Toyo Boseki Kabushiki Kaisha

Hiroshi Tachimori

Yoshimitsu Sakaguchi

Shiro Hamamoto

Satoshi Takase

Hiroaki Taguchi

Kota Kitamura

Takaharu Ichiryu

Tadao Kuroki

Hiroki Murase

Yukihiro Nomura

Yukinari Okuyama

Go Matsuoka

Junko Nakao

Kohei Kiriyama

Yukihiro Abe

Muneatsu Nakamura

Hironori Eguchi

The present invention relates to polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics containing in themselves an organic pigment having heat resistance as high as a thermal decomposition temperature of 200&#xb0; C. or higher, and soluble in a mineral acid and having group(s) of &#x2014;N&#x2550; and/or NH&#x2014; in the molecule, such as any of perinones and/or perylenes, any of phthalocyanines, any of quinacridones, and any of dioxazines, wherein they have a strength retention of 50% or higher when exposed to light from a xenon lamp for 100 hours and having a tensile strength retention of 85% or higher after exposed to an atmosphere of a temperature of 80&#xb0; C. and a relative humidity of 80% for 700 hours. The polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics can be used for cords for reinforcing rubber, sheets and rods for reinforcing cement/concrete, composite materials, sail clothes, ropes, knife proof vests and bullet proof vests.

Polybenzazole fiber and use thereof

An object of the present invention is to obtain a novel polymeric material capable of forming a solid polymer electrolyte excellent not only in processability, solvent resistance and durability/stability but also in ion conductivity by introducing sulfonic acid group or phosphonic acid group into a polybenzazole compound having excellent properties in view of heat resistance, solvent resistance, mechanical characteristics and the like. Means attaining the object of the present invention is a polybenzazole compound including an aromatic dicarboxylic acid bond unit having sulfonic acid group and/or phosphonic acid group and satisfying either a condition that inherent viscosity measured in concentrated sulfuric acid is in the range of 0.25 to 10 dl/g or a condition that inherent viscosity measured in a methanesulfonic acid solution is in the range of 0.1 to 50 dl/g. The object of the present invention can be attained also by a resin composition containing the aforementioned polybenzazole compound, a resin molding, a solid polymer electrolyte membrane, a solid polymer electrolyte membrane/electrode assembly and a method of preparing the solid polymer electrolyte membrane/electrode assembly.

Polybenzazole compound having sulfonic acid group and/or phosphonic acid group, resin composition containing the same, resin molding, solid polymer electrolyte membrane, solid polymer electrolyte membrane/electrode assembly and method of preparing assembly

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Otsu, Japan

Hiroshi Tachimori