Ricoh Company, Ltd.

Miyoshi Yushi Kabushiki Kaisha

Richo Company, Ltd.

Hiroaki Matsui

Masafumi Torii

Masaru Shimada

Kyoji Tsutsui

Hiromi Furuya

Fumio Kawamura

Tadafumi Tatewaki

Masafumi Moriya

Kazuo Hosoda

Katsushi Sugiyama

Katsuhisa Kamio

Katsuaki Kokubo

Hitoshi Hattori

Toshiyuki Furuta

Tomohiko Beppu

Takayuki Sasaki

Mitsunobu Morita

Kunio Hayakawa

Atsushi Kutami

Shoji Maruyama

Takehito Yamaguchi

Toshiaki Ikeda

Tomohisa Kakuda

Yoshiaki Matsunaga

Tohru Kitano

Masatake Kawashima

Yoshitaka Sano

Yuhei Fujimoto

Provided is a linerless thermosensitive recording body package, a roll of a linerless thermosensitive recording sheet being packaged in the linerless thermosensitive recording body package, the linerless thermosensitive recording sheet including a support, a thermosensitive color developing layer over one surface of the support, a release layer over the thermosensitive color developing layer, and an adhesive layer over an opposite surface of the support, the linerless thermosensitive recording sheet being wound in roll shape in a manner that the adhesive layer comes to an internal side of the support, wherein a peel force for peeling the linerless thermosensitive recording sheet from the roll is 50 mN/50 mm or greater but 250 mN/50 mm or less, wherein a water content of the linerless thermosensitive recording sheet is 4.5% or higher but 6.5% or lower, the roll of the linerless thermosensitive recording sheet being seal-packaged in the linerless thermosensitive recording body package.

Linerless thermosensitive recording body package

To provide a thermosensitive recording material, which contains: a base; a thermosensitive coloring layer containing a leuco dye and a color developer; at least one protective layer containing a resin, a crosslinking agent, and wax, wherein the thermosensitive coloring layer is disposed on the base, and the protective layer is disposed on the thermosensitive coloring layer, and wherein the resin is reactive carbonyl group-containing polyvinyl alcohol, the crosslinking agent is a hydrazide compound, and the wax is oxidized polyethylene wax.

Thermosensitive recording material

A thermosensitive adhesive composition including a thermosensitive plastic resin, a dispersing agent, a solid plasticizing agent and a eutectic agent represented by the following chemical structure (1): wherein Xand Xindependently represent any one of a hydrogen atom, a halogen atom and an alkyl group, p and q independently represent an integer of from 1 to 5.

Thermosensitive adhesive composition, method of manufacturing the same and thermosensitive adhesive material

An erasable recording material including a substrate, and an erasable recording layer which is formed overlying the substrate and in which image information is repeatedly recorded and erased, and optionally includes an undercoat layer formed between the substrate and the recording layer, a protective layer formed overlying the recording layer and an intermediate layer formed between the recording layer and the protective layer, wherein the erasable recording material further includes one or more markers which are used for inputting image information additionally written on the recording material. An information recording system and method are also provided in which additional information written on the erasable recording material, in which image information is previously recorded, is incorporated to the previously recorded image information.

Erasable recording material capable of inputting additional information written thereon and information recording system and information recording method using the recording material

Reversible thermosensitive coloring composition and recording material using the composition and recording method using the recording material

Reversible thermosensitive recording medium

A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording layer further includes an erasure promoter including one or more secondary amide group having the following formulas (1), (2) or (3):

Reversible thermosensitive recording material and recording method and apparatus therefor

A reversible thermosensitive coloring composition including an electron donating coloring agent and an electron accepting color developer, wherein the composition achieves a colored state when heated at a temperature not lower than a coloring temperature and then cooled at a cooling speed (a), and the composition in the colored state achieves a non-colored state when heated at a temperature lower than the coloring temperature and not lower than an erasing temperature, or when heated at a temperature not lower than the coloring temperature and then cooled relatively slowly compared to the cooling speed (a), and wherein the electron accepting color developer includes a phenolic compound having the following formula (1):

A reversible thermal recording method using a color/non-color type reversible thermosensitive recording material which has a recording layer formed overlying at least one side of a substrate and including an electron donating coloring agent and an electron accepting color developer and which reversibly forms a colored state and a non-colored state by being appropriately heated and cooled. The recording layer having images of the colored state which have been formed in the recording layer is heated to erase the image, and imagewise heated either at substantially the same time as, or after, the image erasing operation to record new images therein, and then relatively rapidly cooled to maintain the new images. A reversible thermal recording apparatus therefor is also provided.

Reversible thermal recording method and apparatus therefor

A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein n is an integer of between 1 and 3, X represents a divalent group having a nitrogen atom or an oxygen atom, R.sup.1 represents a substituted or non-substituted aliphatic hydrocarbon group having at least two carbon atoms and R.sup.2 represents a hydrocarbon group. A reversible thermosensitive recording medium has a thermosensitive recording layer containing the above composition.

Reversible thermosensitive coloring composition and reversible

A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording material has an image density retention not less than about 60% when the recording material having an image is allowed to settle in a dry place at 50.degree. C. for 24 hours, a residual image density not greater than about 0.03 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image, and a residual image density after light irradiation not greater than about 0.04 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image after light of 5,000 lux is irradiated to the recording material for 100 hours.

Reversible thermosensitive recording material and recording method and

A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein R.sup.1 represents a substituted or non-substituted divalent hydrocarbon group having at least two carbon atoms, R.sup.2 represents a substituted or non-substituted hydrocarbon group, X and Y represent, independently from each other, a divalent group having a hetero atom and r is an integer of between 1 and 3. A reversible thermosensitive recording medium includes a support and a thermosensitive layer including the above composition.

Reversible thermosensitive composition and reversible thermosensitive

A reversible thermosensitive medium having a support and a thermosensitive layer, the layer comprising a composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein n is an integer of between 1 and 3, X represents a divalent group having a nitrogen atom or an oxygen atom, R.sup.1 represents a substituted or non-substituted aliphatic hydrocarbon group having at least two carbon atoms and R.sup.2 represents a hydrocarbon group. A reversible thermosensitive recording medium has a thermosensitive recording layer containing the above composition.

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Numazu, Japan

Hiroaki Matsui