Mitsui Chemicals, Inc.

Hiroaki Tago

Satoshi Yamasaki

Daisuke Hasegawa

Masakazu Kageoka

Hiroshi Kanayama

Makoto Kajiura

A polyurethane gel material includes an aliphatic polyisocyanate (A) having an average functionality of 2.3 or more and 3.2 or less, a polyol (B) having an average functionality of 2.0 or more and 2.3 or less, and a plasticizer (C) having an ester group. The aliphatic polyisocyanate (A) contains an isocyanurate derivative of an aliphatic diisocyanate and/or an alcoholic modified isocyanurate derivative of an aliphatic diisocyanate. The polyol (B) contains a polyoxyalkylene (carbon number of 2 to 3) polyol having an ethylene oxide content of 30% by mass or less, and/or a polytetramethylene ether glycol. The polyol (B) has an average hydroxyl value of 30 mgKOH/g or more and 70 mgKOH/g or less. A ratio of the plasticizer (C) per 100 parts by mass of the polyol component (B) is 50 parts by mass or more and 400 parts by mass or less.

Polyurethane gel material, polyurethane gel, pseudo-biomaterial, and producing method of polyurethane gel

A method for producing a polyurethane resin includes a reaction step of obtaining a primary product by reacting a polyisocyanate component containing a bis(isocyanatomethyl)cyclohexane with a polyol component containing a low molecular weight polyol having a number average molecular weight of 400 or less and a high molecular weight polyol having an average molecular weight of 2500 or more and 4000 or less under the presence of a bismuth catalyst, and a heat treatment step of heat treating the primary product to obtain a polyurethane resin. The bismuth catalyst content in the polyurethane resin is 0.1 ppm or more and 1000 ppm or less, and the heat treatment conditions in the heat treatment step are 50&#xb0; C. or more and 100&#xb0; C. or less and three days or more and ten days or less.

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Chiba, Japan

Hiroaki Tago