Takemoto Yushi Kabushiki Kaisha

Other

Teijin Seiki Co., Ltd.

Takemoto Yushi Kabushiki Kaisha & Teijin Seiki Co., Ltd.

Hirokazu Matsueda

Tatsuhiko Ozaki

Toshiharu Suzuki

Hirotaka Wada

Masato Sugiura

Iwao Komiya

Mitsuo Kinoshita

Yuji Takayama

Shigeru Imamura

Yuuji Takayama

Tsuneo Hagiwara

Masahiko Yamada

Yorikazu Tamura

Tsukasa Kinoshita

Atsushi Kodama

Katsunori Demura

Yoshihiko Ohama

Maseto Sugiura

Yasunari Hoshii

Photocurable resin compositions capable of producing plastic molds with improved durability by stereolithography in the presence of a photoinitiator includes unsaturated urethane of a specified kind, vinyl monomer of a specified kind, a filler and salt of phosphoric acid ester of specified kinds at a specified ratio.

Photocurable resin compositions for plastic molds

In a process for producing a three-dimensional photohardened object by forming a layer of photocurable resin composition containing a photocurable liquid, a filler and a photoinitiator, photohardening at least a portion of this layer by exposing it to actinic radiation, and thereafter repeating the process of forming thereabove a new layer of photocurable resin composition and photohardening at least a portion of this layer by exposing it to actinic radiation, the property of the photocurable resin composition to become level can be improved by adding phosphoric acid ester of a specified structure at a specified rate.

Method of providing leveling property to photocurable resin composition

A plastic mold is produced by first repeating the process of forming a layer of a photocurable resin composition of a specified kind and exposing it to actinic radiation to at least partially photocure it to produce a photocured layered structure having a glass transition temperature of 70.degree.-120.degree. C. This structure is then subjected to a post-cure process at a temperature high than the glass transition temperature by 30.degree.-100.degree. C. Plastic molds made by this method have superior heat distortion temperature and tensile elastic modulus.

Plastic molds and methods of producing same

Photocurable resins containing unsaturated urethane of a specified form and vinyl monomer which is N-(meth)acryloylmorpholine or its mixture with di-ol di(meth)acrylate at a rate within a specified range and compositions containing such a resin and a filler such as solid particles and/or inorganic whiskers of specified kinds at a specified rate are capable of yielding stereo lithographed objects with improved mechanical and thermal properties and form precision.

Photocurable resins for stereolithography and compositions containing

Photocurable resins containing unsaturated urethane of a specified form and vinyl monomer which is N-(meth)acryloylmorpholine or its mixture with di-ol di(meth)acrylate at a rate within a specified range and compositions containing such a resin and a filler such as solid particles and/or inorganic whiskers of specified kinds at a specified rate are capable of yielding stereolithographed objects with improved mechanical and thermal properties and form precision.

Curable polymer mortar or concrete compositions with improved workability and processability use polymerizable liquid resin composed of unsaturated urethane of a specified form and vinyl monomers as binder and also contain an inorganic powder filler, aggregates and a viscosity reducer of a specified kind and a low shrinking agent of a specified kind each at a specified rate. Cured compositions with improved accuracy in measurements, strength and water absorption can be obtained from such compositions. Self-leveling property can also be provided.

Curable polymer mortar or concrete compositions

A polymerizable composition contains unsaturated urethane shown by Formula (1) given below, vinyl monomer which is copolymerizable with this unsaturated urethane, and an inorganic powder filler at weight ratio of (unsaturated urethane)/(vinyl monomer)=10/90-90/10, the inorganic powder filler being 30-300 weight parts with respect to 100 weight parts of the sum of the unsaturated urethane and vinyl monomer: ##STR1## where X is a residual group obtained by removing isocyanate groups from polyisocyanate; Y is a residual group obtained by removing hydroxyl groups from polyol; R.sup.1 is a residual group obtained by removing hydroxyl group from non-radical polymerizable mono-ol having aliphatic hydrocarbon group with 6-22 carbon atoms; R.sup.2 is H or CH.sub.3 ; and p, q and r are each an integer 1-3 such that 2.ltoreq.p+q.ltoreq.4 and qr.gtoreq.2. In-mold cured products obtained from such a polymerizable composition have superior external appearance and water-resistance, and their mold shrinkage is small.

