Nippon Steel Corporation

Nippon Steel Sumitomo Metal Corporation

Nippon Steel Chemical Co., Ltd.

Hiromasa Shoji

Kenichiro Tadokoro

Tadashi Sakon

Takeshi Hamada

Tsutomu Sugiura

Koki Tanaka

Masao Sakashita

Hiromasa Nomura

Atsuo Shimizu

Ikumi Tokuda

Ikuo Jitsuhara

Yuji Yamaguchi

Yasuto Goto

Kiyokazu Ishizuka

Kohei Tokuda

Natsuko Sugiura

Masahiro Fuda

Atsushi Morishita

Kohei Ueda

Yuji Kubo

Hironori Sato

Mamoru Saito

Kimihito Suzuki

Koji Akioka

Taihei Kaneto

Yoichi Kawano

Hiroshi Kajiro

Yoshihiro Kaneda

Masao Kimura

Tetsusei Fukuda

Taro Kohno

Taro Kono

Makoto Yamasaki

Kunihiko Toshin

Noriyuki Kooka

Maki Sekoguchi

Makoto Yamazaki

Yoshikatsu Nishida

This surface-treated steel sheet includes: a steel sheet; a Zn-based plating layer formed on the steel sheet; and a coating formed on the Zn-based plating layer, in which a Si concentration, a P concentration, a F concentration, a V concentration, a Zr concentration, a Zn concentration, and an Al concentration of the coating are, by mass %, Si: 10.00% to 25.00%, P: 0.01% to 5.00%, F: 0.01% to 2.00%, V: 0.01% to 4.00%, Zr: 0.01% to 3.00%, Zn: 0% to 3.00%, and Al: 0% to 3.00%, in a narrow spectrum of 5i2p obtained by performing XP S analysis on a surface of the coating, a ratio of an integrated intensity of a peak having a local, maximum value, at 103.37±0.25 eV to an integrated intensity of a peak having a local maximum value at 102.26±0.25 eV is 0.04 or more and 0.25 or less.

Surface-treated steel sheet

A surface-treated steel sheet includes: a base steel sheet; a plated layer formed on the base steel sheet and containing 50 mass % or more of Zn and 0.3 mass % or more of Mg; and a chemical conversion coating formed on the plated layer. The chemical conversion coating contains a silicon compound, P and F, and Mg, an average Si concentration of the chemical conversion coating is 10 mass % or more, the chemical conversion coating includes an F—Mg concentrated layer having an Mg concentration of 1.50 mass % or more and 40.00 mass % or less and an F concentration of 0.50 mass % or more and 5.00 mass % or less in a region in contact with an interface between the chemical conversion coating and the plated layer, a thickness of the F—Mg concentrated layer is 1.0 nm or more, and an average Mg concentration is less than 0.50 mass % and an average F concentration is less than 0.50 mass % in a region of the chemical conversion coating excluding the F—Mg concentrated layer.

A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

Surface-treated metal material

The object of the invention is to provide a surface-treated steel sheet having a coating having fine adhesiveness to an adhesive on the surface and having excellent corrosion resistance, and a production method thereof. Provided is a surface-treated steel sheet including: a steel sheet; a plated layer containing zinc on the steel sheet; and a coating on the plated layer, wherein the coating contains an acrylic resin, zirconium, vanadium, phosphorus and cobalt, and the acrylic resin has an area ratio of 80 to 100 area % in an area from a surface to a thickness of one-fifth of a film thickness of the coating, and an area ratio of 5 to 50 area % in an area including areas from the film thickness center of the coating to a thickness of one-tenth of the film thickness toward the surface side and toward the plated layer side.

Surface-treated steel sheet and method for producing surface-treated steel sheet

A surface-treated steel sheet for fuel tanks, including a Zn&#x2014;Ni alloy plating layer on one surface or both surfaces of a steel sheet; and a trivalent chromate covering layer or a chromate-free covering layer on the Zn&#x2014;Ni alloy plating layer, wherein, in a surface outermost layer of the trivalent chromate covering layer or the chromate-free covering layer, concavities, of which a depth from an arithmetic average height of a cross-sectional curve of the surface outermost layer is more than or equal to 0.1 &#x3bc;m, exist in a proportion of 50 to 1000 concavities/mm2 and at an area ratio of 20 to 80% to a surface area of the steel sheet.

Surface-treated steel sheet for fuel tanks

A metal material of the present invention is composed of an underlying metal and a phosphate compound-based film which is disposed on the surface of the underlying metal and has a surface part, in which the surface part of the phosphate compound-based film contains Zr.

