Dainippon Ink and Chemicals, Incorporated

Hideyuki Takeuchi

Hiroki Tanaka

Toshifumi Tamaki

Eiji Satake

Yasuhiro Matsumoto

Shingo Takeda

Shigetoki Nishino

An object of the present invention is to provide a water-borne urethane resin composition for forming a microporous layer, which is suited for use in a fibrous material substrate, especially an artificial leather, and which has well-defined heat-sensitive coagulation properties and is capable of being uniformly filled into a fibrous material substrate without causing migration, forming a micrporous layer after drying and imparting a feel equivalent to that obtained in a solvent-based urethane resin composition, i.e., an elastic and genuine feel, by impregnating or coating the fibrous material substrate with the water-borne urethane resin composition; a method of producing a fibrous sheet-like composite using the water-borne urethane resin composition; and an artificial leather obtained by the method. The water-borne urethane resin composition of the present invention comprises (1) a water-borne urethane resin having a heat-sensitive coagulation temperature of 40 to 90&deg; C. and (2) an associated type thickener. In the method of producing a fibrous sheet-like composite according to the present invention, (i) a fibrous material substrate is impregnated or coated with (ii) the water-borne resin composition and then (iii) heat-sensitive coagulation is performed using steam.

Water-borne urethane resin composition for forming microporous layer, method of producing fibrous sheet-like composite, and artificial leather

A method for producing an isocyanate group-blocked liquid urethane prepolymer which comprises: reacting a lactone-modified diol (3) with a polyfunctional isocyanate (4) to form an isocyanate group-having urethane prepolymer (5), wherein said lactone-modified diol (3) is obtainable by ring-opening addition polymerization of a lactone monomer (2) with a diol (1) selected from the group consisting of a polyalkylene ether diol, a polyester diol and a polycarbonate diol; and then reacting said urethane prepolymer with a blocking agent (6).

Method for producing liquid urethane prepolymer and resin composition

A method for producing a polyurethane resin which comprises reacting: (A) a compound having an active hydrogen-containing group, containing: (A ) a compound having one spiro ring and active hydrogen-containing groups at both ends; and (A ) an aliphatic polycarbonate polyol; (B) a polyisocyanate; and (C) a chain-extending agent. Also disclosed are a resin composition comprising the polyurethane resin and a sheet-form article comprising the poylurethane resin or the resin composition.

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Osaka-fu, Japan

Hideyuki Takeuchi