Kao Corporation

Hiroki Sawada

Toshiya Hagihara

Yasuo Ishii

Hiroyasu Togashi

Tadanori Yoshimura

Atsuhito Mori

Hiroshi Nagumo

Shoji Nakagawa

Yuichiro Kobayashi

Jouji Hirai

Akira Yamamuro

Yukinaga Yokota

Akio Kimura

Akimitsu Sakai

Takayuki Ikenaga

Toshihiro Tanaka

Tomoya Tsuboi

Toyomi Koike

Akihiro Onoue

Hideo Suzuki

Masahiro Mori

Tomihiro Kurosaki

Hajime Hirota

Jun Kamegai

Yoshinori Mitsuda

Shogo Nomoto

Jiro Hashimoto

Hidekazu Ogino

Hiroshi Kamitani

Shuichi Inaya

Takuma Kimura

Haruya Mino

Toshitsugu Maeda

Hiroyuki Aizawa

Shigehisa Kamimura

A method for manufacturing a thermoplastic resin composition enabling easy control of the weight average molecular weight of a thermoplastic resin used in a soluble three-dimensional modeling support material, the support material having sufficient strength even when used in the manufacture of a three-dimensional object by an FDM system 3D printer, being less colored with excellent appearance quality, and having a high dissolution speed in neutral water and quickly removable from a precursor of the three-dimensional object without using a strong alkaline aqueous solution; and the thermoplastic resin having dicarboxylic acid monomer units derived from a dicarboxylic acid component and having a proportion of an aromatic dicarboxylic acid monomer unit derived from a sulfonic acid group and/or sulfonate group-containing aromatic dicarboxylic acid component in the dicarboxylic acid monomer units of 10 mol % or more; the method including mixing an organic salt compound represented by formula (I):(R&#x2014;SO)X&#x2003;&#x2003;(I).

Method for manufacturing thermoplastic resin composition

The present invention is a composition of an agent for treating a precursor of a three-dimensional object for removing a support material from a precursor of the three-dimensional object containing a three-dimensional object and the support material, the composition containing water and a water-soluble compound having a solubility parameter (SP value) calculated by using the Fedors' method of 8 (cal/cm)to 13 (cal/cm). The present invention can provide a composition of an agent for treating a precursor of a three-dimensional object that is capable of removing the support material quickly and a method for manufacturing a three-dimensional object using the composition of an agent for treating a precursor of a three-dimensional object by a fused deposition modeling system.

Composition for treating three-dimensional object precursor

The present invention is a soluble material for three-dimensional modeling that is used as a material of a support material for supporting a three-dimensional object when the three-dimensional object is manufactured by a 3D printer of a fused deposition modeling system and that contains a thermoplastic resin having a hydrophilic group and an organic salt compound represented by a general formula (I) below: (R&#x2014;SO)X(I). According to the present invention, it is possible to provide a soluble material for three-dimensional modeling that is used for a support material and that is capable of suppressing the degradation of the modeling accuracy of a three-dimensional object when the three-dimensional object is manufactured by a 3D printer of a fused deposition modeling system, and has a high rate of dissolution to neutral water to be removable speedily from a precursor of the three-dimensional object without use of a strong alkaline aqueous solution.

Soluble material for three-dimensional molding

A soluble material for three-dimensional modeling, which is used as a raw material of a support material for supporting a three-dimensional object when the three-dimensional object is produced, using a 3D printer of a FDM system, includes a polyester resin including one or more aromatic dicarboxylic acid monomer units A with a sulfonate group, one or more dicarboxylic acid monomer units B without a sulfonate group, and one or more diol monomer units. The proportion of the aromatic dicarboxylic acid monomer unit(s) A in the total of all dicarboxylic acid monomer units is from 10 to 70 mol %. The soluble material has hygroscopicity resistance while the material is large in dissolution rate into any neutral water and removable speedily from a precursor of the three-dimensional object without using any aqueous strong alkaline solution.

