Asahi Kasei Kabushiki Kaisha

Hitachi, Ltd.

Hirokazu Kamine

Naoki Matsuoka

Masaki Takahashi

Mitsuhiro Kishimi

Kazuyuki Fujiwara

Akira Yoshino

Makoto Ito

Yutaka Natsume

Fusaji Kita

Xun Zhang

Provided is a nonaqueous secondary battery including: a positive electrode that contains at least one positive electrode active material capable of occluding and releasing lithium ions; a negative electrode that contains a negative electrode active material which is at least one selected from the group consisting of lithium metals and materials capable of occluding and releasing lithium ions; and a nonaqueous electrolytic solution, wherein the negative electrode contains at least one compound selected from the group consisting of compounds represented by general formulas (1)-(3).

Nonaqueous secondary battery

Provided is a non-aqueous secondary battery that includes a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte. The positive electrode includes LiNiCoMnO(0.7<x<0.9, 0<y<0.2, 0<z<0.2) as a lithium-containing metal oxide, and when the positive electrode before and after cycle testing of the non-aqueous secondary battery is analyzed by powder X-ray diffraction using Cu-Kα radiation, the rate of change of the c-axis lattice constant is 1.0% or less. The non-aqueous electrolyte includes 5-20% by volume of acetonitrile and has an ion conductivity of at least 10 mS/cm and less than 15 mS/cm at 20° C.

Non-aqueous secondary battery and non-aqueous electrolyte

The present disclosure provides a nonaqueous electrolyte solution which contains: a nonaqueous solvent containing acetonitrile and vinylene carbonate; and a compound represented by general formula (1) R-A-R(wherein A represents a divalent group that has a structure represented by one of formulae (1-2) to (1-5); and each of Rand Rindependently represents an aryl group, an alkyl group which may be substituted by a halogen atom, while having from 1 to 4 carbon atoms, an alkyl group, a vinylidene group which may be substituted by a halogen atom, or an aryl group which may be substituted by a halogen atom; or alternatively, Rand Rmay combine with each other and form, together with A, a ring structure that may have an unsaturated bond).

Nonaqueous electrolyte solution and nonaqueous electrolyte secondary battery

To provide a non-aqueous electrolyte solution, a non-aqueous secondary battery, a cell pack, and a hybrid power system, capable of improving desired battery performance in an acetonitrile electrolyte solution, the non-aqueous electrolyte solution contains a non-aqueous solvent, POFanions, and cyclic acid anhydride.

Non-aqueous secondary battery

To provide a non-aqueous electrolyte solution, a non-aqueous secondary battery, a cell pack, and a hybrid power system, capable of improving desired battery performance using acetonitrile, the non-aqueous electrolyte solution contains acetonitrile, lithium salt, and cyclic acid anhydride.

Non-aqueous electrolyte solution, non-aqueous secondary battery, cell pack, and hybrid power system

Non-aqueous electrolyte solution

The purpose of the present invention is to provide a nonaqueous electrolyte that contains acetonitrile having an excellent balance between viscosity and the dielectric constant and a fluorine-containing inorganic lithium salt, wherein the generation of complex cations comprising a transition metal and acetonitrile is suppressed, excellent load characteristics are exhibited, and increases in internal resistance upon repeated charge/discharge cycles are suppressed; a further purpose of the present invention is to provide a nonaqueous secondary battery. The present invention relates to a nonaqueous electrolyte which contains: a nonaqueous solvent comprising acetonitrile; a fluorine-containing inorganic lithium salt; and a specific nitrogenous cyclic compound typified by benzotriazole.

Nonaqueous electrolyte and nonaqueous secondary battery

The purpose of the present invention is to provide a nonaqueous electrolyte that contains acetonitrile having excellent balance between viscosity and the dielectric constant and a fluorine-containing inorganic lithium salt, wherein the generation of complex cations comprising a transition metal and acetonitrile is suppressed, excellent load characteristics are exhibited, and self-discharge during high-temperature storage is suppressed; a further purpose of the present invention is to provide a nonaqueous secondary battery. The present invention relates to a nonaqueous electrolyte which contains: a nonaqueous solvent comprising 30 to 100 vol % of acetonitrile; a fluorine-containing inorganic lithium salt; and a specific nitrogenous cyclic compound typified by pyridine.

The non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode, a non-aqueous electrolyte and a separator. The positive electrode includes a positive electrode mixture layer containing a positive electrode active material, a conductive polymer, an organic silane compound, a conductive assistant and a binder, the conductive polymer is polythiophene or a derivative thereof, and the content of the conductive polymer is 0.05 to 0.5 mass % with respect to the total mass of the positive electrode mixture layer.

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Tokyo, Japan

Hirokazu Kamine