Dai-ichi Kogyo Seiyaku Co., Ltd.

Other

Toray Industries, Inc.

Idemitsu Petrochemical Co., Ltd.

Kai-ichi Kogyo Seiyaku Co., Ltd.

501 Dai-ichi Kogyo Seiyaku Co., Ltd.

Hiroshi Hotta

Hideyuki Sumi

Naoki Kitazawa

Manabu Kikuta

Yutaka Nakayama

Takayuki Tsubaki

Yasuhisa Sugita

Satoshi Hiratsuna

Hayashi Tomomi

Toshiaki Yamada

Shigeru Asami

Kinya Yokota

Yoshichika Nishimura

Osamu Wada

Nario Uejyukkoku

Mineo Sabi

Toshiaki Doyama

Masashi Takeda

Katsutoshi Ohta

Kanji Tanaka

Hiroshi Nishiguchi

Tomomi Ueda

Teruaki Sugahara

Shoichi Wakatake

Tetsuo Ishizuka

Disclosed is a polymer material of low relative permittivity obtained through copolymerization of a monomer composition that contains, as monomers, a fumaric diester and an epoxy group-having (meth)acrylate. The polymer material bonds or adheres well to metal conductor layers, and, after crosslinked, it is patternable. In addition, it has good electric properties of low relative permittivity, low dielectric loss tangent and good electric insulation, and has good heat resistance.

Crosslinkable polymer material of low relative permittivity, and films, substrates and electronic units formed of it

The present invention provides a cation-modified linear copolymer which comprises, within the molecule thereof, 95 to 85 mole % of an ethylene structural unit, 0.1 to 10 mole % of an ester structural unit represented by general formula (II), 0.1 to 6 mole % of an acrylic or methacrylic acid structural unit and 1 to 12 mole % of an amide structural unit represented by general formula (IV). The copolymer and has a weight-average molecular weight of 1,000 to 100,000. When incorporated in thermoplastic resins, it shows good compatibility and results in good mechanical properties. ##STR1##

Thermoplastic resin composition comprising cation-modified acrylamide or

The present invention provides a cation-modified linear copolymer which comprises, within the molecule thereof, 95 to 85 mole % of an ethylene structural unit, 0.1 to 10 mole % of an ester structural unit represented by general formula (II), 0.1 to 6 mole % of an acrylic or methacrylic acid structural unit and 1 to 12 mole % of an amide structural unit represented by general formula (IV). The copolymer has a weight-average molecular weight of 1,000 to 100,000. When incorporated in thermoplastic resins, it shows good compatibility and results in good mechanical properties. ##STR1##

Cation-modified acrylamide or methacrylamide copolymer as well as

The invention provides a thermoplastic resin composition uniformly and permanently rendered antistatic which comprises (A) 100 parts by weight of a thermoplastic resin, (B) 3-30 parts by weight of a cationic copolymer comprising 80-98 mol % of an ethylene unit and 2-20 mol % of a cationic unit and having a weight-average molecular weight of 1,000-50,000, and (C) 0.1-10 parts by weight of a copolymer comprising at least one unit each per molecule of a structural unit of formula (4) ##STR1## and a structural unit of formula (5) ##STR2##

Antistatic thermoplastic resin composition

There is disclosed a thermoplastic resin composition comprising as principal components a [A] thermoplastic resin having a functional group reactive with an amino group, a [B] olefinic polymer and/or styrenic polymer, the subtotal of the above [A]+[B] being 100 parts by weight, and 0.05 to 20 parts by weight of a [C] copolymer having a unit represented by ##STR1## wherein Y is a group selected from the groups of the general formula ##STR2##

Thermoplastic resin composition

The present invention provides an antistatic and flame retardant thermoplastic resin composition which comprises [A] 100 weight parts of a thermoplastic resin, [B] 2.0 to 40 weight parts of a bromine-containing organic flame retardant, and [C] 1.0 to 30 weight parts of a (meth)acrylamide-based copolymer and/or a (meth)acrylate ester-based copolymer each comprising 65 to 99 mole percent of an olefin-derived structural unit (I), 0 to 15 mole percent of a (meth)acrylate-derived structural unit (II) and 1 to 35 mole percent of a (meth)acrylamide-derived or (meth)acrylate ester-derived structural unit (III), as arranged linearly, with a weight average molecular weight of 1,000 to 50,000.

