Exxonmobil Research and Engineering Company

The Ohio State University

Exxonmobil Upstream Research Company

Exxonmobil Technology and Engineering Company

Exxonmobil Chemical Patents Inc.

Georgia Tech Research Corporation

B.g. Negev Technologies and Applications Ltd.

Himanshu Gupta

Liang-Shih Fan

Stephen Harold Brown

Scott Jeffrey Weigel

Richard Alan Huntington

Lei Zhang

Franklin F Mittricker

Moses Minta

Loren K Starcher

Mahesh Venkataraman Iyer

Mohsen N Harandi

Kun Wang

Simon Christopher Weston

David Charles Calabro

Mobae Afeworki

Paul Podsiadlo

Xiaochun Xu

Darryl Donald Lacy

Kiara M Benitez

James Richardson Lattner

Jihad Mohammed Dakka

Stuart Leon Soled

Michael Siskin

Paul Joseph Berlowitz

Wenyih Frank Lai

Doron Levin

Jane C Cheng

Chuansheng Bai

Ajit Bhaskar Dandekar

Walter Weissman

Randall David Partridge

Robert D Denton

Quanchang Li

Timothy Lee Hilbert

Bal K Kaul

David C Dankworth

Joseph M Falkowski

John Frances Brody

Tilman W Beutel

Benjamin S Umansky

Michael B Carroll

Keith K Aldous

Christine Esther Kliewer

Sulabh K Dhanuka

Robert J Falkiner

Brian Michael Weiss

Richard Charles Dougherty

Carla S Pereira

Eugine Choi

Federico Barrai

Juan D Henao

James William Gleeson

Tracie L Owens

Yi Du

Partha Nandi

Chad C Rasmussen

April D Ross

Mordechay Herskowitz

Miron Landau

Glenn C Wood

Steven Webster Levine

Thomas Francis Degnan, Jr

Eric B Senzer

Sara L Yohe

Tim Lieuwen

David A Griffin

Rajeev Agnihotri

Steven Pyl

Jonathan E Mitchell

Meghan Nines

Gerardo J Majano Sanchez

Quddus A Nizami

Iehudit Reizner

James E Kegerreis

Todd P Marut

Dongil Kang

James W Gleeson

Travis M DeShazo

Khizera Tariq

Cindy J Hughart

Jung Park

Deyaa I AbuSalim

Yaron Konra

Kirtan Kunjbihari Trivedi

John D Nelson

Andrew J Stella

Ketih K Aldous

The present disclosure provides mesoporous catalyst compounds and compositions having one or more group 13 atoms. The present disclosure further relates to processes for converting hydrocarbon feedstocks to small olefins. In one aspect, a catalyst compound includes a zeolite having a structural type selected from MFI, MSE, MTW, Theta-One (TON), Ferrierite (FER), AFI, AFS, ATO, BEA, BEC, BOG, BPH, CAN, CON, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITN, IWR, IWW, LTL, MAZ, MEI, MOR, MOZ, OFF, OKO, OSI, SAF, SAO, SEW, SFE, SFO, SSF, SSY, and USI, or a combination thereof, the zeolite having a silicon to aluminum molar ratio (Si/Al ratio) of from about 5 to about 40. In one aspect, a catalyst composition includes the catalyst compound and one or more group 13 metal.

Mesoporous catalyst compounds and uses thereof

Methods comprising contacting a residue comprising paraffinic, olefinic, and aromatic hydrocarbons with a polar solvent under conditions effective to extract at least a portion of the aromatic hydrocarbons from the residue into the polar solvent, thereby generating: an extract phase comprising the portion of aromatic hydrocarbons and the polar solvent; and, a raffinate phase comprising a majority of the paraffinic and olefinic hydrocarbons.

Liquid-liquid extraction of vacuum resid-containing fluid

A process for converting light paraffins and/or light hydrocarbons to a high octane gasoline composition is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohol; (2) conversion of the alkyl hydroperoxides and alcohol to dialkyl peroxides; and (3) radical coupling of one or more iso-paraffins and/or iso-hydrocarbons using the dialkyl peroxides as radical initiators, thereby forming a gasoline composition comprising gasoline-range molecules including a C7 enriched gasoline composition having a road octane number (RON) greater than 100.

Production of high-value fuel mixtures from synthetic and biologically derived hydrocarbon molecules

Disclosed are zeolitic imidazolate framework (ZIF) compositions in which at least a portion of the ligands in its shell have been exchanged with other ligands, and methods of making such shell-ligand-exchanged ZIFs. Also disclosed is the use of such shell-ligand-exchanged ZIFs in hydrocarbon separation processes.

Ligand-exchanged zeolite imidazolate frameworks

A method for producing a metal nitride and/or a metal carbide, a metal nitride and/or metal carbide optionally produced according to the method, and the use of the metal nitride and/or carbide in catalysis optionally catalytic hydroprocessing. Optionally, the method comprises: i) contacting at least one metal oxide comprising at least one first metal Mwith a cyanometallate comprising at least one second metal Mto form a reaction mixture; and, ii) subjecting the reaction mixture to a temperature of at least 300&#xb0; C. for a reaction period. Optionally, the metal nitride and/or metal carbide is a metal nitride comprising tungsten nitride.

