Mitsubishi Yuka Badische Company, Ltd.

Yuka Badische Co., Ltd.

Hiroshi Endo

Toshio Yagi

Toshihiro Gotoh

Masakazu Arai

Masanori Saito

Shigeki Mathuno

Takanori Suzuki

Masahiro Tanaka

Masanori Tanaka

Hiroshi Matsui

Shigeo Nishikawa

Kunikazu Nagasaki

Foamed particles of a propylene resin are described which comprises, as a base resin, a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight. A foamed mold article is also described which is composed of a random copolymer of propylene and 1-butene, and having a density of from 0.015 to 0.09 g/cm.sup.3. A bumper core material for use in automobile bumpers is also described which is composed of a foamed mold article of a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight, said foamed mold article having a density of from 0.02 to 0.08 g/cm.sup.3, a compression stress at 50% compression as measured at 20.degree. C. of 2.5 to 10 kg/cm.sup.2, and an energy absorption efficiency as measured at 20.degree. C. of 60 to 90%, the ratio (E.sub.80 /E.sub.20) of the amount of the energy absorption of said foamed mold article as measured at 80.degree. C. (E.sub.80) to the amount of the energy absorption of said foamed mold article as measured at 20.degree. C. (E.sub.20) being 0.5 to 0.9.

Propylene resin foamed particles and foamed mold article

Foamed particles of a propylene resin are described which comprises, as a base resin, a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight. A foamed mold article is also described which is composed of a random copolymer of propylene and 1-butene, and having a density of from 0.015 to 0.09 g/cm.sup.3. A bumper core material for use in automobile bumpers is also discribed which is composed of a foamed mold article of a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight, said foamed mold article having a density of from 0.02 to 0.08 g/cm.sup.3, a compression stress at 50% compression as measured at 20.degree. C. of 2.5 to 10 kg/cm.sup.2, and an energy absorption efficiency as measured at 20.degree. C. of 60 to 90% the ratio (E.sub.80 /E.sub.20) of the amount of the energy absorption of said foamed mold article as measured at 80.degree. C. (E.sub.80) to the amount of the energy absorption of said foamed mold article as measured at 20.degree. C. (E.sub.20) being 0.5 to 0.9.

A process for producing expanded particles of a styrene-acrylonitrile-butadiene copolymer is disclosed, comprising dispersing styrene-acrylonitride-butadiene copolymer particles in water in a closed vessel, feeding a volatile blowing agent to the aqueous dispersion in the closed vessel, heating the aqueous dispersion to a temperature higher than a glass transition point of the copolymer particles by at least 20.degree. C. to impregnate the volatile blowing agent into the copolymer particles, and opening one end of the closed vessel to release the aqueous dispersion containing the expandable copolymer particles into a low pressure zone having a pressure lower than the inner pressure of the closed vessel. The resulting expanded particles have a degree of expansion of from 10 to 50.

Process for producing expanded particles of

A method of producing a polypropylene resin molded product from foamed polypropylene particles is disclosed, which comprises introducing a pressurizing gas into foamed polypropylene particles having closed cells so that the particles have an internal gas pressure of from 0.3 to 2.5 Kg/cm.sup.2 G, charging the particles in a mold cavity while compressing the particles with a pressurizing inorganic gas until the initial apparent volume of the particles is reduced to 50 to 99%, removing the gas from the mold cavity while keeping the foamed particles in a compressed state, and introducing steam in the cavity to cause adhesion of the compressed foamed particles. The method produces a molded product having satisfactory appearance and excellent adhesion among particles in a shortened molding cycle.

Methods of producing molded products from foamed polypropylene particles

A process for producing propylene random copolymer resin foamed particles is disclosed. The process comprises dispersing propylene-ethylene random copolymer resin particles having an ethylene content of from 1 to 12% by weight in water in a closed vessel, feeding an inorganic gas into the closed vessel to raise the pressure within the closed vessel to at least 5 Kg/cm.sup.2 G, heating the dispersion to a temperature above the melting point of said copolymer resin particles but not higher than that by 25.degree. C. or more, opening a discharge port provided in the closed vessel below the water surface, and releasing the copolymer resin particles together with water as a dispersing medium into an atmosphere having a lower pressure than in the closed vessel. A foamed product produced by molding the foamed particles has firm bondage among the particles and excellent mechanical strength.

Process for producing foamed particles of propylene copolymer resin

Substantially non-crosslinked polypropylene resin foamed particles having a bulk density of from 8 to 100 g/l and a particle diameter of from 1 to 5 mm, the polypropylene resin is composed of from 5 to 30% by weight of a room-temperature xylene soluble matter having an ethylene content of from 20 to 80% by weight and from 70 to 95% by weight of a room-temperature xylene insoluble matter having a main melting peak temperature of from 130.degree. to 158.degree. C. The foamed particles provide a foamed product having well-balanced properties, such as low-temperature moldability, heat resistance, recovery from compression, and the like.

Polypropylene foamed particles

A process for producing foamed particles of a polyolefin resin which comprises dispersing polyolefin resin particles in water in a closed vessel, feeding a volatile blowing agent into the closed vessel, heating the dispersion to a temperature above the softening point of the polyolefin resin particles but below their melting point, opening a discharge port provided within the closed vessel below the water surface and releasing the aqueous dispersion containing the polyolefin resin particles impregnated with the blowing agent into an atmosphere kept at a lower pressure than the pressure within the closed vessel; wherein

Process for producing foamed particles of polyolefin resin

Substantially non-crosslinked polypropylene foamed particles having a bulk density of from 8 to 100 g/l and a particle diameter of from 1 to 5 mm and containing an organic sodium phosphate represented by the formula: ##STR1##

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Mie, Japan

Hiroshi Endo