Thermoplastic resin with (meth)acrylamide or aminoalkyl (meth)acrylate

A novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc., and can undergo hydrolysis to give a copolymer containing a primary amino group, and a novel copolymer containing a primary amino group obtained by hydrolysis.

Formamide group-containing copolymer, process for producing the same,

A process for producing a novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc., and can undergo hydrolysis to give a copolymer containing a primary amino group, and a novel copolymer containing a primary amino group obtained by hydrolysis, which comprises reacting a compound having a recurring unit derived from styrene, olefins or derivatives thereof, a recurring unit derived from dienes such as butadiene, and a recurring unit derived from acid anhydrides such as maleic anhydride, with a salt of a specific primary diamine in the presence of a formyl group-containing compound such as formamide, to effect imidation and/or amidation, and then deacidifying the product with a base, or by imidation and/or amidation of the above-mentioned copolymer with a reaction product obtained by reacting a primary diamine with a formyl group-containing compound such as formamide.

Process for producing formamide group-containing copolymer, and

Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:

Compositions containing allylformamide copolymers

A linear random N-substituted acrylamide copolymer comprising 65 to 99% by mole of ethylene units, 1 to 15% by mole of acrylate units and 1 to 35% by mole of acrylamide units, the copolymer having a weight average molecular weight of 1000 to 50000, and an aqueous composition, a resin film, a laminate, recording paper and a foamed article comprising the N-substituted acrylamide copolymer, respectively. The N-substituted acrylamide copolymer is excellent in antistatic ability for thermoplastic resins and does not lower physical properties such as transparency and elongation of films and articles which are formed from a thermoplastic resin. Moreover, the N-substituted acrylamide copolymer is excellent in anti-blocking ability so that the copolymer can be suitably used for various uses.

N-substituted acrylamide copolymer

A flame-retardant TAIC is polymerized in the presence of a polymerization modifier and a polymerization initiator. As the polymerization modifier, 6H-dibenz [c,e] [1,2] oxaphosphorine-6-oxide is used in an amount of 1 to 200% by weight on the basis on the weight of triallyl isocyanurate.

Method for preparing a flame-retardant triallyl isocyanurate prepolymer

A conductive film-forming composition for use in the manufacture of electrostatic recording paper is provided. This composition comprises a copolymer of a diallylammonium halide derivative with a N-vinylacetamide derivative as an essential component. The conductive paper manufactured by coating or impregnating a substrate paper with this composition is of remarkably high practical value in terms of electrical conductivity, hardness, surface tackiness and solvent resistance.

Conductive film-forming composition

A process for forming a gel by gelling an aqueous solution of a water-soluble polymer with a chromium compound as a gelling agent, in which a copolymer of acrylamide, 0.5 to 40% by mole of an unsaturated sulfonic acid or its salt, and optionally an unsaturated carboxylic acid or its salt having an intrinsic viscosity of at least 10 in 1N-NaNO.sub.3 at 30.degree. C., is used as the water-soluble polymer, and which is availably applied to improvement of water-oil ratio in oil production and to civil engineering for preventing leakage of underground water. The formed gel is very stable in a water system containing salts in high concentrations at high temperatures.

Process for preparing stable aqueous gel

Natural coal containing inorganic impurities may be deashed by the selective flocculation process using a novel flocculant which is a water-soluble or water-dispersible copolymer having a molecular weight from about 100,000 to about 30,000,000 comprising a hydrophilic monomeric unit having a solubility in water greater than 15% by weight at 20.degree. C. and a hydrophobic monomeric unit having a solubility in water less than 10% by weight at 20.degree. C. in proportions of 99:1 to 20:80% by weight.

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Kyoto, Japan

Hiroshi Hotta