Honmoto

Satoshi Nishikawa

Takahiro Daido

Hiroyoshi Minematsu

Satoshi Igarashi

Shigeru Niki

Shogo Ishizuka

Nobuaki Kido

Youji Yanagi

Yasushi Kitagishi

There is provided a solar cell in which a lower electrode layer, a photoelectric conversion layer having a chalcopyrite structure that includes a Group Ib element, a Group IIIb element, and a Group VIb element, and an upper electrode layer are sequentially formed on top of a substrate, wherein the solar cell is provided with a silicate layer between the substrate and the lower electrode layer.

Solar cell and manufacturing method thereof

A nonaqueous secondary battery separator which is a composite porous membrane obtained by integrally covering both sides of a polyolefin microporous membrane having a gas permeability (JIS P8117) of between 15 seconds/cc&#xb7;&#x3bc;m and 50 seconds/100 cc&#xb7;&#x3bc;m per unit thickness and a film thickness of between 5 &#x3bc;m and 25 &#x3bc;m, with a porous layer composed of polymetaphenylene isophthalamide, and which exhibits both a shutdown function and effective heat resistance for meltdown resistance, as features desired for high-energy-density, high-output, large-sized, high-performance nonaqueous secondary batteries, while also having excellent handleability and ion permeability. The film thickness of the composite porous membrane is between 6 &#x3bc;m and 35 &#x3bc;m, the gas permeability (JIS P8117) is between 1.01 and 2.00 times that of the polyolefin microporous membrane, and the polymetaphenylene isophthalamide coating amount is between 1.0 g/mand 4.0 g/m.

Nonaqueous secondary battery separator and process for its fabrication

A separator, used for a lithium ion secondary battery that produces electromotive force by lithium doping/dedoping, which is composed of a porous film comprising an organic polymer (component A) which can swell in an electrolyte solution to retain it, surrounding a nonwoven fabric which cannot swell in the electrolyte solution, the porous film including an electrolyte solution non-swelling organic polymer with a melting point of 210&#xb0; C. or above (component B) and an electrolyte solution non-swelling organic polymer with a melting point of 180&#xb0; C. or below (component C), wherein component B is incorporated in the fiber composing the nonwoven fabric. The separator is highly safe and exhibits low reduction mechanical properties with respect to organic solvents.

Separator for lithium ion secondary battery

A process for production of a composite porous film wherein a porous support, of which both sides have been coated with a solution (dope) of an organic polymer compound in a water-soluble organic solvent to form a coated film, is passed through an air gap step and conveyed into a coagulating bath comprising water or a mixture of water with the same solvent as the organic solvent, and is then immersed in the coagulating bath so that the coated film on both surfaces of the porous support directly contact the coagulating bath for coagulation, and is then washed and dried. This production process is suitable for production of non-aqueous secondary battery separators, and yields non-aqueous secondary battery separators with good handling properties and at low cost, whereby the ion permeability, adhesion with electrodes and electrolyte solution retention can be strictly controlled.

Process for production of composite porous film

A lithium ion secondary battery including a positive electrode, a negative electrode, a separator and a nonaqueous electrolyte, where the separator essentially includes a porous sheet. The positive electrode active material and the negative electrode active material can be reversibly doped and dedoped such that, where Qp (mAh) is an electric charge necessary for causing total lithium contained in the positive electrode to be dedoped and Qn (mAh) is an electric charge necessary for causing lithium to fully dope the negative electrode, Qp>Qn. Further, when the battery is charged at a charging current Ic (mA) in a range of 0.2 Qn/h<Ic<2 Qn/h, in a range of an electric charge for charging Qc (mAh) of 1<Qc/Qn<Qp/Qn, doping of the positive electrode by lithium is initiated by producing lithium particles on the negative electrode by charging of the battery until Qc<Qp.

Growing community of inventors

Iwakuni, Japan

Hiroyuki Honmoto