Nippon Shokubai Co., Ltd.

Sumitomo Chemical Company, Limited

Hiroto Kasuga

Eiichi Shiraishi

Etsushige Matsunami

Yoshitaka Arita

Kaori Nakatani

Michio Tanimoto

Hideaki Tsuneki

Tsukasa Takahashi

Masaru Kirishiki

Naohiro Fukumoto

Naomasa Kimura

Masaki Okada

Masafumi Sugio

The present invention provides a process for producing acrylic acid from glycerin with a catalyst having a prolonged life. In the process for producing acrylic acid from glycerin, a molar ratio of oxygen to glycerin in a raw material gas is set to be not lower than 0.8 and not higher than 20.

Process for producing acrylic acid

The present invention provides a process for producing acrolein, which exhibits a prolonged catalyst life, low energy consumption, and excellent efficiency, and which is earth-conscious, and a glycerin-containing composition which can preferably be used even in this process. The process for producing acrolein is one which includes bringing a raw material gas containing glycerin gas into contact with a solid acid catalyst in a reactor, and the partial pressure of the glycerin gas in the raw material gas is set to be from 0.01 to 30 kPa. The glycerin-containing composition is for use in a process for producing acrolein using a solid catalyst and includes a fatty acid and/or a fatty acid ester, and a total mass of the fatty acid and the fatty acid ester is from 0.001% to 5% by mass, relative to the glycerin.

Process for producing acrolein and glycerin-containing composition

There is provided a process for producing acrolein from glycerin, exhibiting a suppressed decrease in the yield of acrolein with time. In the process for producing acrolein by dehydrating glycerin in the presence of a catalyst containing a metal phosphate, one, or two or more, metal phosphates are used, which are selected from aluminum salts, zirconium salts, manganese salts, alkali metal salts (provided that the alkali metal is sodium, potassium, or cesium, and the ratio between the mole number (M) of the alkali metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 2.0 or lower), alkali earth metal salts (provided that the ratio between the mole number (M) of the alkali earth metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 1.0 or lower), and the like.

Process for production of acrolein

This invention provides a method of reactivating a catalyst for methacrylic acid production, which catalyst is used in production of methacrylic acid through vapor-phase oxidation of methacrolein or vapor-phase oxidative dehydrogenation of isobutyric acid, contains P and Mo, and exhibits reduced activity. The process comprises treating the catalyst, whose activity level has dropped (deteriorated catalyst), with a gas containing a nitrogen-containing heterocyclic compound (e.g., pyridine, piperidine, piperazine, quinoline).

Method for reactivating catalyst for methacrylic acid preparation

A catalyst useful for catalytic vapor-phase oxidation of isobutylene, t-butanol or propylene to produce respectively corresponding unsaturated aldehyde and unsaturated carboxylic acid is provided. The catalyst consists of ring-formed shaped bodies composed of (i) a catalyst composition containing at least molybdenum and bismuth as the active ingredients and (ii) inorganic fibers. The catalyst excels in mechanical strength, can give the object products at high yield and shows little activity degradation with time.

Catalyst for preparation of unsaturated aldehyde and unsaturated carboxylic acid

A catalyst suited for catalytic vapor-phase oxidation of isobutylene, t-butanol or propylene to produce respectively corresponding unsaturated aldehyde and unsaturated carboxylic acid is provided. Said catalyst consists of ring-formed shaped bodies composed of (i) a catalyst composition containing at least molybdenum and bismuth as the active ingredients and (ii) inorganic fibers. The catalyst excels in mechanical strength, can give the object products at high yield and shows little activity degradation with time.

The invention provides a method for regenerating with high efficiency a deteriorated catalyst of reduced activity, said catalyst originating from a heteropolyacid catalyst containing heteropolyacid formed of molybdophosphoric acid and/or molybdovanadophosphoric acid, or a salt thereof, to a heteropolyacid catalyst which exhibits approximately equivalent activity level to that of the fresh catalyst. Said method comprises mixing a deteriorated catalyst and a nitrogen-containing heterocyclic compound under the conditions whereunder ammonium ions and nitrate anions are present at such ratio that the amount of total ammonium ions per mol of total nitrate anions does not exceed 1.7 mols, drying the mixture and calcining the same.

Method for regenerating heteropolyacid catalyst and method for producing methacrylic acid

The present invention produces (meth)acrylic acid in a high yield in a process for producing (meth)acrylic acid by subjecting at least one member selected from the group consisting of (meth)acrolein, propane, and isobutane to catalytic gas phase oxidation with molecular oxygen or a molecular-oxygen-containing gas. In addition, the present invention makes it possible to produce (meth)acrylic acid in a high yield and stably for a long time. The present invention provides a process for producing (meth)acrylic acid by catalytic gas phase oxidation reaction, which is characterized by allowing a reaction gas to contain a reducible compound.

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Himeji, Japan

Hiroto Kasuga