Metal material having excellent corrosion resistance

A composite coated metal sheet comprising a coated film having a low environmental impact prepared free from hexavalent chromium, and having good corrosion resistance equivalent to that provided by chromate treatment and excellent adhesiveness between the coated film and a resin layer formed on the coated film. Also, a treatment agent and a method of manufacturing the composite coated metal sheet with the treatment agent is described. The composite coated metal sheet comprises a coated film formed on a surface of a plated metal sheet or metal sheet, the coated film contains an oxide and/or a hydroxide of metal other than chromium, and an organic component comprising modified and/or unmodified functional group(s).

Composite coated metal sheet, treatment agent and method of manufacturing composite coated metal sheet

A method for production of a metal oxide and/or metal hydroxide coated metal material comprises immersing a metal material or electrolyzing a conductive material in an aqueous treatment solution at pH 2-7 containing metal ion and fluorine ion in a 4-fold or more molar ratio with respect to the metal ion, and/or containing a complex ion comprising at least a metal and fluorine in a 4-fold or more molar ratio with respect to the metal, to form on the surface of the metal material a metal oxide and/or metal hydroxide coating containing the metal ion and/or the metal, as well as a metal oxide and/or metal hydroxide coated metal material having a metal oxide and/or metal hydroxide coating produced by the method.

Metal oxide and/or metal hydroxide coated metal materials and method for their production

The present invention provides a precoated metal sheet excellent in the coating material adhesion and having little affect on environment. The precoated metal sheet of the invention is a precoated metal sheet comprising a metal or plated metal sheet having stacked on the surface thereof at least a coat layer and an organic resin layer, the metal or plated metal sheet mainly comprising zinc and aluminum and the coat layer mainly comprising one or both of a metal oxide and a metal hydroxide each using a metal species exclusive of chromium.

Precoated metal sheet with little affect on environment

To provide a chemical conversion-treated metal sheet excellent in the corrosion resistance and coating adhesion, free from elution of chromium oxide and small in the environmental load, there is provided a chemical conversion-treated metal sheet comprising a metal sheet having on at least one surface thereof an inorganic film, wherein the inorganic film is a film comprising as a main component one or both of a metal oxide and a metal hydroxide exclusive of Cr and the film contains F.

Chemical conversion-treated metal plate

This invention relates to a graphite material for negative electrode of lithium secondary battery. This graphite material is obtained by carbonizing the pulverized green coke to yield coke, adding one kind or more of boron or a compound thereof to the coke, graphitizing the resulting mixture and controlling the particle size of the product graphite. This graphite material for negative electrode is characterized by showing a tap density of 0.95 g/cmor more after tapping 20 times or 1.15 g/cmor more after tapping 300 times and a BET specific surface area of 1.5 m/g or less. A lithium secondary battery made by the use of this graphite material for negative electrode has a large discharge capacity and suffers little loss during charging and discharging.

Graphite material for negative pole of lithium secondary battery, method of manufacturing the graphite material, and lithium secondary battery

A lithium secondary battery comprising a positive electrode active material, a negative electrode active material, and a non-aqueous electrolyte is disclosed. The negative electrode active material is a powder of a silicon material containing boron and has a boron content in the range of 0.1-50 wt. %.

Lithium secondary battery and active material for negative electrode in lithium secondary battery

A metal plate having a rust preventive organic layer, said rust-preventive organic layer being a colloid or micelle of a slightly water soluble organic corrosion inhibitor as an organic layer mixed with and dispersed in a matrix resin, its production process and a treatment liquid in which it is processed.

Metallic sheet having rust-preventive organic coating thereon, process for the production thereof and treating fluid therefor

A surface treated metal sheet which is coated with a layer comprising, as main components, a complex and/or salt between a rare earth metal element and an organic compound having in the molecule one or more functional groups selected from among &mdash;O&mdash;, &boxH;O, &mdash;OH, &mdash;COOH, &mdash;NH,, &boxH;NH, &boxH;N&mdash;, &mdash;SH, &mdash;SO,H and phosphoric groups, and a matrix which physically holds the above and has adhesive power for metal sheets, as well as a metal surface treatment solution used therefor.

Surface-treated metal plate and metal surface treating fluid

Surface treated metal materials with corrosion-resistant coating layers composed mainly of oxyacid compounds of rare earth elements (lanthanum, cerium, etc.) or Group IVA elements (zirconium, etc.), oxyacids or mixtures thereof. The corrosion resistant coating layers may also contain resins. Also provided are corrosion resistant coating layers containing rare earth element and Group IVA element compounds in resin matrixes. The corrosion resistant coating layers, particularly inorganic layers, may be covered with resin layers.

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Tokyo, Japan

Hiromasa Shoji