Mitsubishi Jukogyo Kabushiki Kaisha

Other

Mitsubishi Heavy Industries Limited

Mitsubishi Gas Chemical Company, Inc.

Tokyo Gas Company Limited

Mitsubishi Gas Chem. Company, Inc.

Hiroshi Makihara

Kazuto Kobayashi

Wataru Matsubara

Kensuke Niwa

Masaki Iijima

Kazuhiro Morita

Shigeo Hasegawa

Hiroshi Uchida

Toshiro Okamoto

Ritsuo Hashimoto

Katsutoshi Murayama

Masaaki Kuwa

Kazutaka Mori

Yoshimitsu Nakajima

Yoshihiko Saito

Naoyuki Takahashi

Yoshinori Shirasaki

Younosuke Hoshi

Yoshimasa Fujimoto

Michio Oshima

Daisaku Shozen

Yoshihiko Kamimura

Yoshu Ohta

Masayuki Gondaira

Kennosuke Kuroda

Toshiyuki Uchida

Shinsuke Ohta

Toshikazu Shinkawa

Hisayoshi Fujita

Murayama Katsutoshi

Masashi Asaeda

A method of converting a plastic waste into oil by decomposing the plastic waste by a reaction using water in a supercritical or near supercritical region as a reaction medium. In this method, the reaction is conducted by using a tubular continuous reactor. The present invention further provides an apparatus therefor. Moreover, the present invention provides a method of converting a plastic waste into oil by conducting the reaction after hydrogen chloride is removed by performing the pyrolysis of the plastic waste in the case that the plastic waste contain chlorine. The present invention further provides an apparatus for performing this method.

Method for converting a plastic waste into oil in a stainless steel reactor

Apparatus for converting a plastic waste into oil

To present an oil-forming method of chlorine-containing plastic refuse capable of obtaining oily product free from chlorine content, while suppressing apparatus corrosion by efficiently capturing hydrogen chloride generated by decomposition of chlorine-containing plastics, the oil-forming method of chlorine-containing plastic refuse is characterized by decomposing chlorine-containing plastic refuse using water in supercritical region as reaction medium and forming into oil, wherein silver nitrate of 0.8 to 2.0 times the reaction equivalent amount of hydrogen chloride generated by decomposition of chlorine-containing plastic refuse is added in the water as reaction medium to decompose and form into oil, and generated hydrogen chloride is removed in a form of silver chloride.

Oil-forming method of chlorine-containing plastic refuse

A hydrogen producing apparatus for producing hydrogen on an industrial scale by steam reforming reactions and separating hydrogen using a hydrogen-permeable membrane, including nested outer (14), intermediate (18) and inner (20) cylinders, a combustion burner (44) disposed toward the inner hollow chamber of the inner cylinder (20), a catalyst layer (A) in the annulus (30) between the intermediate (18) and inner (20) cylinders, hydrogen-permeable tubes (32) disposed in the catalyst layer (A-30), and sweep gas supply tubes (34) in the hydrogen-permeable tubes (32). The raw material gas is fed to the catalyst layer (A) and is converted into hydrogen at a high temperature produced by the burner (44), the produced hydrogen permeates the hydrogen-permeable tubes (32) which selectively separate and collect the hydrogen, and the permeated hydrogen flows with the sweep gas out of the apparatus through the outlet (52) for the sweep tubes (34).

Hydrogen producing apparatus

Reaction vessel

A process for synthesizing material uses an exothermic reactor which comprises a coolant shell, two concentric pipes provided within the shell, a catalyst bed packed between inner and outer ones of the concentric pipes, an introduction tube connected to the inner pipe through which a starting fluid is introduced, and a communication path enabling the fluid after the passage of the inner pipe to be passed through the catalyst bed in a direction opposite to the direction of the passage through the inner pipe, the coolant shell having an inlet and an outlet for a coolant arranged in such a way that the flow of the coolant is parallel to the flow of the fluid within the catalyst bed. The coolant on the outside and the starting fluid on the inside of the catalyst bed cools the bed in such a way as to produce a temperature distribution along the bed that follows a maximum reaction rate line (M in FIG. 1) relating the concentration of the methanol to the temperature of the starting fluid.

Process for synthesizing methanol with an optimal temperature profile

A wetted wall type method of humidifying gas with a liquid which is composed, or mainly composed, of water wherein the liquid flows down a heated vertical wall to form a wetted wall and gas flows along the wetted wall in contact with the liquid on the wetted wall to increase the humidity contained in the gas, comprises supplying a greater amount of liquid than the amount of liquid used or evaporated for increasing the humidity, and recirculating the liquid which is not evaporated from an outlet of the wetted wall to a liquid supply portion, the amount of the flowing liquid being adapted to satisfy the following equation:

Method of humidifying a gas

A method for preparing a ceramic membrane for the separation of a condensed component which is characterized by comprising the steps of impregnating pores of a ceramic porous material with an alumina sol produced by hydrolyzing an aluminum alcoholate or an aluminum chelate; immersing the ceramic porous material into an aqueous sodium silicate solution; and subjecting the ceramic porous material to a water vapor treatment in a high-temperature water vapor.

Method for preparing ceramic membrane for separation of condensed

A thermal cracking method for producing olefins from hydrocarbons which comprises the steps of mixing said hydrocarbons with a mixed gas of methane and hydrogen in a methane/hydrogen mol ratio of 0.2 or more; prior to reaction carrying out a thermal cracking reaction under conditions such that the total concentration of methane and hydrogen is at least 40 mol % or more at the outlet of a reactor, the partial pressure of said hydrogen is 3 bars or more, the temperature at the outlet of the reactor is from 800.degree. to 1200.degree. C., and the residence time in the reactor is from 5 to 300 milliseconds; and quenching the reaction product discharged through the outlet of the reactor.

Thermal cracking method for producing olefins from hydrocarbons

Growing community of inventors

Hiroshima-ken, Japan

Hiroshi Makihara