Mitsubishi Gas Chemical Company, Inc.

Mgc Filsheet Co., Ltd.

Hidetaka Shimizu

Genki Sugiyama

Hiroyoshi Maruyama

Kohei Yoshiya

Takeshi Onishi

Osamu Kakinoki

Yasuyoshi Nakayasu

Hirohiko Aikawa

Shun Ishikawa

Toshinari Aoki

Kosei Hino

Ken Ogasawara

A sheet formed from a carbon fiber reinforced thermoplastic resin with a simplified production process and excellent mechanical characteristics, and a production method of said sheet is provided. This sheet is formed from a carbon fiber reinforced thermoplastic resin that contains carbon fibers, dichloromethane, and a thermoplastic resin containing at least one of a polycarbonate resin and a polyarylate resin, and the content of the dichloromethane contained in the sheet is 10-10,000 ppm by mass.

Sheet formed from carbon fiber reinforced thermoplastic resin, and production method of said sheet

A sheet formed from carbon fiber reinforced thermoplastic resin with high heat resistance, and a production method of said sheet is provided. This sheet is formed from a carbon fiber reinforced thermoplastic resin that contains carbon fibers, dichloromethane, and a thermoplastic resin containing at least one of a polycarbonate resin and a polyarylate resin. The aforementioned at least one of a polycarbonate resin and a polyarylate resin has a constituent unit derived from a dihydric phenol represented by formula (1), and the content of the dichloromethane contained in the sheet is 10-10,000 ppm by mass. (In formula (1), R-Rindependently represent a hydrogen, a halogen, a nitro, or a methyl group; X represents a divalent group represented by any of formulas (2) to (4).) 

A sheet formed from carbon fiber reinforced thermoplastic resin with high moldability, and a production method of said resin is provided. This sheet is formed from a carbon fiber reinforced thermoplastic resin that contains carbon fibers, dichloromethane, and a thermoplastic resin containing at least one of a polycarbonate resin and a polyarylate resin. The aforementioned at least one of a polycarbonate resin and a polyarylate resin has a terminal structure derived from a monohydric phenol represented by formula (1) and a constituent unit derived from a dihydric phenol, and the content of the dichloromethane contained in the sheet is 10-10,000 ppm by mass. (In formula (1), Rrepresents an alkyl group with 8-36 carbons, or an alkenyl group with 8-36 carbons, and R-Rindependently represent a hydrogen, a halogen, an alkyl group with 1-20 carbons optionally having a substituent, or an aryl group with 6-12 carbons optionally having a substituent.) 

A synthetic resin laminate is excellent in shape stability in high-temperature high-humidity environments and in surface hardness and usable for a transparent substrate material or protection material. A synthetic resin laminate includes a substrate layer containing a polycarbonate (B); and a resin layer laminated on one or both surfaces of the substrate layer, the resin layer containing a resin (A) that contains a (meth)acrylate copolymer (a1) and a polycarbonate (a2); wherein (a1) is a (meth)acrylate copolymer composed of 5 to 80% by mass of an aromatic (meth)acrylate unit (a11) and 20 to 95% by mass of a methyl methacrylate unit (a12); (a2) is a polycarbonate containing a constituent unit represented by formula [1]; and the ratio of (a1) with respect to the resin (A) is 5 to 55% by mass, and the ratio of (a2) with respect to the resin (A) is 95 to 45% by mass.

Synthetic resin laminate

A synthetic resin laminated sheet, in which whitening, cracking, and foaming do not occur when thermoforming is carried out, in particular when deep-draw molding is carried out, and defects do not occur during lamination of a hard coating layer; and a molded article obtained by molding the laminated sheet. A synthetic resin laminated sheet has a coating layer, which includes an acrylic resin, laminated on one surface of a substrate layer including a polycarbonate resin in which a monohydric phenol represented by general formula (1) is used as a chain terminator and is obtained by reacting the monohydric phenol with a dihydric phenol and a carbonate binding agent and has a viscosity average molecular weight of 18000-35000. (In the formula, R1 represents a C8-36 alkyl group or a C8-36 alkenyl group. R2-R5 each represent hydrogen, halogen, or an optionally substituted C1-20 alkyl group or C6-12 aryl group). 

Synthetic resin laminated sheet

The present invention has an object of providing a synthetic resin laminate that is usable for a transparent substrate material or protective material, has high thermoformability (pressure formability, thermal-bending formability), high insert moldability, and high surface hardness and/or impact resistance, and also providing a molded body formed by molding such a synthetic resin laminate. The synthetic resin laminate includes a polycarbonate-based substrate layer; and a resin laminated on one of, or both of, two surfaces of the polycarbonate-based substrate layer, the resin containing a specific (meth)acrylate copolymer resin and a specific polycarbonate resin. The polycarbonate-based substrate layer includes a polymer alloy and thus has a glass transition temperature (Tg) of 110 to 130&#xb0; C. Thus, the resultant synthetic resin laminate has high thermoformability and high surface hardness.

Growing community of inventors

Ibaraki, Japan

Hidetaka Shimizu