Polymerizable compositions and in-mold cured products using same

As cotton bales are produced by obtaining lint cotton by subjecting collected seed cotton to a ginning process, linear polyorganosiloxane of a specified type which has 10-6000 siloxane units and is insoluble or dispersive in water is adhesively attached to the seed cotton or to the lint cotton by 0.03-2.0 weight % with respect to the lint cotton.

Method of producing cotton bales

A polymerizable composition contains unsaturated urethane shown by Formula (1) given below, vinyl monomer which is copolymerizable with this unsaturated urethane, and an inorganic powder filler at weight ratio of (unsaturated urethane)/(vinyl monomer)=10/90-90/10, the inorganic powder filler being 30-300 weight parts with respect to 100 weight parts of the sum of the unsaturated urethane and vinyl monomer: ##STR1## where R.sup.1 is hydrogen atom or methyl group; X is a residual group obtained by removing isocyanate groups from diisocyanate; Y is a residual group obtained by removing hydroxyl groups from non-radical polymerizable di-ol or tri-ol of a specified kind; Z is an organic group in the form of (R.sup.2 O).sub.m or R.sup.3 O, R.sup.2 being an alkylene group with 2-4 carbon atoms, R.sup.3 being an alkylene group with 2-12 carbon atoms, and m being an integer 2-10; and n is 2 or 3.

Radical polymerizable liquid resins contain unsaturated urethane of a specified structure and vinyl monomers at weight ratio of (unsaturated urethane)/(vinyl monomers)=10/90-90/10. The unsaturated urethane has (meth)acryloyl and higher aliphatic hydrocarbon groups in its molecule, and the vinyl monomers are copolymerizable with this unsaturated urethane. Radical polymerizable liquid resin compositions are obtained by adding inorganic powder filler to such radical polymerizable liquid resins In-mold cured products obtained from such radical polymerizable resins or radical polymerizable resin compositions have improved water resistance and other favorable properties

Polymerizable molding liquid resins, compositions containing same and

Molded products with improved dimensional stability and surface property can be obtained by in-mold curing of a polymerizable composition containing unsaturated urethane of a specified structure, alkyl (meth)acrylate, and a thermoplastic macromolecular compound capable of dissolving in or swelling by impregnating alkyl (meth)acrylate. These components are contained at specified weight ratio. The mold is initially at temperature 30.degree..about.120.degree. C. and the curing is effected in the presence of a radical initiator.

Polymerizable compositions

A steam stripping fraction of sesame seed oil with increased concentration of sesamin and episesamin is used in a molecular distillation process to obtain a fraction containing more than 70 weight % of sesamin and episesamin. The steam stripping fraction is preferably obtained by a steam stripping process wherein the temperature (t.degree. C.) of the sesame seed oil and the pressure (P mmHg) for the process are such that {(4.24.times.10.sup.3)/(9.41-log P)}-273 .ltoreq.t.ltoreq.280 and 0.5.ltoreq.P.ltoreq.20.

Method of separating sesamin and episesamin

Cotton bales and method of producing same

Unsaturated urethane having specified molecular structure shown by Formula (1) given below and vinyl monomers which are copolymerizable with such unsaturated urethane can form together polymerizable compositions which, as well as in-mold cured products therefrom, have improved characteristics such as compatibility between the constituents and water resistance: ##STR1## where X is a residual group obtained by removing the hydroxyl groups from a trihydric or tetrahydric polyol; R.sup.1 and R.sup.3 are each H or CH.sub.3 ; R.sup.2 is higher aliphatic hydrocarbon group with 5.about.21 carbon atoms; p and q are each 1 or 2; r is an integer 0.about.2 such that p+q+r=3 or 4 and p+r=2 or 3; and a is an integer 2.about.4.

A hardenable unsaturated polyester resin composition contains block copolymers and unsaturated polyester. The block copolymer includes both polyester blocks and a polydiene block as constituent segments.

Growing community of inventors

Aichi, Japan

Hirokazu Matsueda