Method for producing metal nitrides and metal carbides

A fuel, an oxidant, and a diluent can be introduced to a combustion zone, wherein the oxidant comprises air, oxygen-enriched air, or oxygen-lean air. At least a portion of the fuel can be combusted to produce an exhaust gas comprising, nitrogen, nitrogen oxides, and carbon monoxide. The exhaust gas can be expanded to produce mechanical power and an expanded exhaust gas. A concentration of at least one of oxygen, hydrogen, nitrogen oxides and carbon monoxide, in the exhaust gas or the expanded exhaust gas or both can be determined, and an amount of the oxidant or the fuel introduced to the combustion zone, or both, can be adjusted based on the determined concentration to produce an exhaust gas containing a combined amount of oxygen and carbon monoxide of less than about 2 mol % and a nitrogen concentration ranging from 20 mol % to 75 mol %. The diluent to the combustion zone can include at least a portion of the exhaust gas containing a combined amount of oxygen and carbon monoxide of less than 2 mol % and a nitrogen concentration ranging from 20 mol % to 75 mol %.

Systems and methods for controlling combustion of a fuel

Methods are provided for producing lubricant base stocks from deasphalted oils formed by sequential deasphalting. The deasphalted oil can be exposed a first deasphalting process using a first solvent that can provide a lower severity of deasphalting and a second deasphalting process using a second solvent that can provide a higher severity of deasphalting. This can result in formation of at least a deasphalted oil and a resin fraction. The resin fraction can represent a fraction that traditionally would have been included as part of a deasphalter rock fraction.

Sequential deasphalting for base stock production

Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any 'pitch' generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.

Processing of heavy hydrocarbon feeds

A system and process for selectively separating HS from a gas mixture which also comprises COis disclosed. A water recycle stream is fed to the absorber in order to create a higher concentration absorbent above the recycle feed and having a greater HS selectivity at lower acid gas loadings, and a more dilute absorbent below the recycle feed and having a greater HS selectivity at higher acid gas loadings. Also disclosed is a system and process for selectively separating HS by utilizing two different absorbents, one absorbent for the upper section of the absorber, tailored to have a greater HS selectivity at lower acid gas loadings, and a second absorbent for the lower section of the absorber, tailored to have a greater HS selectivity at higher acid gas loadings.

Process designs for increased selectivity and capacity for hydrogen sulfide capture from acid gases

Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each Ris a ZOZZSiZgroup, wherein each Zrepresents a hydrogen atom, a C-Calkyl group, or a bond to a silicon atom of another monomer unit; each Zand Zindependently represent a hydroxyl group, a C-Calkyl group, a C-Calkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Zrepresents a C-Calkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

Organosilica materials and uses thereof

Methods for reducing impurities and improving color in liquid hydrocarbon products (e.g., diesel fuel) are provided herein.

Methods of reducing impurities in diesel fuel

Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant derived from enriched air and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a recycle exhaust stream and drive a main compressor. A boost compressor receives and increases the pressure of the recycle exhaust stream and prior to being compressed in a compressor configured to generate the compressed recycle exhaust gas. To promote the stoichiometric combustion of the fuel and increase the COcontent in the recycle exhaust gas, the enriched air can have an increased oxygen concentration.

Stoichiometric combustion of enriched air with exhaust gas recirculation

Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a gaseous exhaust stream and drive a main compressor. A boost compressor can receive and increase the pressure of the gaseous exhaust stream and inject it into an evaporative cooling tower configured to use an exhaust nitrogen gas having a low relative humidity as an evaporative cooling media. The cooled gaseous exhaust stream is then compressed and recirculated through the system as a diluent to moderate the temperature of the stoichiometric combustion.

Stoichiometric combustion with exhaust gas recirculation and direct contact cooler

Systems and methods are provided for processing a heavy oil feed, such as an atmospheric or vacuum resid, using a combination of solvent assisted hydroprocessing and slurry hydroconversion of a heavy oil feed. The systems and methods allow for conversion and desulfurization/denitrogenation of a feed to form fuels and gas oil (or lubricant base oil) boiling range fractions while reducing the portion of the feed that is exposed to the high severity conditions present in slurry hydroconversion.

Staged solvent assisted hydroprocessing and resid hydroconversion

Provided are processes for making hydrocarbons from renewable feed sources. In an embodiment, there is provided a method for producing a lube basestock including: contacting a compound of Formula (I) and a feedstock of biological origin with a catalyst component including a basic material: wherein Ris selected from acyclic hydrocarbyl, cyclic hydrocarbyl, and aryl, wherein Rhas one or more optional substitutions selected from the group consisting of &#x2014;R, &#x2014;OR, &#x2014;C(O)R, and &#x2014;C(O)OR, wherein Ris H or C-Calkyl group; and n is 1, 2, 3, 4 or 5; and hydrogenating a ketone to a hydrocarbon with a catalyst including a hydrogenation catalyst and a hydrothermally stable binder.

Process for making lube base stocks from renewable feeds

Growing community of inventors

Lorton, VA, United States of America

Himanshu Gupta