Nippon Sheet Glass Company, Limited

Other

Nsg Techno-research Co., Ltd.

Hiroaki Tada

Hideo Kawahara

Akihiko Hattori

Koji Shimoda

Kazuhiro Doushita

Toshiya Ito

Yasuhiro Saito

Etsuo Ogino

Masahiro Hirata

Harunobu Yoshida

Kenji Mori

Takashi Sunada

Hirotsugu Nagayama

Hiroyuki Inomata

Yoshifumi Kijima

Tetsuro Kawahara

Masato Hyodo

Kunio Miyata

A surface of a glass plate is coated with a first n-type semiconductor film which is a 50 nm-thick niobium oxide film as a primer layer. The primer layer is coated with a 250 nm-thick photocatalyst film comprising titanium oxide. Thus, an article having a photocatalytically active surface is obtained. The two coating films can be formed by sputtering. The first n-type semiconductor film as the primer layer is selected so as to have a larger energy band gap than the titanium oxide. Due to this constitution, more holes are generated near the film surface. This article can be free from the problem of conventional titanium oxide films having photocatalytic activity that it is difficult to generate many surface holes contributing to photocatalytic activity, because electrons and holes generated by charge separation recombine within the film, making it impossible to effectively heighten catalytic activity.

Article having photocatalytic activity

The present invention relates to An anti-fogging and stain-prevented glass article having an alkali shut-off film and a photocatalytic film in the order laminated on the surface of glass substrate, in which dents and projections having an arithmetical mean roughness (Ra) from 1.5 to 80 nm and mean interval (Sm) of dents and projections from 4 to 300 nm are formed thereon, and to An anti-fogging and stain-prevented glass article having an alkali shut-off film, a photocatalytic film, and a silicon oxide monocomponent equivalent layer or a layer of organosilane including at least one kind of functional group selected from polyalkyleneoxide group, alkyl group, alkenyl group and aryl group in its molecules or its hydrolyzed substance, laminated in the order on the surface of a glass article. The abovementioned anti-fogging and stain-prevented glass article can be used for window glasses of automobiles and buildings, and glasses, etc.

Nonfogging and stainproof glass articles

Fluorine contained within a photocatalyst layer containing titanium oxide and other metallic oxide semiconductors increases the metallic oxide's photocatalytic activity. The described photocatalyst may be in the form of either film, flake, particulate, or fiber. In addition, it can be used for coating the surface of a base material of various forms, such as sheet, film, flake, particulate, bar, or fiber. When using a base material that has an alkaline-containing glass composition, establishing a fluorine-containing layer, such as a layer of fluorine-containing silicon dioxide and other metallic oxide, between the photocatalyst film and the base material can prevent the deterioration of photocatalytic activity of the photocatalyst layer. The fluorine-containing layer functions as an alkaline barrier that controls the diffusion and migration of alkali metallic ions in the glass fibers, such as Na ions, into the photocatalyst layer. Inorganic fiber- and glass sheet-based photocatalyst bearing materials have an excellent capability to decompose rarefied harmful organic gases, and are suitable for use as interior wall and air filters in super clean enclosed spaces and conveyance spaces for semiconductor production, clean rooms for various other purposes, and office and residential buildings, and for other purposes including air cleaning, antibacterial action, anti-fouling action, and defogging of clear sheets (maintaining hydrophilicity).

Photocatalyst and method of making

Photocatalyst and process for the preparation thereof

A light controlling device comprising a pair of substrates, a viscoelastic or elastic dispersing medium containing fine particles aligned in an approximately constant direction, and a way for applying a shear stress to the viscoelastic or elastic material. The device can control light transmission in non-stage by applying a shear stress to the viscoelastic or elastic material to incline the direction of the alignment of particles with respect to the incident light.

Light controlling device and process for controlling light transmission

An electromagnetic device comprising solid matrix layer, wherein micro-capsules containing suspension anisotropic particles are dispersed, and a means for applying electric field or magnetic field to the anisotropic particles. According to the present invention, not only range of transmittance of solar radiation can be much improved, but also a smart window of large scale having nonuniformity of thickness and nonuniformity of density of particles can be realized.

Electromagnetic device

An electrochromic device comprising an oxidation coloring substance coloring in an oxidized state and a reduction coloring substance coloring in a reduced state which are formed on the surfaces of a pair of electrodes, respectively, and an electrolyte held between the two substances, wherein the oxidation coloring substance is a double salt containing an iron hexacyanoferrate and the reduction coloring substance is a tungsten-oxalic acid compound. The electrochromic device has a long life suitable for actual applications and a short response time and can operate at low applied voltages.

Electrochromic device

Growing community of inventors

Osaka, Japan

Hiroaki Tada