Three-dimensional-modeling soluble material

A molded article selected from the group consisting of (1) a sheet or a film, (2) a thermoformed article, (3) a stretched film, wherein the molded article is made of a polyester resin composition containing a polyester resin and a polyester-based plasticizer represented by the following formula (I): RO&#x2014;CO&#x2014;R&#x2014;CO&#x2014;[(OR)O&#x2014;CO&#x2014;R&#x2014;CO&#x2014;]OR(I), wherein Ris an alkyl group having from 1 to 4 carbon atoms, Ris an alkylene group having from 2 to 4 carbon atoms, Ris an alkylene group having from 2 to 6 carbon atoms, m is the number of from 1 to 6, and n is the number of from 1 to 12, with proviso that all the R's may be identical or different, and that all the R's may be identical or different. The molded article of the present invention can be, for example, suitably used, such as a sheet or film for use in various industrial applications in foods, agriculture, and industries, a thermoformed article for use in various applications such as food containers, wrapping materials for daily sundries and household electric appliances, and industrial trays of industrial parts, and a stretched film for use in various applications such as wrapping materials for food wrappings, daily sundries, and household electric appliances, and various industrial films, respectively.

Molded product composed of polyester resin composition

A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

Resin composition

A method for promoting crystallization of a biodegradable resin composition, including the step of melt-kneading a raw material containing ethylenebis 12-hydroxystearic amide having an amine value of 1.0 mg KOH/g or less and a biodegradable resin. Since the biodegradable resin composition obtainable by the method for promoting crystallization of the present invention has favorable crystallization velocity, a time period required upon molding the composition is shortened, whereby a molded article can be produced productively. The biodegradable resin composition can be suitably used in, for example, in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

Method for promoting crystallization of biodegradable resin composition

The invention provides a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, the reaction being conducted with a catalyst containing at least one metal selected from iron, cobalt and manganese in an amount of 0.1 to 60 ppm in terms of metal (weight ratio to the total weight of glycerin and the acyl-containing compound), as well as a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, including a step of maintaining the amount of water at 500 to 5000 ppm in the reaction system after the degree of conversion in the reaction of glycerin with fatty acid reaches 90% or more based on the fatty acid, or during the ester exchange reaction of glycerin with glycerin ester.

Process for producing a monoglyceride-containing composition

The invention provides a surfactant for emulsion polymerization represented by the formula (I), (II) or (VI). The invention also provides a method of producing a polymer emulsion using this surfactant. wherein A represents an alkylene group having 3 to 18 carbon atoms or an alkoxymethylethylene group (alkoxy group has 4 to 18 carbon atoms), EO represents an oxyethylene group, a denotes a number of 0 to 50, b denotes a number of 0 to 200 wherein a and b are not 0 at the same time and M represents a cation; wherein A'O represents an oxyalkylene group having 3 to 18 carbon atoms, E&#x2032;O represents an oxyethylene group, m denotes a number of 0 to 50 and n denotes a number of 5 to 200, provided that the -(A&#x2032;O)&#x2014; groups m in number [-(A&#x2032;O)m-] may be the same as or different from one another.

Surfactant for emulsion polymerization

Surfactant composition for emulsion polymerization

A process is disclosed for the production of an alkyl glycoside stable in hue and odor, which comprises the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing a higher alcohol, (2) decoloring the alkyl glycoside reaction product with hydrogen peroxide, (3) contacting the decolored alkyl glycoside with a metal/hydrogen complex represented by formula (I)

Process for production of alkyl glycoside stable in hue and odor

Ethoxylate and propoxylated higher alcohol surfactant in high

Surfactant composition

Polyol ether derivatives, a method for producing the polyol ether derivatives, and a working fluid composition for a refrigerating machine containing a hydrofluorocarbon and a refrigeration oil containing the polyol ether derivatives as a base oil.

Polyol ether derivatives and production methods therefor

Growing community of inventors

Wakayama, Japan

Hiroki Sawada